• Title/Summary/Keyword: interfacial energy

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Analysis of Propagating Crack Along Interface of Isotropic-Orthotropic Bimaterial by Photoelastic Experiment

  • Lee, K.H.;Shukla, A.;Parameswaran, V.;Chalivendra, V.;Hawong, J.S.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.102-107
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    • 2001
  • Interfacial cracks between an isotropic and orthotropic material, subjected to static far field tensile loading are analyzed using the technique of photoelasticity. The fracture parameters are extracted from the full-field isochromatic data and the same are compared with that obtained using boundary collocation method. Dynamic Photoelasticity combined with high-speed digital photography is employed for capturing the isochromatics in the case of propagating interfacial cracks. The normalized stress intensity factors for static crack is greater when $\alpha=90^{\circ}C$ (fibers perpendicular to the interface) than when $\alpha=0^{\circ}C$ (fiber parallel to the interface) and those when $\alpha=90^{\circ}C$ are similar to ones of isotropic material. The dynamic stress intensity factors for interfacial propagating crack are greater when $\alpha=0^{\circ}C$ than $\alpha=90^{\circ}C$. The relationship between complex dynamic stress intensity factor $|K_D|$ and crack speed C is similar to that for isotropic homogeneous materials, the rate of increase of energy release rate G or $|K_D|$ with crack speed is not as drastic as that reported for homogeneous materials.

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Realistic adsorption behaviors of the copper onto the functionalized CNTs

  • Park, Mi-Na;Kim, Byeong-Hyeon;Lee, Gwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.476-476
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    • 2011
  • Introduction of CNTs into a metal matrix has been considered to improve the mechanical properties of the metal matrix. However, the binding energy between metals and pristine CNTs wall is known to be so small that the interfacial slip between CNTs and the matrix occurs at a relatively low external stress. The interfacial strength between CNT and metal matrix is thus one of the key factors for successful development of the CNT/metal composites. Defective or functionalized CNT has been considered to enhance the interfacial strength of nanocomposites. In the present work, we design the various realistic hybrid structures of the single wall CNT/Cu complexes and characterize the interaction between single wall CNTs and Cu nano-particle and Cu13 cluster using first principle calculations. The characteristics of functionalized CNTs with various surface functional groups, such as -COOH, -OH, and -O interacting with Cu are investigated. We found that the binding energy can be enhanced by the surface functional group including oxygen since the oxygen atom can mediate and reinforce the interaction between carbon and Cu. These results strongly support the recent experimental work which suggested the oxygen on the interface playing an important role in the excellent mechanical properties of the CNT/Cu composite.

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Interfacial Condensation Heat Transfer for Countercurrent Steam-Water Stratified Flow in a Circular Pipe

  • Chu, In-Cheol;Chung, Moon-Ki;Yu, Seon-Oh;Chun, Moon-Hyun
    • Nuclear Engineering and Technology
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    • v.32 no.2
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    • pp.142-156
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    • 2000
  • An experimental study of steam condensation on a subcooled thick water layer (0.018 ~0.032 m) in a countercurrent stratified flow has been performed using a nearly horizontal circular pipe. A total of 103 average interfacial condensation heat transfer coefficients were obtained and parametric effects of steam and water flow rates and the degree of subcooling on condensation heat transfer were examined. The measured local temperature and velocity distributions in the thick water layer revealed that there was a thermal stratification due to the lack of full turbulent thermal mixing in the lower region of the water layer Two empirical Nusselt number correlations, one in terms of average steam and water Reynolds numbers, and the water Prandtl number, and the other in terms of the Jakob number in place of the Prandtl number, which agree with most of the data within $\pm$ 25%, were developed based on the bulk flow properties. Comparisons of the present data with existing correlations showed that the present data were significantly lower than the values predicted by existing correlations.

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Research Trend in the Development of Electrocatalysts for Water Electrolysis via Interfacial Engineering (계면 제어를 통한 수전해 전기화학 촉매 개발 동향)

  • Minhui Kim;Seonggyu Lee
    • Journal of Adhesion and Interface
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    • v.25 no.2
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    • pp.50-55
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    • 2024
  • Hydrogen is attracting much attention as a renewable energy source with high energy density and environmental friendliness. Among various hydrogen production methods, water electrolysis stands out as a clean hydrogen production technique that could lead the future of hydrogen production, as it does not emit carbon, and many studies are currently underway to realize this technology. However, the high overpotential, which increases the cost of hydrogen production, acts as a stumbling block, making the development of electrocatalysts extremely important. This paper aims to summarize and introduce recent research trends in the development of electrocatalysts for hydrogen evolution reaction and oxygen evolution reaction through interfacial engineering, and to deeply discuss the challenges in implementing next-generation water electrolysis devices.

Controlled interfacial energy for UV-imprinting using resin adhesion to substrates

  • Kim, Jin-Ook;Nam, Yeon-Heui;Chae, G.S.;Chung, In-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1622-1624
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    • 2006
  • We introduce a modified UV-imprint lithography, a resin transfer from the template to the substrate. We analyzed this method by considering the surface and interfacial free energies of the template-resinsubstrate system. This technique is purely fast and applicable to large area patterning.

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A Review of Surface Energy of Solid Electrodes with Emphasis on Its Controversial Issues in Interfacial Electrochemistry

  • Go Joo-Young;Pyun Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.211-219
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    • 2004
  • A classical Lippmann equation valid for liquid electrodes can not describe the interfacial properties of solid electrodes due to the elastic surface strain on solid electrodes. Although there have been many attempts to derive the thermodynamic equations for solid electrodes Outing the past few decades, their validity has been still questioned by many researchers. In practice, although there are various experimental techniques to measure surface energy of solid electrodes, the results obtained by each technique are rather inconsistent due to the complexity of the surface strain on solid electrodes. This article covers these controversial issues in surface energy of solid electrodes. After giving brief summaries of the definition of the important thermodynamic parameters and the derivation of the thermodynamic equations for solid electrodes, the several experimental methods were introduced for the measurement of surface energy of solid electrodes. And then we discussed in detail the inconsistent results in the measurement of the potential of zero charge (pac) and the potential of electrocapillary maximum (ecm).

The Effect of Interfacial Properties and RTM Process of Composites with Different Cross-linking Density by Molecular Weight of Hardener (경화제의 분자량에 의한 가교밀도 차이에 따른 복합재료의 계면 물성 및 RTM 성형성에 미치는 영향)

  • Park, Ha-Seung;Shin, Pyeong-Su;Kim, Jong-Hyun;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.30 no.3
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    • pp.169-174
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    • 2017
  • Demand of glass fiber reinforced composites (GFRC) increased with developing aircraft and defense industries using resin transfer molding (RTM) process to produce complex product. In this research, wetting, interfacial, and mechanical properties were evaluated with different Cross-linking Density by Molecular Weight of Hardener. Epoxy resin as matrices was used bisphenol-A type and amine-type hardeners with different molecular weight. Specimens were manufactured via RTM and wetting property of resin and glass fiber (GF) mat was evaluated to viscosity of epoxy and injection time of epoxy matrix. Mechanical property of GFRC was determined via flexural strength whereas interfacial properties were determined by interlaminar shear strength (ILSS) and interfacial shear strength (IFSS). The difference in mechanical property depends upon the fiber weight fraction (wt %) of GFRC by RTM as well as the different Molecular Weight of Hardener.

Study on Enhancement for Interfacial Energy Release Rate of Adhesive Layer in Fiber Metal Laminates using Taguchi Method (다구찌 기법을 적용한 섬유금속적층판 접착층의 에너지 해방률 강화에 대한 연구)

  • Kil, Min-Gyu;Park, Eu-Tteum;Song, Woo-Jin;Kang, Beom-Soo
    • Composites Research
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    • v.29 no.5
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    • pp.249-255
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    • 2016
  • The fiber metal laminates have been widely used at aerospace industry due to outstanding fatigue characteristic, corrosion resistance and impact resistance and so forth. The objective of this research is to establish the proper manufacturing variables for enhancing the interfacial energy release rate of fiber metal laminates using Taguchi method. The major variables of the manufacturing process are surface treatment, pre-specified temperature holding time and additional pressure. In order to determine the interfacial adhesive strength, the double cantilever beam and end-notched flexure tests were conducted. Afterward, Mode I and II energy release rates at various conditions were introduced signal-to-noise ratio with respect to each condition. Finally, the most efficient manufacturing variables are recognized using larger-the-better characteristic.

Thermodynamic Issues of Lead-Free Soldering in Electronic Packaging (전자 패키징에 사용되는 무연 솔더에 관한 열역학적 연구)

  • 정상원;김종훈;김현득;이혁모
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.3
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    • pp.37-42
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    • 2003
  • In soldering of electronic packaging, the research on substituting lead-free solder materials for Pb-Sn alloys has become active due to environmental and health concerns over the use of lead. The reliability of the solder joint is very important in the development of solder materials and it is known that it is related to wettability of the solder over the substrate and microstructural evolution during soldering. It is also highly affected by type and extent of the interfacial reaction between solder and substrate and therefore, it is necessary to understand the interfacial reaction between solder and substrate completely. In order to predict the intermetallic compound (IMC) phase which forms first at the substrate/solder interface during the soldering process, a thermodynamic methodology has been suggested. The activation energy for the nucleation of each IMC phases is represented by a function of the interfacial energy and the driving force for phase formation. From this, it is predicted that the IMC phase with the smallest activation energy forms first. The grain morphology of the IMC at the solder joint is also explained by the calculations which use the energy. The Jackson parameter of the IMC grain with a rough surface is smaller than 2 but it is larger than 2 in the case of faceted grains.

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Effects of Serrated Grain Boundary Structures on Boron Enrichment and Liquation Cracking Behavior in the Simulated Weld Heat-Affected Zone of a Ni-Based Superalloy (니켈기 초내열합금의 파형 결정립계 구조가 보론 편석과 재현 열영향부 액화균열거동에 미치는 영향)

  • Hong, Hyun-Uk;Choi, June-Woo;Bae, Sang-Hyun;Yoon, Joong-Geun;Kim, In-Soo;Choi, Baig-Gyu;Kim, Dong-Jin;Jo, Chang-Yong
    • Journal of Welding and Joining
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    • v.31 no.3
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    • pp.31-38
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    • 2013
  • The transition of serrated grain boundary and its effect on liquation behavior in the simulated weld heat-affected zone (HAZ) have been investigated in a wrought Ni-based superalloy Alloy 263. Recently, the present authors have found that grain boundary serration occurs in the absence of adjacent coarse ${\gamma}^{\prime}$ particles or $M_{23}C_6$ carbides when a specimen is direct-aged with a combination of slow cooling from solution treatment temperature to aging temperature. The present study was initiated to determine the interdependence of the serration and HAZ property with a consideration of this serration as a potential for the use of a hot-cracking resistant microstructure. A crystallographic study indicated that the serration led to a change in grain boundary character as special boundary with a lower interfacial energy as those terminated by low-index {111} boundary planes. It was found that the serrated grain boundaries are highly resistant to boron enrichment, and suppress effectively grain coarsening in HAZ. Furthermore, the serrated grain boundaries showed a higher resistance to susceptibility of liquation cracking. These results was discussed in terms of a significant decrease in interfacial energy of grain boundary by the serration.