• 제목/요약/키워드: interfacial change

검색결과 214건 처리시간 0.025초

건조 상태에 따른 CNT 및 ITO로 코팅된 PET 투명전극의 표면 조절 및 내구성 평가 (Surface control and durability evaluation of CNT and ITO coated PET transparent electrode with different dry conditions)

  • 권동준;왕작가;구가영;박종만
    • Composites Research
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    • 제24권5호
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    • pp.17-22
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    • 2011
  • 최근 투명전극으로 주로 사용되고 있는 ITO 재료를 대체하가 위해 CNT를 이용한 투명전극의 활용 연구가 활발히 진행되고 있다. 본 연구에서는 건조온도에 따라 CNT와 ITO의 응집이 일어나는 정도가 달라진다는 점을 이용하여 표면을 조절하여 CNT 및 ITO가 코팅된 폴리에틸렌 테레프탈레이트 (PET)를 제조하였다. CNT를 ITO를 대신할 투명전극으로의 활용 가능성을 평가하면서, 표면의 물성 변화를 유도 하기 위해 코팅 후 건조온도를 $20^{\circ}C$, $80^{\circ}C$, 그리고 $120^{\circ}C$ 3단계로 나누어 표면을 관찰하였다. 전기저항측정법을 활용하여 재료의 내구성 및 전기적 물성을 평가함으로써 제조한 투명전극의 특성을 평가하였다. 전자현미경을 이용하여 건조온도에 따른 표면 변화를 관찰하였고, UV-스펙트럼을 통해 건조온도가 증가함에 따라 투과도가 변화하는 것을 확인하였다. 나노입자의 코팅 표면 조절에 따른 전기적 물성 변화를 확인하기 위해 순환전압전류법을 이용 하였다. CNT 코팅 표면의 내구성이 ITO 코팅 표면의 내구성보다 우수함을 알았다. 그리고, 건조온도가 높을수록 나노입자들의 응집이 크게 증가 하여 내구성이 우수한 코팅 표면을 만들며, 이에 따른 전기적 물성의 향상도 확인하였다.

서해안 준설토의 침강압밀특성에 관한 실험적 연구 (An Experimental Research About Settling and Consolidation Characteristic of Dredged Soil in West Coast)

  • 이승호;이정학
    • 한국지반환경공학회 논문집
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    • 제12권5호
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    • pp.29-36
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    • 2011
  • 본 연구에서는 침강압밀특성을 분석하기 위하여 준설투기가 예상되는 대표시료 중 점성토와 사질토를 대상으로 침강시험을 실시하였다. 분석결과 침강압밀계수($C_s$), 함수비와 계면고의 관계에서 점성토와 사질토는 뚜렷한 차이를 보이고 있다. 그러나 준설매립 직후 초기 체적변화 예측결과 점성토에서는 시간에 따른 함수비변화가 급감하였으나 사질토층에서 함수비변화에 따른 차이를 보이지 않았다. 또한 본 실험에서 적용한 실험조건에 대한 타당성 검토를 위해 실질토량고에 따른 침강압밀계수와 초기침강 속도를 분석한 결과 실험조건은 적정한 것으로 판단되며, 이와 같은 분석으로 재료 각각에 대하여 압밀침강특성치의 범위와 평균 및 대표적인 관계식을 제안하였다.

Level Contour Reconstruction 방법을 이용한 다상유동 수치해석 (NUMERICAL SIMULATION OF MULTIPHASE FLOW USING LEVEL CONTOUR RECONSTRUCTION METHOD)

  • 신승원
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2009년 추계학술대회논문집
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    • pp.193-200
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    • 2009
  • Recently, there have been efforts to construct hybrids among the existing methodologies for multiphase flow such as VOF, Level Set, and Front Tracking with the intention of facilitating simulations of general three-dimensional problems. As one of the hybrid method, we have developed the Level Contour Reconstruction Method (LCRM) for general three-dimensional multiphase flows including phase change. The main idea was focused on simplicity and a robust algorithm especially for the three-dimensional case. It combines characteristics of both Front Tracking and Level Set methods. While retaining an explicitly tracked interface using interfacial elements, the calculation of a vector distance function plays a crucial role in the periodic reconstruction of the interface elements in the LCRM method to maintain excellent mass conservation and interface fidelity. In addition, compact curvature formulation is incorporated for the calculation of the surface tension force thereby reducing parasitic currents to a negligible level.

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One-Dimensional Heterostructures Based Nanodevices

  • Myung, Nosang V.
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.3.1-3.1
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    • 2009
  • Nanotechnology has beenrapidly evolved from passive nanostructures where nanostructures with steadystructures and functions often used as parts of a product to activenanostructures which change their properties during use. Startingaround 2010, it is anticipated that researchers will cultivate expertise withsystems of nanostructures, directing large numbers of intricate components tospecified needs. One dimensional (1-D) nanostructures suchas nanowires and nanotubes are extremely attractive building blocks for nextgeneration devices because of their high surface to volume ratio and uniquesize dependent properties. In addition, their extremely high aspectratio offers researchers the potentials to build axial or radialheterostructures to integrate multiple functionality from intrinsic propertiesof the material or through interfacial phenomena. Spatialmanipulation and the ability to assemble and position nanostuructures in acontrolled matter so they are registered to define spaces is also a criticalstep toward scalable integration in high density nanodevices. In thispresentation, a generalized template directed electrodeposition with ancillaryassembly, contact will be presented to synthesize axial and radialheterostructures in cost-effective matter and these individual nanostructureswill be applied to spintronics, gas and biological sensors and thermoelectrics.

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이온도금된 Ti(C, N)피막의 물성에 대한 전자빔가열 효과 (Effects of Electron Beam Heating(EBH) on the Properties of ion Plated Ti(C, N) Films)

  • 김치명;고경현;안재환;배종수;정형식
    • 한국표면공학회지
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    • 제28권5호
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    • pp.267-275
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    • 1995
  • Electron beam can provide convenient way to heat the substrate during Hollow Cathode Discharge (HCD) ion plating of Ti(C, N)films. Densification of columnar structrue is enhanced by longer duration of electron beam heating(EBH). While strong(111) texture is identified always to be formed, the amount of (200) oriented grains which coherently interfaced with carbide particles of the substrate increased with heating(EBH). In turns, these crystallogaphical change lead to the increase of micro hardness and adhesion of coating. Adhesion of Ti(C, N) films increased more dramatically in case of ASP30 substrate of which carbide particles dispersed more finely than M42. Therefore, it could be concluded that both the density of film and interfacial structure can affect the adhesion property. Overheating of substrate could be resulted in low adhesion resistance due to high residual stress developed in the film.

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Dissolution and Reprecipitation Behavior of TiC-TiN-Ni Cermets During Liquid-Phase Sintering

  • Yoon, Choul-Soo;Shinhoo Kang;Kim, Doh-Yeon
    • The Korean Journal of Ceramics
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    • 제3권2호
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    • pp.124-128
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    • 1997
  • An attempt was made to understand the dissolution and reprecipitation behavior of the constituent phases such as TiC, TiN, and Ti(CN) in TiC-TiN-Ni system. During the liquid-phase sintering the TiC phase was found to dissolve preferentially in Ni binder. The solid-solution phase, Ti(CN), formed around the TiN phase, resulting in a core/rim structure. This result was reproduced when large TiC particles were used with fine TiN particles. The path for the microstructural change in TiC-TiN-Ni system was largely controlled by the difference in the interfacial energy of each phase with the liquid binder phase. The results were discussed with thermodynamic principles.

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Al2O3/Cu 나노복합체 제조공정에 따른 미세조직 특성 (Microstructural Characteristics of Al2O3/Cu Nanocomposites Depending on Fabrication Process)

  • 강계명;오승탁
    • 한국재료학회지
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    • 제13권1호
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    • pp.59-63
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    • 2003
  • The microstructural characteristics of $Al_2$$O_3$/Cu composites hot-pressed at different temperatures for atmosphere switching from $H_2$to Ar have been studied. When the composite atmosphere was switched at $1000^{\circ}C$ it led to more homogeneous microstructure than when the atmosphere was switched at $1450^{\circ}C$. The strong sensitivity of Cu to atmosphere, especially the oxygen content in the atmosphere, was found to be responsible for the observed change, based upon the interfacial phenomena related to the formation of $CuAlO_2$. The practical implication of these results is that an optimum processing condition for the design of homogeneous microstructure and stable properties can be established.

중간재가 질화규소/스테인레스 스틸 접합체의 굽힘강도에 미치는 영향 (Effect of Interlayers on the Bending Strength of Silicon Nitride/Staineless Steel Joints)

  • 박상환;최영화;김태우
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.251-258
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    • 1996
  • The reactions between an active metal brazing alloy and interlayers together with the effects of interlayer type on the interfacial microstructure change were investiaged for silicon nitride/stainless steel joint. The bending strengths were measured for joints with Mo, Cu, Ni interlayer type of different thicknesses. It was found that the interlayer with a low yield strength value is effective to improve the bending strength of the Si3N4/stainless steel joint. The maximum joint strength obtained at room temperature for a laminated Cu/Mo interlayer was about 460 MPa. The combined use of Mo and thin Cu layer was found to be effective in enhancing the bending strength for the Si3N4/S.S.316 joint.

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Relationships between Antithrombogenicity and Surface Free Energy of Regenerated Silk Fibroin Films

  • Park, Won Ho;Ha, Wan Shik;Ito, Hiraku;Miyamoto, Takeaki;Inagaki, Hiroshi;Noishiki, Yasuharu
    • Fibers and Polymers
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    • 제2권2호
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    • pp.58-63
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    • 2001
  • Silk fibroin (SF) was dissolved in calcium chloride/ethanol/water mixture(1/2/8 in mole ratio) at $70^{\circ}C$ for 4h. The dissolved silk fibroin was regenerated by casting the dialyzed solution into films. The films were treated with 50% aqueous solution of methanol for different times, and their antithrombogenicity was evaluated by in vivo tests. In vivo blood tests were made by a method of peripheral vein indwelling suture. It was found that the silk fibroin had a good antithrombogenicity and an absorbability even though the polymer showed foreign body reaction. Finally, the blood compatibilty of silk fibroin films which were subjected to structural change by the methoanl treatment, was examined in connection with their interfacial surface energy, and a correlation between these properties was found to be present.

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Investigating loading rate and fibre densities influence on SRG - concrete bond behaviour

  • Jahangir, Hashem;Esfahani, Mohammad Reza
    • Steel and Composite Structures
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    • 제34권6호
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    • pp.877-889
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    • 2020
  • This work features the outcomes of an empirical investigation into the characteristics of steel reinforced grout (SRG) composite - concrete interfaces. The parameters varied were loading rate, densities of steel fibres and types of load displacement responses or measurements (slip and machine grips). The following observations and results were derived from standard single-lap shear tests. Interfacial debonding of SRG - concrete joints is a function of both fracture of matrix along the bond interface and slippage of fibre. A change in the loading rate results in a variation in peak load (Pmax) and the correlative stress (σmax), slip and machine grips readings at measured peak load. Further analysis of load responses revealed that the behaviour of load responses is shaped by loading rate, fibre density as well as load response measurement variable. Notably, the out-of-plane displacement at peak load increased with increments in load rates and were independent of specimen fibre densities.