• Title/Summary/Keyword: interface energy

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Microstructure Observation of the Grain Boundary Phases in ATF UO2 Pellet with Fission Gas Capture-ability (핵분열 기체 포획 기능을 갖는 사고저항성 UO2 펠렛에서 형성되는 입계상의 미세구조 관찰)

  • Jeon, Sang-Chae;Kim, Dong-Joo;Kim, Dong Seok;Kim, Keon Sik;Kim, Jong Hun
    • Journal of Powder Materials
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    • v.27 no.2
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    • pp.119-125
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    • 2020
  • One of the promising candidates for accident-tolerant fuel (ATF), a ceramic microcell fuel, which can be distinguished by an unusual cell-like microstructure (UO2 grain cell surrounded by a doped oxide cell wall), is being developed. This study deals with the microstructural observation of the constituent phases and the wetting behaviors of the cell wall materials in three kinds of ceramic microcell UO2 pellets: Si-Ti-O (STO), Si-Cr-O (SCO), and Al-Si-Ti-O (ASTO). The chemical and physical states of the cell wall materials are estimated by HSC Chemistry and confirmed by experiment to be mixtures of Si-O and Ti-O for the STO; Si-O and Cr-O for SCO; and Si-O, Ti-O, and Al-Si-O for the ASTO. From their morphology at triple junctions, UO2 grains appear to be wet by the Si-O or Al-Si-O rather than other oxides, providing a benefit on the capture-ability of the ceramic microcell cell wall. The wetting behavior can be explained by the relationships between the interface energy and the contact angle.

A Protocol Interface for Energy-efficient Network Management in Ubiquitous Sensor Networks (유비쿼터스 센서네트워크에서 에너지 효율적인 망관리 프로토콜 인터페이스)

  • Kim, Byoung-Kug;Hur, Kyeong;Eom, Doo-Seop
    • Journal of Korea Multimedia Society
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    • v.13 no.8
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    • pp.1221-1234
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    • 2010
  • MANET(Mobile Ad-hoc Network)s have been researched primary at routing protocols and at the guarantees of QoS(Quality of Service) for mobile environments. Otherwise the Ubiquitous Sensor Networks (USNs) have some limitations in power energies and in processing of sensing data, as well as their network topologies are frequently changed by fading off and node failures. Thus we should redesign network protocols with concerning to energy efficiency for the USNs above all. In this paper, we focus on the protocol interface for managing for USNs based on the surveys. And then we figure the topology of USNs out and design the network protocol interface to make power saved, with data gathering and processing more efficient using our designed packet structures.

Physicochemical Properties of Phosphatidylcholine (PC) Monolayers with Different Alkyl Chains, at the Air/Water Interface

  • Yun, Hee-Jung;Choi, Young-Wook;Kim, Nam-Jeong;Sohn, Dae-Won
    • Bulletin of the Korean Chemical Society
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    • v.24 no.3
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    • pp.377-383
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    • 2003
  • Physicochemical properties of a series of PC monolayers with different alkyl chains (C24, C20, C16, and C8), at the air/water interface were investigated. The surface pressure is influenced mainly by the hydrophobicity of the PCs, which is confirmed by the curve shape and the on-set value of π-A isotherms at the air/water interface by increasing the number of alkyl chain. The on-set values of surface pressure were 125 Ų/molecule for DOPC(C8), 87 Ų/molecule for DPPC(C16), 75 Ų/molecule for DAPC(C20), and 55 Ų/molecule for DLPC(C24), respectively. The orientations of alkyl chains at the air/water interface are closely connected with the rigidity of the monolayers, and it was confirmed by the tendency of monolayer thickness in ellipsometry data. The temperature dependence of a series of PCs shows that the surface pressure decreases by increasing temperature, because the longer the alkyl chain length, the larger the hydrophobic interaction in surface pressure. The temperature effects and the conformational changes of unsaturated and saturated PCs were confirmed by the computer simulation study of the cis-trans transition with POPC and DPPC(C16). The cistrans conformational energy difference of POPC is 62.06 kcal/mol and that of DPPC(C16) is 6.75 kcal/mol. Due to the high conformational energy barrier of POPC, phase transition of POPC is limited in comparison with DPPC(C16).

Determination of Energy Release Rate of Penny-shaped Interface Crack on Bimaterial Cylinder (동전모양 균열이 존재하는 이상복합체의 에너지해방율 산정)

  • 양성철;서영찬;박종원
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.15 no.3
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    • pp.389-398
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    • 2002
  • The mixed mode problem (I and II) of a peny-shaped interface cracks in remote tension loading on a bi-material cylinder is studied using finite element method. The energy release rates for the tip of the crack in the interface were calibrated for several different moduli combinations and crack ratios using the modified crack closure integral technique and J-integral method, with numerical results obtained from a commercial finite element program. Numerical results show that non-dimensional value of$\sqrt{G_{II}E^*}/\sqrt[p]{\pi a}$ increases as the crack size or moduli ratio increases. Meanwhile, non-dimensional value of$\sqrt{G_{I}E^*}/\sqrt[p]{\pi a}$ decreases as the moduli ratio increases, but above the moduli ratio of 3 its value decreases then increases again as the crack size increases. Reliability of the numerical analysis in this study was acquired with comparison to an analytical solution for the peny-shaped interface crack in an infinite medium.

Interfacial Characteristics of Epoxy Composites Filled with γ-APS Treated Natural Zeolite (γ-APS로 표면처리된 천연 제올라이트/에폭시 복합재료의 계면특성)

  • Lee, Jae-Young;Lee, Sang-Keun;Kim, Sang-Wook
    • Journal of Adhesion and Interface
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    • v.2 no.3
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    • pp.1-8
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    • 2001
  • Epoxy composites filled with natural zeolite was prepared to investigate the effects of silane coupling agent, ${\gamma}$-APS (${\gamma}$-aminopropyltriethoxysilane)on the surface free energy, tensile properties and interfacial morphology. The value of Lifshitz-van der Waals component, ${\gamma}{\frac{LW}{SV}}$ for polar was $19.22mJ/m^2$ and increased, while that of Lewis acid-base component, ${\gamma}{\frac{AB}{SV}}$ for polar was $15.27mJ/m^2$ and decreased with the increasing content of ${\gamma}$-APS treatment. It is due that the surface of the zeolite is more coated by hydrophobic of alkyl group than hydrophilic amine or hydroxyl group. The tensile strength and Young's modulus of epoxy system were improved by the treatment with ${\gamma}$-APS due to the strong interface bonding, which was confirmed by SEM.

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Energy Management Services based on Wireless Sensors and Home Gateway

  • Hwang, Jong-Woon;Seo, Jeong-Ho;Kim, Woong-Hee
    • 한국IT서비스학회:학술대회논문집
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    • 2010.05a
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    • pp.151-154
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    • 2010
  • In this paper, we propose an energy monitoring and management service based on wireless sensors and a home gateway for homes and buildings. Homes and buildings have a significant energy saving potential compared with other sectors. Sensing, monitoring, and managing of the information on the energy consumption are required for an efficient energy saving service. The proposed system is composed of two main components, wireless sensor and an intelligent home gateway. Wireless sensors have the ZigBee communication interface for communication, and the intelligent home gateway is an energy portal. We expect that energy saving could be achieved with this system. As a further work, we will analyze the practical impact of the proposed service.

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Determination of Bond Strength and Fracture Energy of a Bi-material Cylinder with Peny-shaped Interface Crack by Pull-off Test (직접인장시험에 의한 원형 비부착면이 삽입된 신.구 콘크리트의 부착강도 및 파괴에너지 산정)

  • Yang, Sung-Chul;Kim, Jin-Chul;Park, Jong-Won
    • International Journal of Highway Engineering
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    • v.6 no.1 s.19
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    • pp.47-56
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    • 2004
  • To determine the pure bond strength between substrate and its overlayed concrete material, a direct pull-off test method was introduced by using a bi-material cylinder with which a penny-shaped crack was mountained at its interface. First, to evaluate the stress magnification or concentration at the interface, the energy release rates of a penny-shaped interface crack in remote tension loading on a bi-material cylinder were determined in terms of different modulus ratios and undonded area ratios(crack ratios) using a commercial finite element program. Then the energy release rates were calibrated as non-dimensional values in consideration of structural dimensions and applied forces. And to evaluate whether this new pull-off test method gives sound test results, three different sizes of unbended area ratios were incorporated along their interface in bi-material cylinders(sulphur polymer concrete + old concrete). Test results showed that all specimens were broken off at their interfaces as intended. Also the FEM analyses and test results indicated that a bi-material specimen with unbended area ratio of 0.4$\sim$0.6 is suitable for best accurate testing.

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Effects of Ar/N2 Two-step Plasma Treatment on the Quantitative Interfacial Adhesion Energy of Low-Temperature Cu-Cu Bonding Interface (Ar/N2 2단계 플라즈마 처리에 따른 저온 Cu-Cu 직접 접합부의 정량적 계면접착에너지 평가 및 분석)

  • Choi, Seonghun;Kim, Gahui;Seo, Hankyeol;Kim, Sarah Eunkyung;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.2
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    • pp.29-37
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    • 2021
  • The effect of Ar/N2 two-step plasma treatment on the quantitative interfacial adhesion energy of low temperature Cu-Cu bonding interface were systematically investigated. X-ray photoelectron spectroscopy analysis showed that Ar/N2 2-step plasma treatment has less copper oxide due to the formation of an effective Cu4N passivation layer. Quantitative measurements of interfacial adhesion energy of Cu-Cu bonding interface with Ar/N2 2-step plasma treatment were performed using a double cantilever beam (DCB) and 4-point bending (4-PB) test, where the measured values were 1.63±0.24 J/m2 and 2.33±0.67 J/m2, respectively. This can be explained by the increased interfacial adhesion energy according phase angle due to the effect of the higher interface roughness of 4-PB test than that of DCB test.

Analysis of Acoustic Emission Signal During Contact Start/stop Test on Computer Hard Disk (컴퓨터 하드디스크의 CSS 테스트에 의한 AE 신호 해석)

  • Hwang, Pyung;Kim, Woo-Seok;Kim, Do-Hyung
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.06a
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    • pp.170-174
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    • 1999
  • In order to analysis contact mechanism of head/ disk interface on hard disk drive, many techniques of analysis have been developed. Acoustic Emission sensor can be used for detect elastic energy of contact at head/disk interface. This work presents a good understanding of slider characteristics in frequency domain. The results show that torsional and bending mode of slider are dominant in head/disk contact.

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광반응 폴리이미드위에 RF bias sputtering 방식으로 증착된 Cr의 접착력에 관한 연구

  • 김선영;김영호;윤종승
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2001.11a
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    • pp.171-177
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    • 2001
  • The adhesion enhancement from inserting a RF bias-sputtered Cr layer between Cu and polyimide (PI) has been studied. The RF bias power applied in this study was ranged from 0 to 400 W. Without the RF bias, the peel strength, which measures the adhesion strength, was nearly o g/mm. As the RF power was increased, the peel strength rose up to ~130 g/mm at 200 W, which remained constant with further increase of the RF bias power. Cross-sectional transmission electron microscopy(TEM) was used to investigate the interfacial reaction between the Cr film and PI substrate during the bias sputtering. The Cr/PI interface without the application of RF dais showed a clean, sharp interface while the RF raised Cr/PI interface had about 10~30 nm thick atomistically mixed interlayer between the metal film and PI substrate. This interlayer appeared to have resulted from the implantation of high energy adatoms during the RF bias sputtering of Cr film. This mixed layer serves as an interlocking layer, which enhances adhesion between the metal and PI layers.

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