• 제목/요약/키워드: inter-particle

검색결과 141건 처리시간 0.03초

확률모형과 수식정보를 이용한 와/과 병렬사구 범위결정 (Range Detection of Wa/Kwa Parallel Noun Phrase using a Probabilistic Model and Modification Information)

  • 최용석;신지애;최기선
    • 한국정보과학회논문지:소프트웨어및응용
    • /
    • 제35권2호
    • /
    • pp.128-136
    • /
    • 2008
  • 한국어 구문 분석의 초기 단계로서 병렬구조의 해석은 파싱의 효율을 높일 수 있다. 본 논문은 병렬구조 해석을 위한 비지도식 언어에 독립적인 확률 모델을 제안한다. 이 모델은 병렬구조의 대칭성과 상호교환성에 근거한다. 대칭성은 같은 구조가 반복된다는 것이고, 교환성은 좌우 구성요소를 교환해도 같은 의미를 지닌다는 것이다. 병렬구조는 일반적으로 대칭성을 따르지만, 수식어의 성질에 따라서 한쪽만을 수식하는 비대칭적인 구조가 출현하기도 한다. 비대칭 병렬구조 해석을 위해서 추가적으로 수식관계 통계정보를 사용한다. 제안된 모델을 본 논문에서는 "와/과" 조사로 이루어진 한국어의 명사구 병렬구조를 해석하는데 사용되는 것[1]을 중점으로 보여준다. 지도적 방식에 의한 모델을 포함한 다른 모델들에 비해 효율적임을 실험적으로 보여준다.

분자 끈을 활용한 CdSe/ZnS 양자 점의 향상된 배열 (Molecular Linker Enhanced Assembly of CdSe/ZnS Core-Shell Quantum Dots)

  • 조근태;이종현;남혜진;정덕영
    • Korean Chemical Engineering Research
    • /
    • 제46권6호
    • /
    • pp.1081-1086
    • /
    • 2008
  • 양자 점을 이용한 QD-LED(Quantum Dot - Light Emitting Device)의 소자 제작을 하기 위해서는 양자 점의 균일한 배열이 중요하다. 핵-껍질(core-shell) 구조의 CdSe/ZnS 양자 점을 기판에 고 밀도, 고 균일도로 배열하기 위하여 두 종류의 분자 끈(molecular linker)을 사용하였고, 공정의 단순화와 비용 절감을 위하여 고분자 도장인 PDMS(polydimethylsiloxane)를 이용한 미세접촉인쇄방법으로 양자 점들을 배열하였다. $TiO_2/ITO$ 기판에 양자 점을 고정시켜주는 역할을 하는 분자 끈으로는 2-carboxyethylphosphonic acid(CAPO)를 사용하였고, 양자 점 사이의 인력을 향상시켜주는 분자 끈으로는 1,6-hexanedithiol(HDT)을 사용하였다. 양자 점들의 배열 특성을 주사전자현미경(SEM, scanning electron microscope)과 원자 힘 현미경(AFM, atomic force microscope)으로 분석하였고, 광 발광분광기(PL, photoluminescence spectroscope)로 발광특성을 측정하였다.

Solution-Processed Inorganic Thin Film Transistors Fabricated from Butylamine-Capped Indium-Doped Zinc Oxide Nanocrystals

  • Pham, Hien Thu;Jeong, Hyun-Dam
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권2호
    • /
    • pp.494-500
    • /
    • 2014
  • Indium-doped zinc oxide nanocrystals (IZO NCs), capped with stearic acid (SA) of different sizes, were synthesized using a hot injection method in a noncoordinating solvent 1-octadecene (ODE). The ligand exchange process was employed to modify the surface of IZO NCs by replacing the longer-chain ligand of stearic acid with the shorter-chain ligand of butylamine (BA). It should be noted that the ligand-exchange percentage was observed to be 75%. The change of particle size, morphology, and crystal structures were obtained using a field emission scanning electron microscope (FE-SEM) and X-ray diffraction pattern results. In our study, the 5 nm and 10 nm IZO NCs capped with stearic acid (SA-IZO) were ligand-exchanged with butylamine (BA), and were then spin-coated on a thermal oxide ($SiO_2$) gate insulator to fabricate a thin film transistor (TFT) device. The films were then annealed at various temperatures: $350^{\circ}C$, $400^{\circ}C$, $500^{\circ}C$, and $600^{\circ}C$. All samples showed semiconducting behavior and exhibited n-channel TFT. Curing temperature dependent on mobility was observed. Interestingly, mobility decreases with the increasing size of NCs from 5 to 10 nm. Miller-Abrahams hopping formalism was employed to explain the hopping mechanism insight our IZO NC films. By focusing on the effect of size, different curing temperatures, electron coupling, tunneling rate, and inter-NC separation, we found that the decrease in electron mobility for larger NCs was due to smaller electronic coupling.

개별요소법을 통한 지반의 포화도와 밀도가 함몰에 미치는 영향 평가 (Influence of Saturation and Soil Density on the Ground Subsidence Using Distinct Element Method)

  • 김연호;김현빈;박성완
    • 한국지반공학회논문집
    • /
    • 제34권8호
    • /
    • pp.27-36
    • /
    • 2018
  • 연속적인 입자 유실에 의해 발생하는 지반 함몰 유형은 지반의 포화상태 및 상대밀도에 따라 전개 거동이 다르게 발생한다. 본 연구에서는 지반의 포화상태에 따라 함몰 유형을 분류하고 각 유형에 대해 상대밀도에 따른 해석을 개별요소법을 통해 수행하여 영향 인자에 따른 지반 함몰 전개 거동 변화를 분석하였다. 조밀한 지반인 경우, 포화상태에서는 비교적 작은 침하량과 침하 영향범위가 발생하였고 부분포화상태에서는 지반 내부에 동공을 형성하는 결과를 보였다. 반면, 느슨한 지반인 경우, 포화상태에서는 침하량과 침하 영향범위가 크게 발생하였으며 부분포화상태에서도 동공을 형성하지 못하고 즉각적인 함몰이 발생하였다. 결과적으로 지반의 상대밀도 및 포화상태는 입자 사이에 작용하는 맞물림 효과에 큰 영향을 미치며 함몰 거동을 변화시키는 중요한 인자로 작용하는 것으로 나타났다.

Variation in optical, dielectric and sintering behavior of nanocrystalline NdBa2NbO6

  • Mathai, Kumpamthanath Chacko;Vidya, Sukumariamma;Solomon, Sam;Thomas, Jijimon Kumpukattu
    • Advances in materials Research
    • /
    • 제2권2호
    • /
    • pp.77-91
    • /
    • 2013
  • High quality nanoparticles of neodymium barium niobium ($NdBa_2NbO_6$) perovskites have been synthesized using an auto ignition combustion technique for the first time. The nanoparticles thus obtained have been characterized by powder X-ray diffraction, thermo gravimetric analysis, differential thermal analysis, Fourier transform infrared spectroscopy, Raman spectroscopy and transmission electron microscopy. UV-Visible absorption and photoluminescence spectra of the samples are also recorded. The structural analysis shows that the nano powder is phase pure with the average particle size of 35 nm. The band gap determined for $NdBa_2NbO_6$ is 3.9 eV which corresponds to UV-radiation for optical inter band transition with a wavelength of 370nm. The nanopowder could be sintered to 96% of the theoretical density at $1325^{\circ}C$ for 2h. The ultrafine cuboidal nature of nanopowders with fewer degree of agglomeration improved the sinterability for compactness at relatively lower temperature and time. During the sintering process the wide band gap semiconducting behavior diminishes and the material turns to a high permittivity dielectric. The microstructure of the sintered surface was examined using scanning electron microscopy. The striking value of dielectric constant ${\varepsilon}_r=43$, loss factor tan ${\delta}=1.97{\times}10^{-4}$ and the observed band gap value make it suitable for many dielectric devices.

The observation of permeation grouting method as soil improvement technique with different grout flow models

  • Celik, Fatih
    • Geomechanics and Engineering
    • /
    • 제17권4호
    • /
    • pp.367-374
    • /
    • 2019
  • This study concluded the results of a research on the features of cement based permeation grout, based on some important grout parameters, such as the rheological properties (yield stress and viscosity), coefficient of permeability to grout ($k_G$) and the inject ability of cement grout (N and $N_c$ assessment), which govern the performance of cement based permeation grouting in porous media. Due to the limited knowledge of these important grout parameters and other influencing factors (filtration pressure, rate and time of injection and the grout volume) used in the field work, the application of cement based permeation grouting is still largely a trial and error process in the current practice, especially in the local construction industry. It is seen possible to use simple formulas in order to select the injection parameters and to evaluate their inter-relationship, as well as to optimize injection spacing and times with respect to injection source dimensions and in-situ permeability. The validity of spherical and cylindrical flow model was not verified by any past research works covered in the literature review. Therefore, a theoretical investigation including grout flow models and significant grout parameters for the design of permeation grouting was conducted in this study. This two grout flow models were applied for three grout mixes prepared for w/c=0.75, w/c=1.00 and w/c=1.25 in this study. The relations between injection times, radius, pump pressure and flow rate for both flow models were investigated and the results were presented. Furthermore, in order to investigate these two flow model, some rheological properties of the grout mixes, particle size distribution of the cement used in this study and some geotechnical properties of the sand used in this work were defined and presented.

Investigation of shear behavior of soil-concrete interface

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming;Marji, Mohammad Fatehi;Masoumi, Alireza
    • Smart Structures and Systems
    • /
    • 제23권1호
    • /
    • pp.81-90
    • /
    • 2019
  • The shear behavior of soil-concrete interface is mainly affected by the surface roughness of the two contact surfaces. The present research emphasizes on investigating the effect of roughness of soil-concrete interface on the interface shear behavior in two-layered laboratory testing samples. In these specially prepared samples, clay silt layer with density of $2027kg/m^3$ was selected to be in contact a concrete layer for simplifying the laboratory testing. The particle size testing and direct shear tests are performed to determine the appropriate particles sizes and their shear strength properties such as cohesion and friction angle. Then, the surface undulations in form of teeth are provided on the surfaces of both concrete and soil layers in different testing carried out on these mixed specimens. The soil-concrete samples are prepared in form of cubes of 10*10*30 cm. in dimension. The undulations (inter-surface roughness) are provided in form of one tooth or two teeth having angles $15^{\circ}$ and $30^{\circ}$, respectively. Several direct shear tests were carried out under four different normal loads of 80, 150, 300 and 500 KPa with a constant displacement rate of 0.02 mm/min. These testing results show that the shear failure mechanism is affected by the tooth number, the roughness angle and the applied normal stress on the sample. The teeth are sheared from the base under low normal load while the oblique cracks may lead to a failure under a higher normal load. As the number of teeth increase the shear strength of the sample also increases. When the tooth roughness angle increases a wider portion of the tooth base will be failed which means the shear strength of the sample is increased.

Development and evaluation of probiotic delivery systems using the rennet-induced gelation of milk proteins

  • Ha, Ho-Kyung;Hong, Ji-Young;Ayu, Istifiani Lola;Lee, Mee-Ryung;Lee, Won-Jae
    • Journal of Animal Science and Technology
    • /
    • 제63권5호
    • /
    • pp.1182-1193
    • /
    • 2021
  • The aims of this study were to develop a milk protein-based probiotic delivery system using a modified rennet-induced gelation method and to determine how the skim milk powder concentration level and pH, which can affect the rennet-induced intra- and inter-molecular association of milk proteins, affect the physicochemical properties of the probiotic delivery systems, such as the particle size, size distribution, encapsulation efficiency, and viability of probiotics in simulated gastrointestinal tract. To prepare a milk protein-based delivery system, skim milk powder was used as a source of milk proteins with various concentration levels from 3 to 10% (w/w) and rennet was added to skim milk solutions followed by adjustment of pH from 5.4 or 6.2. Lactobacillus rhamnosus GG was used as a probiotic culture. In confocal laser scanning microscopic images, globular particles with a size ranging from 10 ㎛ to 20 ㎛ were observed, indicating that milk protein-based probiotic delivery systems were successfully created. When the skim milk powder concentration was increased from 3 to 10% (w/w), the size of the delivery system was significantly (p < 0.05) increased from 27.5 to 44.4 ㎛, while a significant (p < 0.05) increase in size from 26.3 to 34.5 ㎛ was observed as the pH was increased from 5.4 to 6.4. An increase in skim milk powder concentration level and a decrease in pH led to a significant (p < 0.05) increase in the encapsulation efficiency of probiotics. The viability of probiotics in a simulated stomach condition was increased when probiotics were encapsulated in milk protein-based delivery systems. An increase in the skim milk powder concentration and a decrease in pH resulted in an increase in the viability of probiotics in simulated stomach conditions. It was concluded that the protein content by modulating skim milk powder concentration level and pH were the key manufacturing variables affecting the physicochemical properties of milk protein-based probiotic delivery systems.

Ca과 Y 복합 첨가가 AZ91 마그네슘 압출재의 시효 거동에 미치는 영향 (Effect of Combined Addition of Ca and Y on Aging Behavior of Extruded AZ91 Magnesium Alloy)

  • 김현지;김영민;배준호;박성혁
    • 소성∙가공
    • /
    • 제31권3호
    • /
    • pp.160-166
    • /
    • 2022
  • The purpose of this study is to investigate the effects of combined addition of Ca and Y on the precipitation and age-hardening behavior of an extruded AZ91 alloy by conducting the aging treatment at 200 ℃ for hot-extruded AZ91 and AZ91-0.3Ca-0.2Y alloys. In the AZ91 alloy, many Mg17Al12 discontinuous precipitate (DP) bands formed during air cooling immediately after extrusion are present, whereas in the AZ91-0.3Ca-0.2Y alloy, a few DP bands and numerous Al2Y, Al8Mn4Y, and Al2Ca phase particles are distributed along the extrusion direction. The peak-aging time of the AZ91-0.3Ca-0.2Y alloy is 16 hours, twice that of the AZ91 alloy. Although both alloys have similar hardness before aging treatment, the hardness after peak-aging treatment (i.e., peak hardness) of the AZ91-0.3Ca-0.2Y alloy is higher than that of the AZ91 alloy, as 93.1 and 88.7 Hv, respectively. The microstructures of both peak-aged alloys comprise DPs and continuous precipitates (CPs). However, the peak-aged AZ91-0.3Ca-0.2Y alloy has a smaller amount of DPs and a larger amount of CPs than the peak-aged AZ91 alloy. Additionally, the inter-particle spacings of DPs and CPs in the former are significantly narrower than those in the latter. These results demonstrate that the addition of small amounts of Ca and Y to a commercial AZ91 alloy considerably affects the formation rate, size, and amount of CPs and DPs during aging and resultant age-hardening behavior.

Effect of loading frequency and clay content on the dynamic properties of sandy-clay mixtures using cyclic triaxial tests

  • Alireza Hasibi Taheri;Navid Hadiani;S. Mohammad Ali Sadredini;Mahmood Zakeri Nayeri
    • Geomechanics and Engineering
    • /
    • 제36권4호
    • /
    • pp.317-328
    • /
    • 2024
  • Adopting a rational engineering methodology for building structures on sandy-clay soil layers has become increasingly important since it is crucial when structures erected on them often face seismic and cyclic wave loads. Such loads can cause a reduction in the stiffness, strength, and stability of the structure, particularly under un-drained conditions. Hence, this study aims to investigate how the dynamic properties of sand-clay mixtures are affected by loading frequency and clay content. Cyclic triaxial tests were performed on a total of 36 samples, comprising pure sand with a relative density of 60% and sand with varying percentages of clay. The tests were conducted under confining pressures of 50 and 100 kPa, and the samples' dynamic behavior was analyzed at loading frequencies of 0.1, 1, and 4 Hz. The findings indicate that an increase in confining pressure leads to greater inter-particle interaction and a reduced void ratio, which results in an increase in the soil's shear modulus. An increase in the shear strength and confinement of the samples led to a decrease in energy dissipation and damping ratio. Changes in loading frequency showed that as the frequency increased, the damping ratio decreased, and the strength of the samples increased. Increasing the loading frequency not only reflects changes in frequency but also reduces the relative permeability and enhances the resistance of samples. An analysis of the dynamic properties of sand and sand-clay mixtures indicates that the introduction of clay to a sand sample reduces the shear modulus and permeability properties.