• Title/Summary/Keyword: interface energy

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Development of a New Software to Analyze Displacement and Predict Failure Time of the Rock Slope (암반사면 변위자료 분석 및 파괴시간 예측 소프트웨어 개발)

  • Noh, Young-Hwan;Um, Jeong-Gi
    • Tunnel and Underground Space
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    • v.25 no.1
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    • pp.76-85
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    • 2015
  • We have developed a software to predict failure time of the rock slope based on analysis of the data from real time displacement measurements with respect to time. The software consists of four modules that play roles in analytical methods such as inverse velocity method, log time-log velocity method, log velocity-log acceleration method and nonlinear least square method to estimate failure time. VisualBasic.NET on the MS Visual Studio platform was utilized as a development tool to efficiently implement the modules and the graphical user interface of the software. Displacement data obtained from laboratory physical model studies of plane sliding were used to explore the applicability of the software, and to evaluate the possibility of predicting potential slope failure. It seems possible to estimate failure time using developed software for sliding plane having exponential type of deformability.

Properties of Synthesis LSCF Cathode with pH Control using Oxalate Method (Oxalate법으로 합성한 LSCF의 pH 변화에 따른 공기극 특성)

  • Lee, Mi-Jai;Choi, Byung-Hyun;Kim, Sei-Ki;Lee, Mi-Jung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.17-18
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    • 2007
  • Solid oxide fuel cells are clean, pollution-free technology for the electrochemical generation of electricity at high efficiency. Specially, the polarization resistance between electrolyte and electrode of SOFC unit cell is of importance, because it is desirable to develop SOFC operating at intermediate temperature below $800^{\circ}C$. The LSCF cathode prepared using modified oxalate method was investigated with different electrolyte. A precursor was prepared with oxalic acid, ethanol and $NH_4OH$ solution. The LSCF precursor was prepared at $80^{\circ}C$, and pH control was 2, 6, 8, 9 and 10. The precursor powder was calcined at $800^{\circ}C$, $1000^{\circ}C$ and $1200^{\circ}C$ for 4hrs. The crystal of LSCF powders show single phase at pH 2, 6, 8 and 9, and the average particle size was about $3{\mu}m$. The LSCF cathode with heat treatment at $1200^{\circ}C$ showed a plot of electric conductivity versus temperature. Unit cell prepared from the LSCF cathode, buffer layer between cathode and electrolyte and the LSGM, YSZ, ScSZ and CeSZ electrolyte. Also interface reaction between LSCF, buffer layer and electrolyte were measured by EPMA and the polarization resistance for unit cell with cycle measure using a Solatron 1260 analyzer.

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The study on photoreflectance characteristics of the $Al_xGa_{1-x}As$ epilayer grown by MBE method (MBE 법으로 성장시킨 $Al_xGa_{1-x}As$ 에피층의 Photoreflectance 특성에 관한 연구)

  • 이정렬;김인수;손정식;김동렬;배인호;김대년
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.341-347
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    • 1998
  • We analyzed photoreflectance (PR) characterization of the $Al_xGa_{1-x}As$ epilayer grown by molecular beam epitaxy (MBE) method. The band-gap energy $(E_0)$ satisfying low power Franx-Keldysh (LPFK) due to GaAs buffer layer is 1.415 eV, interface electricall field $(E_i)$ is 1.05$\times$$10^4$V/cm, carrier concentration (N) is $1.3{\times}10^{15}\textrm{cm}^{-3}$. In PR spectrum intensity analysis at 300 K the $A^*$ peak below $(E_0)$ signal is low and distorted because of residual impurity in sample growth. The trap characteristic time ${\tau}_i$ of GaAs buffer layer is about 0.086 ms, and two superposed PR signal near 1.42eV consist of the third derivative signal of chemically eteched GaAs substrate and Franz-Keldysh oscillation (FKO) signal due to GaAs buffer layer.

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Secure Configuration Scheme for Internet of Things using NFC as OOB Channel (NFC를 OOB 채널로 활용한 사물인터넷 보안 설정 기술)

  • Kim, Jeongin;Kang, Namhi
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.16 no.3
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    • pp.13-19
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    • 2016
  • The PSK (Pre-shared Secret Key) based method is appropriate for the IoT environment consisting of lightweight devices since this method requires less computing time and energy than the method to configure the session key based on the public key algorithm. A fundamental prerequisite for the PSK based method is that PSK should have been configured between the communication entities safely in advance. However, in case of a small sensor or actuator, no input and output interface such as keyboard and monitor required for configuration exists, so it is more difficult to configure PSK for such lightweight devices safely in the IoT environment than the previous Internet devices. Especially, normal users lack expertise in security so they face difficulty in configuration. Therefore, the default value configured at the time of manufacturing at factories is used or the device installer configures PSK in most cases. In such case, it is a matter for consideration whether all installers and manufacturers can be trusted or not. In order to solve such problem, this paper proposes a secure bootstrapping scheme, which utilizes the NFC (Near Field Communication) as an OOB (Out-Of-Band) channel, for lightweight devices with limited resources.

Interface chemistry of SiC/Co reaction (SiC/Co 반응의 계면화학)

  • ;Hubertus Nickel
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.2
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    • pp.109-121
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    • 1995
  • Reaction coulples of SiC with cobalt were annealed in an Ar/4 vol% $H_2$ atmosphere at temperatures between $950^{\circ}C$ and $1250^{\circ}C$for various times between 4 and 100 h. At temperatures above $950^{\circ}C$, solid state reactions lead to the formation of various silicides with carbon precipitates. The typical reaction layer sequence was $SiC/CoSi + C/CozSi + C/CozSi/CozSi + C/{\cdot\cdot\}/CO_2Si/CO$ in the reaction zone. The mechanism of the periodic band structure formation with the carbon precipitation behaviour was examined and discussed in terms of reaction kinetics and thermodynamic considerations. The growth of the reaction zone has a square root of time dependence. The reaction kinetics is proposed to estimate the effective reaction constant from the parabolic gowth of the reaction zone. The mechanical properties of the reaction zones were determined by the microhardness test.

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Microstructural, Mechanical, and Durability Related Similarities in Concretes Based on OPC and Alkali-Activated Slag Binders

  • Vance, Kirk;Aguayo, Matthew;Dakhane, Akash;Ravikumar, Deepak;Jain, Jitendra;Neithalath, Narayanan
    • International Journal of Concrete Structures and Materials
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    • v.8 no.4
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    • pp.289-299
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    • 2014
  • Alkali-activated slag concretes are being extensively researched because of its potential sustainability-related benefits. For such concretes to be implemented in large scale concrete applications such as infrastructural and building elements, it is essential to understand its early and long-term performance characteristics vis-a'-vis conventional ordinary portland cement (OPC) based concretes. This paper presents a comprehensive study of the property and performance features including early-age isothermal calorimetric response, compressive strength development with time, microstructural features such as the pore volume and representative pore size, and accelerated chloride transport resistance of OPC and alkali-activated binder systems. Slag mixtures activated using sodium silicate solution ($SiO_2$-to-$Na_2O$ ratio or $M_s$ of 1-2) to provide a total alkalinity of 0.05 ($Na_2O$-to-binder ratio) are compared with OPC mixtures with and without partial cement replacement with Class F fly ash (20 % by mass) or silica fume (6 % by mass). Major similarities are noted between these binder systems for: (1) calorimetric response with respect to the presence of features even though the locations and peaks vary based on $M_s$, (2) compressive strength and its development, (3) total porosity and pore size, and (4) rapid chloride permeability and non-steady state migration coefficients. Moreover, electrical impedance based circuit models are used to bring out the microstructural features (resistance of the connected pores, and capacitances of the solid phase and pore-solid interface) that are similar in conventional OPC and alkali-activated slag concretes. This study thus demonstrates that performance-equivalent alkali-activated slag systems that are more sustainable from energy and environmental standpoints can be proportioned.

A study on interfacial characteristics of Ni-Cr alloy by Nb content for Porcelain Fused to Metal Crown (금속소부도재관용 Ni-Cr 합금에 첨가된 Nb이 계면특성에 미치는 영향)

  • Kim, Chi-Young;Choi, Sung-Min
    • Journal of Technologic Dentistry
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    • v.27 no.1
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    • pp.97-104
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    • 2005
  • The effect of Nb on interfacial bonding characteristics of Ni-Cr alloy for porcelain fused to metal crown (PFM) has been studied in order to investigate oxide layer. A specimens, which is 0.8mm in thickness, were fired at 1,000$^{\circ}C$ with four tests such as air, vacuum, air for 5 minutes and vacuum for 5 minutes in order to examine an oxide behavior of alloy surface generated by the adding of Nb to be controlled at a rate of 0, 1, 3 and 5. It observed oxide film form of the fired specimens with optical microscope and scanning electron microscope (SEM), and chemical formation of them with energy disperse X-ray spectroscopy (EDX). The other specimens, which is 2mm in thickness, were fired at 1,000$^{\circ}C$ with air and vacuum in order to analyze the diffusion behaviors of alloy-porcelain interface by X-ray dot mapping. The results of this study were as follows: 1. The observation of microstructure of specimens by SEM showed that the more Nb content is high, the more much intermediate compound of rich Nb is observed. 2. The surface morphology of oxide film is most dense in 3% Nb. The heat treatment in air constitutes denser oxide film than heat treatment under vacuum. 3. The diffusion behavior of oxide layer by X-ray dot mapping showed that Si, Al of porcelain diffuse toward metal.

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Improvement Research of BLE-based System for Monitoring the cause of Breakdown of Automatic Doors (자동문의 고장원인을 모니터링하기 위한 BLE 기반의 시스템 개선연구)

  • Kim, Gi-Doo;Won, Seo-Yeon;Kim, Hie-Sik
    • Journal of the Institute of Electronics and Information Engineers
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    • v.54 no.7
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    • pp.93-102
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    • 2017
  • Recently increasing usage of smartphones makes the Internet of Things (IoT) a leading technology that can collect and share data through sensor networks and wireless communication such as low-power Bluetooth (BLE). BLE-based application can provide operators more precise information on Automatic Door system by remotely diagnosing the system faults through wireless sensor networks and sensors around the Automatic Door. In this paper, a smart device with extended BLE module is implemented which can monitor and Control the system states and faults remotely without on-site diagnostic. while maintaining system integrity so that increase efficiency of time and costs for system management. We can use the results of this research as a basis in evaluating reliability of data between devices, extending communication module in Controller of obsolete Door systems, and establishing centralized monitoring systems in near future with multi-channel Door Controls.

The Friction Coefficients of Interfaces between Weathered Granite Soil and Reinforcements (화강토와 보강재 경계면에서의 마찰계수에 관한 연구)

  • 김상규;이은수
    • Geotechnical Engineering
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    • v.12 no.2
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    • pp.107-114
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    • 1996
  • A series of shear tests is performed to measure friction coefficients of the interface between different reinforcements and weathered granite soils. The reinforcements tested are smooth steel strip, Paraweb(friction tie) and geotextile with rough surface, while the weathered granite soils are composed of different, grain size distribution. Soils are compacted with the energy of 95% modified AASHTO and fully saturated before testing to simulate the worst site condition. Because of characteristics of the direct shear apparatus, shear strength is obtained in terms of drained condition. Test results show that the more fines the soils contain, the larger ratio of friction coefficient ($\mu=\frac{tan{\delta}}{tan{\Psi}}$) is obtained. Also the ratios are much higher for the Friction tie and the geotextile compared to the smooth steel strip. Those suggest that even weathered granite soils with 36% fines are possible to use as backfill of reinforced earth structures for the two reinforcements when a drainage system is provided.

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METAL SURFACE CHANGES BY HEAT TREATMENT OF Ni-Cr ALLOYS (열처리에 의한 도재용 Ni-Cr합금 표면의 변화에 관한 연구)

  • Kim, Young-Han;Lee, Sun-Hyung;Yang, Jae-Ho;Jung, Heon-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.27 no.2
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    • pp.219-248
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    • 1989
  • The purposes of this study were to analyze the microstructural and compositional changes of metal surfaces following different conditions of preoxidizing heat treatment, to investigate the composition of metal oxides, and to evaluate the effect of preoxidation and removal of surface oxides on microstructure and diffusion profiles. The techniques of EDAX (energy-dispersive analysis of x-ray), ESCA (electron spectroscopy for chemical analysis), and EPMA (electron probe micro analysis) were used, along with SEM (scanning electron microscopy). The obtained results were as follows : 1. A surface of the specimen became rough and the amount of the metal oxides increased with increasing the heat treatment time and temperature and the partial pressure of oxygen. 2. At an air pressure of 28' vacuum, the higher the temperature and the longer the time of preoxidation, the higher Ni concentration was detected. 3. Cr concentration in the specimen heat treated with air was higher than that of with vacuum. 4. The oxides in the specimens were mainly composed of Ni and Cr oxides. On the globular growth particles, significant rises in Al concentration of Rexillium III and Ti concentration of Verabond were noted. 5. Atomic diffusion occurred at the ceramic-metal interface, furthermore the amount of the flux was increased with preoxidation heat treatment.

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