• Title/Summary/Keyword: interface treatment

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An Ultrathin Polymer Network through Polyion-Complex by Using Sodium Dioctadecyl Sulfate as Monolayer Template

  • Lee, Burm-Jong;Kim, Hee-Sang;Kim, Seong-Hoon;Son, Eun-Mi;Kim, Dong-Kyoo;Shin, Hoon-Kyu;Kwon, Young-Su
    • Bulletin of the Korean Chemical Society
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    • v.23 no.4
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    • pp.575-579
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    • 2002
  • Two-dimensionally cross-linked ultrathin films of poly(maleic acid-alt-methyl vinyl ether) (MA-MVE) and poly(allylamine) (PAA) were produced by using sodium dioctadecyl sulfate (2C18S) as the monolayer template for Langmuir-Blodgett (LB) depositio n. The template molecules were subsequently removed by thermal treatment followed by extraction. The polyion-complexed monolayers of three components, i.e., template 2C18S, co-spread PAA, and subphase MA-MVE, were formed at the air-water interface. Their monolayer properties were studied by the surface pressure-area isotherm. The monolayers were transferred on solid substrates as Y type. The polyion-complexed LB films and the resulting network films were characterized by FT-IR spectroscopy, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The cross-linking to form a polymer network was achieved by amide or imide formation through heat treatment under a vacuum. SEM observation of the film on a porous fluorocarbon membrane filter (pore diameter 0.1 ㎛) showed covering of the pores by four layers in the polyion complex state. Extraction by chloroform followed by heat treatment produced hole defects in the film.

APPLICATIONS OF SERICITE IN WASTEWATER TREATMENT : REMOVAL OF Cu(II) AND Pb(II) FROM AQUEOUS SOLUTIONS

  • Tiwari, Diwakar;Kim, Hyoung-Uk;Lee, Seung-Mok
    • Environmental Engineering Research
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    • v.11 no.6
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    • pp.303-310
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    • 2006
  • The aim of this study is to assess the applicability of sericite in wastewater treatment particularly the removal of two important heavy metal toxic ions viz., Cu(II) and Pb(II) from aqueous solutions. The batch type experiments showed that sericite is found to be one of useful natural sorbent for the removal of these two cations from aqueous solutions and it is also to be observed that with the increase in sorptive concentration amount of metal uptake increases and the concentration dependence data obtained are fitted well for the Langmuir adsorption isotherm rather than Freundlich adsorption model. Further, the Langmuir monolayer adsorption capacity is found to be $1.674\;mg\;g^{-1}$ for Cu(II) and $4.697\;mg\;g^{-1}$ for Pb(II). Kinetic studies enabled, an apparent equilibria can be achieved between soild/solution interface within ca 10 mins for Cu(II) and ca 90 mins for Pb(II). Moreover, the removal behavior of sericite for these two metal ions is greatly influenced by solution pH.

An Insulation Life Time of the Epoxy Composites according to Breakdown Time (파괴시간을 이용한 에폭시 복합체의 절연수명)

  • Shin, C.G.;Kim, J.S.;Cho, C.N.;Lee, D.K.;Lee, S.I.;Park, G.H.;Kim, C.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04b
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    • pp.8-9
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    • 2008
  • In the procedure of the estimation, the short time breakdown characteristics for the epoxy composite specimens, which were made with the variation of hardener and/or filler, were tested firstly. Then the long time voltage-to-time test was implemented. Finally, the long time breakdown voltage of each specimen was estimated with the parameters obtained from the statistical treatment with Weibull distribution. Base on the results, it has been found that the optimal weight ratio of epoxy resin/hardener/filler that has the excellent long time breakdown characteristic was 100/100/65. It was due to the silane treatment which relieves the electric field at the interface between filler and epoxy.

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Crystalline Phases and Superconductor Characteristics of the Plasma Sprayed YBa2Cu$\chi$O7-y High Tc Superconductor Thick Film (플라즈마 용사법에 의해 제조된 YBa2Cu$\chi$O7-y(X=3, 3.5, 4) 고온초전도체 후막층의 결정상 및 초전도 특성)

  • 한명섭;서동수
    • Journal of the Korean Ceramic Society
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    • v.29 no.2
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    • pp.152-160
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    • 1992
  • High-Tc superconductor thick films of YBa2Cu$\chi$O7-y (X=3, 3.5, 4) of which thickness varies from 100 $\mu\textrm{m}$ to 200 $\mu\textrm{m}$ were successfully prepared by plasma spraying method, and the characteristics of thick film depending on copper content and heat treatment conditions were investigated. Regardless of heat-treated temperature, the specimens with X=3 were composed of YBa2Cu$\chi$O7-y, Y2BaCuO5 and BaCuO3 phases. The specimens with X=4, however, were composed of YBa2Cu$\chi$O7-y phase at all heat treatment conditions. The specimens with X=4 composition showed the best superconducting characteristics after heat treatment at 925$^{\circ}C$, and the superconducting transition temperature with zero resistivity (Tc,zero) was 87K. The thick film lost superconductivity when the specimens were heat-treated at 950$^{\circ}C$ because of interdiffusion between superconductor elements and bond coating elements and Y2BaCuO5 phase was found was found to be main phase at the interface.

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The development of discharge reactor for water purification and the fundamental study on the change of water characteristics (수질 개선용 방전 리액터의 개발과 기본적 수질 특성 변화 조사)

  • Han, Sang-Bo;Park, Jae-Youn;Kim, Jong-Seog;Jung, Jang-Gun;Koh, Hee-Seog;Lee, Hyun-Woo
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2193-2195
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    • 2005
  • The hybrid discharge reactor was designed for the application of wastewater treatment and the removal of hazardous volatile organic substances in water. This discharge type was similar to the barrier discharge, and the surface discharge on the dielectric surface was propagated to the water surface. That caused the heterogeneous chemical reaction strongly at the interface between the working gases and the water surface. Changes of the conductivity, acidity, and the dissolved ozone with respect to the treatment time and water quantities were studied as the fundamental experiment. The concentration of hydrogen ions largely increased with increasing the treatment time and the conductivity increased with respect to the increase of water quantities under the constant other discharge parameters.

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A Study on the Interfacial Phenomena As Heat treatment of SiCw/Al Composites (SiCw/Al 복합재료의 열처리에 따른 계면 현상에 관한 연구)

  • Oh, Hyeok-Jin;Bang, Myung-Sung;Lee, Eui-Kil;Nam, Seoung-Eui
    • Journal of Korea Foundry Society
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    • v.12 no.6
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    • pp.464-470
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    • 1992
  • In the present study, the effects of Al/SiC interface reaction and the formation of $Al_4C_3$ compounds on the mechanical properties of the Al/SiC composites prepared by squeeze casting were investigated. After squeeze casting, the size of dendrites in Al without whiskers were larger than those with whiskers. The hardness of composite materials (about 72 Hv) was found to be approximating 40% higher than that of matrix metal (29Hv), which gradually increases which heat treatment Time showing maximum hardness at 12hr. The observation of increasing number of compounds in 12hrs heat treatment suggests that these compounds are responsible for the increase of hardness. By X-ray diffraction studies, those compounds were identified as $Al_4C_3$, (Al, Si). And intensity of Si peak increased. The tensile strengh of composite materials was gradually decresed by heat tretment, which was in contrast to the behavior of hardeness. With incresing heat tretment time, the fracture mode of composite materials was changed from large dimples and pull-out form of fiber to the fracture and rupture foum of fiber.

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Effects of Hydration Treatments on the Phase Transition of Anodic Aluminum Oxide Layers (알루미늄 양극산화 피막의 상전이에 미치는 수화처리의 영향)

  • Joo, E.K.;Kim, S.S.;Oh, H.J.;Cho, S.H.;Chi, C.S.
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.540-544
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    • 2002
  • Hydration treatments were performed on the pure aluminum substrate at $100^{\circ}C$ followed by anodizing and heat treatments on the layers. The transformation behaviors of the oxide layers according to the hydration treatment were studied using TEM, XRD, RBS etc. Above $90^{\circ}C$ the hydrous oxide film could be formed, which were turned out to be hydrous oxides(AlOOH $nH_2$O). The anodization on the hydrous oxide film was more effective for the transition of amorphous anodic oxides to the crystalline $\Upsilon-Al_2$ $O_3$ comparing with the case for anodizing on the aluminum substrate without hydration treatment And additional heat treatments were also helpful for the acceleration of the transformation of the hydrous oxide to $\Upsilon-Al_2$ $O_3$. During the heat treatment the interface between $\Upsilon-Al_2$ $O_3$and the hydrous oxide layers migrated to the outer side of hydrous layer.

A Study on the Analysis of the Spatial Composition of Rehabilitation Department in Regional Public Hospital (지방의료원 재활의학부의 공간구성 분석 연구)

  • Lee, Joorang;Chai, Choul Gyun
    • Journal of The Korea Institute of Healthcare Architecture
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    • v.27 no.1
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    • pp.35-44
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    • 2021
  • Purpose: To presenting basic data for the spatial composition required when planning the future department of rehabilitation medicine by analyzing the spatial composition of the location, size, area, and plan type of the rehabilitation department of the Regional Public Hospital. Methods: 3 Methods have been used in this paper. 1) Analyzing drawings to derive the net floor area of each room. 2) A literature survey about rehabilitation healthcare system. 3) Observation survey for user circulation analysis. Results: 1) Rehabilitation is an overall process of treatment that helps to play a role as an individual in society, away from the perspective of treating physical damage. The Department of Rehabilitation Medicine of the local medical center must provide rehabilitation medical services corresponding to the recovery and maintenance period for community rehabilitation. 2) The Department of Rehabilitation Medicine can be classified into diagnostics area, examination area, treatment area, management area, and interface area based on the rehabilitation treatment process. Implication: It can be used as basic data when planning related facilities by analyzing the characteristics of the space plan of the required room according to the relationship between activities, movement lines, and operation plans based on user behavior.

Bond behavior between circular steel tube and high-strength concrete after elevated temperatures

  • Ji, Zhou;Zongping, Chen;Maogen, Ban;Yunsheng, Pang
    • Structural Engineering and Mechanics
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    • v.84 no.5
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    • pp.575-590
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    • 2022
  • In this paper, bond-slip behavior of high strength concrete filled circular steel tube (HSCFCST) after elevated temperatures treatment was studied. 17 specimens were designed for push-out test. The influence was discussed as following parameters: (a) concrete strength, (b) constant temperature, and (c) bond length. The results showed that (1) after elevated temperatures treatment, the bond strength of the HSCFCST specimens increased first and then decreased with temperature rising; (2) the bond strength increased with the increase of concrete strength at room temperature, while the influence subsided after elevated temperatures treatment; (3) the strain of the circular steel tube was distributed exponentially along its length, the stress changed from exponential distribution to uniform distribution with the increase of load; (4) the bond damage process was postponed with the increase of constant temperature; and (5) the energy consumption capacity of the bonding interface increased with the rise of concrete strength and constant temperature. Moreover, computational formulas of ultimate and residual bond strength were obtained by regression, and the bond-slip constitutive models of HSCFCSTs after elevated temperatures was established.

Recovery of Radiation-Induced Damage in MOSFETs Using Low-Temperature Heat Treatment (저온 열처리를 통한 MOSFETs 소자의 방사선 손상 복구)

  • Hyo-Jun Park;Tae-Hyun Kil;Ju-Won Yeon;Moon-Kwon Lee;Eui-Cheol Yun;Jun-Young Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.5
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    • pp.507-511
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    • 2024
  • Various process modifications have been used to minimize SiO2 gate oxide aging in metal-oxide-semiconductor field-effect transistors (MOSFETs). In particular, post-metallization annealing (PMA) with a deuterium ambient can effectively eliminate both bulk traps and interface traps in the gate oxide. However, even with the use of PMA, it remains difficult to prevent high levels of radiation-induced gate oxide damage such as total ionizing dose (TID) during long-term missions. In this context, additional low-temperature heat treatment (LTHT) is proposed to recover from radiation-induced damage. Positive traps in the damaged gate oxide can be neutralized using LTHT, thereby prolonging device reliability in harsh radioactive environments.