• 제목/요약/키워드: inter-diffusion

검색결과 161건 처리시간 0.025초

일방향 초내열합금 GTD-111DS에서 삽입금속 분말에 따른 천이액상확산접합부의 접합강도 특성 (The Bonding Strength Characteristic of the Filler Metal Powder on the TLP Bonded Region of Superalloy GTD-111DS)

  • 오인석;김길무;문병식
    • Journal of Welding and Joining
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    • 제25권5호
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    • pp.45-50
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    • 2007
  • The Ni-base superalloy GTD111 DS is used in the first stage blade of high power land-based gas turbines. Advanced repair technologies of the blade have been introduced to the gas turbine industry over recent years. The effect of the filler metal powder on Transient Liquid Phase bonding phenomenon and tensile mechanical properties was investigated on the GTD111 DS superalloy. At the filler metal powder N series, the base metal powders fully melted at the initial time and a large amount of the base metal near the bonded interlayer was dissolved by liquid inter metal. Liquid filler metal powder was eliminated by isothermal solidification which was controlled by the diffusion of B into the base metal. The solids in the bonded interlayer grew from the base metal near the bonded interlayer inward the insert metal during the isothermal solidification. The bond strength of N series filler metal powder was over 1000 MPa. and ${\gamma}'$ phase size of N series TLP bonded region was similar with base metal by influence of Ti, Al elements. At the insert metal powder M series, the Si element fluidity of the filler metal was good but microstructure irregularity on bonded region because of excessive Si element. Nuclear of solids formed not only from the base metal near the bonded interlayer but also from the remained filler metal powder in the bonded interlayer. When the isothermal solidification was finished, the content of the elements in the boned interlayer was approximately equal to that of the base metal. But boride and silicide formed in the base metal near the bonded interlayer. And these boride decreased with the increasing of holding time. The bond strength of M series filler metal powder was about 400 MPa.

크로스토크 제거를 통한 입체 음향 구현에 관한 연구 (A Study on the Implementation of Realistic Sound Through Cross-Talk Cancellation)

  • 김학진
    • 대한전자공학회논문지SP
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    • 제41권2호
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    • pp.99-108
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    • 2004
  • 5.1채널 스피커 시스템을 이용하여 음향을 재현 시 나타나는 현상인 크로스토크를 제거하여 청취자에게 보다 입체적인 음을 재현하는 방법에 관한 것이다. 본 논문에서는 자유음장 모델에 기초하여 5.1채널 스피커 시스템의 보상함수를 해석, 이를 심리음향에 기초한 바크 스케일(bark scale) 등가 보상 밴드패스 필터에 적용하여 주파수 제한적인 음질 보상을 실시하였다. 정면 채널과 서라운드 채널의 음원을 제작하여 기존의 2채널 및 5.1 시스템에서 제시하는 음원과 비교하여 객관적인 음질평가 및 청취자를 대상으로 한 주관 평가를 실시하였다. 제안된 방법에 따라 측정한 결과에 따르면 ±30。의 정면 스피커를 배치한 돌비 표준 스피커 배치에서 38㏈ 이상의 분리도를 얻었으며 확산감에 대해 전문가를 대상으로 한 주관 평가는 5점 평가를 기준으로 0.4점이 향상되었다.

클렌부테롤 경피흡수제제의 개발 (Development of Transdermal Delivery Systems Containing Clenbuterol)

  • 최한곤;권기철;정시영;이종달;용철순
    • Journal of Pharmaceutical Investigation
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    • 제30권4호
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    • pp.247-252
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    • 2000
  • The advantages of transdermal administration are avoiding hepatic first pass effect, minimizing inter- and intra-patient variation, maintaining steady-state plasma level to provide long-term therapy from a single dose, and allowing a rapid termination of drug input. Clenbuterol, a selective ${\beta}_2-adrenergic$ receptor stimulant, has been introduced as a potent bronchodilator for patients with bronchial asthma, chronic obstructive bronchial disease. For the development of transdermal systems containing clenbuterol, two limiting factors - long lag time and low flux - must be overcome. In this study, we attempted to select optimal formulation for preparation of clenbuterol patch using hairless mouse skin and flow-through diffusion cell. The flux of clenbuterol increased as the percent of clenbuterol dose dependently in the concentration range of 5-15%. Based on this result, we fixed the concentration of clenbuterol as 15%. The effect of various penetration enhancers on percutaneous absorption of clenbuterol through hairless mouse skin was investigated. Labrafil was the most effective enhancer, which increased the permeability of clenbuterol approximately 4-fold compared with the control without penetration enhancer. Optimal enhancer concentration was 3%. The effect of various adhesives on penetration of clenbuterol was also investigated. Among the adhesives studied, MA-31 was the most effective adhesive. Furthermore, the clenbuterol patch composed of 15% clenbuterol, 3% Labrafil and 82% MA-31, which gave most excellent penetration of drug in in vitro penetration study, maintained therapeutic plasma levels in in vivo study using S.D. rats. These studies demonstrated a good feasibility of clenbuterol administration through the intact skin using a transdermal patch, and show a possibility of the development of clenbuterol patches.

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Unusual ALD Behaviors in Functional Oxide Films for Semiconductor Memories

  • Hwang, Cheol Seong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.77.1-77.1
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    • 2013
  • Atomic layer deposition (ALD) is known for its self-limiting reaction, which offers atomic-level controllability of the growth of thin films for a wide range of applications. The self-limiting mechanism leads to very useful properties, such as excellent uniformity over a large area and superior conformality on complex structures. These unique features of ALD provide promising opportunities for future electronics. Although the ALD of Al2O3 film (using trimethyl-aluminum and water as a metal precursor and oxygen source, respectively) can be regarded as a representative example of an ideal ALD based on the completely self-limiting reaction, there are many cases deviating from the ideal ALD reaction in recently developed ALD processes. The nonconventional aspects of the ALD reactions may strongly influence the various properties of the functional materials grown by ALD, and the lack of comprehension of these aspects has made ALD difficult to control. In this respect, several dominant factors that complicate ALD reactions, including the types of metal precursors, non-metal precursors (oxygen sources or reducing agents), and substrates, will be discussed in this presentation. Several functional materials for future electronics, such as higher-k dielectrics (TiO2, SrTiO3) for DRAM application, and resistive switching materials (NiO) for RRAM application, will be addressed in this talk. Unwanted supply of oxygen atoms from the substrate or other component oxide to the incoming precursors during the precursor pulse step, and outward diffusion of substrate atoms to the growing film surface even during the steady-state growth influenced the growth, crystal structure, and properties of the various films.

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일방향응고 Ni기 초내열합금 천이액상화산접합부의 미세조직에 미치는 모재와 삽입금속 분말 혼합비의 영향 (The Mixing Ratio Effect of Insert Metal Powder and Insert Brazing Powder on Microstructure of the Region Brazed on DS Ni Base Super Alloy)

  • 예창호;이봉근;송우영;오인석;강정윤
    • Journal of Welding and Joining
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    • 제23권6호
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    • pp.99-105
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    • 2005
  • The mixing ratio effect of the GTD-111(base metal) powder and the GNI-3 (Ni-l4Cr-9.5Co-3.5Al-2.5B) powder on TLP(Transient Liquid Phase) bonding phenomena and mechanism was investigated. At the mixing ratio of the base metal powder under $50wt\%$, the base metal powders fully melted at the initial time and a large amount of the base metal near the bonded interlayer was dissolved by liquid inter metal. Liquid insert metal was eliminated by isothermal solidification which was controlled by the diffusion of B into the base metal. The solid phases in the bonded interlayer grew epitaxially from the base metal near the bonded interlayer inward the insert metal during the isothermal solidification. The number of grain boundaries farmed at the bonded interlayer corresponded with those of base metal. At the mixing ratio above $60wt\%$, the base metal powder melted only at the surface of the powder and the amount of the base metal dissolution was also less at the initial time. Nuclear of solids firmed not only from the base metal near the bonded interlayer but also from the remained base metal powder in the bonded interlayer. Finally, the polycrystal in the bonded interlayer was formed when the isothermal solidification finished. When the isothermal solidification was finished, the contents of the elements in the boned interlayer were approximately equal to those of the base metal. Cr-W borides and Cr-W-Ta-Ti borides formed in the base metal near the bonded interlayer. And these borides decreased with the increasing of holding time.

크로스토크 제거를 위한 바크스케일 등가 보상 필터를 이용한 음질 향상에 관한 연구 (A Study on the Sound Quality Improvement Using the Equal Compensation Filter in Bark-scale for the Cross-talk Cancellation)

  • 김학진;김순협
    • 정보처리학회논문지B
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    • 제11B권3호
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    • pp.345-352
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    • 2004
  • 본 논문에서는 자유음장 모델을 기초로 5.1채널 스피커 시스템의 보상함수를 해석하고, 이를 심리음향에 기초한 바크 스케일(bark scale) 등 가 보상 밴드패스 필터에 적용하여 주파수 제한적인 음질 보상에 대한 실험을 통해 5.1채널 스피커 시스템에서 음향 재현시 나타나는 크로스토크를 제거함으로써 보다 입체적인 음을 재현하는 방법을 제안하였다. 정면 채널과 서라운드 채널의 음원을 기존의 2채널 및 5.1채널 시스템에서 제시하는 음원과 비교를 위하여 음질 평가와 함께 청취자를 대상으로 주관적인 평가를 실시하였다. 실험 결과 \pm30{\circ}$의 정면 스피커를 배치한 돌비 표준 스피커 배치에서 38dB 이상의 분리도를 얻었으며, 전문가 그룹의 음의 확산감에 대한 주관 평가에서는 5점 평가를 기준으로 0.4∼0.5점, 음의 깊이감 평가에서는 0.1∼0.2점이 향상되었다.

Structural and Magnetic Properties of (CoFe2O4)0.5(Y3Fe5O12)0.5 Powder

  • Lee, Jae-Gwang;Chae, Kwang-Pyo;Lee, Young-Bae;Lee, Sung-Ho
    • Journal of Magnetics
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    • 제10권3호
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    • pp.80-83
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    • 2005
  • Cobalt ferrite and garnet powders were grown using a conventional ceramic method in two different ways for understanding the magnetic interaction between structurally different materials. Structures of these powders were investigated by using an X-ray diffractometer (XRD) and the magnetic interaction between iron ions and the magnetic properties of the powders were measured by a $M\ddot{o}ssbauer$ spectroscopy and a vibrating sample magnetometer (VSM), respectively. The result of the XRD measurement showed that the annealing temperature higher than $1200^{\circ}C$ was necessary to grow a $(CoFe_2O_4)_{0.5}(Y_3Fe_5O_{12})_{0.5}$ powder. $M\ddot{o}ssbauer$ spectra for the powders grown separately and mixed mechanically consisted of sub-spectra of cobalt ferrite and garnet, however, powders annealed together had an extra sub-spectrum, which was related with the magnetic interaction between the grain surface of cobalt ferrite and the one of the garnet. In case of annealing the powders at the temperature large enough to crystallize them, raw chemicals became fine cobalt ferrite and garnet particles at first and then these fine particles were aggregated and formed large grains of ferrite powders. The result of the VSM measurement showed that the powders prepared at $1200^{\circ}C$ had the similar saturation magnetization and the coercivity regardless of the preparation method.

사용후핵연료의 연소도 변화에 따른 산화 및 OREOX 공정에서 핵분열기체 방출 특성 (Release Characteristics of Fission Gases with Spent Fuel Burn-up during the Voloxidation and OREOX Processes)

  • 박근일;조광훈;이정원;박장진;양명승;송기찬
    • 방사성폐기물학회지
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    • 제5권1호
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    • pp.39-52
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    • 2007
  • 사용후핵연료의 건식 재가공을 위한 핵연료 원격 제조공정중 분말제조를 위한 산화 및 OREOX(산화 환원공정)열처리 공정으로부터 $^{85}Kr$$^{14}C$ 핵분열기체의 방출거동을 정량적으로 평가하였다. 특히 사용후핵연료의 평균 연소도가 $27,000{\sim}65,000\;MWd/tU$ 범위내에서 연소도 변화에 따른 핵분열기체의 방출 분율은 측정한 실험결과와 ORIGEN 코드로부터 계산된 초기 inventory를 상호 비교하여 구하였다. $500^{\circ}C$ 1차 산화공정(voloxidation)에서 $^{85}Kr$$^{14}C(^{14}CO_2)$의 시간에 따른 방출거동은 $UO_2$ 핵연료의 $U_3O_8$으로의 분말화 정도와 밀접한 관련이 있는 것으로 보이며, 입계(grain-boundary)에 분포된 핵분열기체가 대부분 방출되는 것으로 여겨진다. 산화분말을 이용한 OREOX 공정으로부터 핵분열기체의 높은 방출율은 $700^{\circ}C$의 환원공정에서 온도 증가에 의한 기체 확산 및 $UO_2$으로의 환원에 의한 U 원자 이동성 증가에 의존하며 주로 inter-grain 및 intra-grain에 분포된 핵분열기체가 방출된 것으로 판단된다. 일차 산화공정시 $^{85}Kr$$^{14}C$ 핵분열기체의 방출 분율은 핵 연료 연소도가 증가함에 따라 높게 나타났고 방출 분율 범위는 총 inventory의 $6{\sim}12%$정도며, 산화분말의 OREOX 공정처리시 잔류 핵분열기체 대부분이 방출되는 것으로 보인다. 아울러 사용후핵 연료로부터 핵분열기체의 제거를 위해서는 고온 환원분위기보다는 산화에 의한 분말화가 더 효과적인 것으로 여겨진다.

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참여자관점에서 공급사슬관리 시스템의 성공에 영향을 미치는 요인에 관한 실증연구 (An Empirical Study on the Determinants of Supply Chain Management Systems Success from Vendor's Perspective)

  • 강성배;문태수;정윤
    • Asia pacific journal of information systems
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    • 제20권3호
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    • pp.139-166
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    • 2010
  • The supply chain management (SCM) systems have emerged as strong managerial tools for manufacturing firms in enhancing competitive strength. Despite of large investments in the SCM systems, many companies are not fully realizing the promised benefits from the systems. A review of literature on adoption, implementation and success factor of IOS (inter-organization systems), EDI (electronic data interchange) systems, shows that this issue has been examined from multiple theoretic perspectives. And many researchers have attempted to identify the factors which influence the success of system implementation. However, the existing studies have two drawbacks in revealing the determinants of systems implementation success. First, previous researches raise questions as to the appropriateness of research subjects selected. Most SCM systems are operating in the form of private industrial networks, where the participants of the systems consist of two distinct groups: focus companies and vendors. The focus companies are the primary actors in developing and operating the systems, while vendors are passive participants which are connected to the system in order to supply raw materials and parts to the focus companies. Under the circumstance, there are three ways in selecting the research subjects; focus companies only, vendors only, or two parties grouped together. It is hard to find researches that use the focus companies exclusively as the subjects probably due to the insufficient sample size for statistic analysis. Most researches have been conducted using the data collected from both groups. We argue that the SCM success factors cannot be correctly indentified in this case. The focus companies and the vendors are in different positions in many areas regarding the system implementation: firm size, managerial resources, bargaining power, organizational maturity, and etc. There are no obvious reasons to believe that the success factors of the two groups are identical. Grouping the two groups also raises questions on measuring the system success. The benefits from utilizing the systems may not be commonly distributed to the two groups. One group's benefits might be realized at the expenses of the other group considering the situation where vendors participating in SCM systems are under continuous pressures from the focus companies with respect to prices, quality, and delivery time. Therefore, by combining the system outcomes of both groups we cannot measure the system benefits obtained by each group correctly. Second, the measures of system success adopted in the previous researches have shortcoming in measuring the SCM success. User satisfaction, system utilization, and user attitudes toward the systems are most commonly used success measures in the existing studies. These measures have been developed as proxy variables in the studies of decision support systems (DSS) where the contribution of the systems to the organization performance is very difficult to measure. Unlike the DSS, the SCM systems have more specific goals, such as cost saving, inventory reduction, quality improvement, rapid time, and higher customer service. We maintain that more specific measures can be developed instead of proxy variables in order to measure the system benefits correctly. The purpose of this study is to find the determinants of SCM systems success in the perspective of vendor companies. In developing the research model, we have focused on selecting the success factors appropriate for the vendors through reviewing past researches and on developing more accurate success measures. The variables can be classified into following: technological, organizational, and environmental factors on the basis of TOE (Technology-Organization-Environment) framework. The model consists of three independent variables (competition intensity, top management support, and information system maturity), one mediating variable (collaboration), one moderating variable (government support), and a dependent variable (system success). The systems success measures have been developed to reflect the operational benefits of the SCM systems; improvement in planning and analysis capabilities, faster throughput, cost reduction, task integration, and improved product and customer service. The model has been validated using the survey data collected from 122 vendors participating in the SCM systems in Korea. To test for mediation, one should estimate the hierarchical regression analysis on the collaboration. And moderating effect analysis should estimate the moderated multiple regression, examines the effect of the government support. The result shows that information system maturity and top management support are the most important determinants of SCM system success. Supply chain technologies that standardize data formats and enhance information sharing may be adopted by supply chain leader organization because of the influence of focal company in the private industrial networks in order to streamline transactions and improve inter-organization communication. Specially, the need to develop and sustain an information system maturity will provide the focus and purpose to successfully overcome information system obstacles and resistance to innovation diffusion within the supply chain network organization. The support of top management will help focus efforts toward the realization of inter-organizational benefits and lend credibility to functional managers responsible for its implementation. The active involvement, vision, and direction of high level executives provide the impetus needed to sustain the implementation of SCM. The quality of collaboration relationships also is positively related to outcome variable. Collaboration variable is found to have a mediation effect between on influencing factors and implementation success. Higher levels of inter-organizational collaboration behaviors such as shared planning and flexibility in coordinating activities were found to be strongly linked to the vendors trust in the supply chain network. Government support moderates the effect of the IS maturity, competitive intensity, top management support on collaboration and implementation success of SCM. In general, the vendor companies face substantially greater risks in SCM implementation than the larger companies do because of severe constraints on financial and human resources and limited education on SCM systems. Besides resources, Vendors generally lack computer experience and do not have sufficient internal SCM expertise. For these reasons, government supports may establish requirements for firms doing business with the government or provide incentives to adopt, implementation SCM or practices. Government support provides significant improvements in implementation success of SCM when IS maturity, competitive intensity, top management support and collaboration are low. The environmental characteristic of competition intensity has no direct effect on vendor perspective of SCM system success. But, vendors facing above average competition intensity will have a greater need for changing technology. This suggests that companies trying to implement SCM systems should set up compatible supply chain networks and a high-quality collaboration relationship for implementation and performance.

한국 아동 집단의 구조 뇌연결지도 (Anatomical Brain Connectivity Map of Korean Children)

  • 엄민희;박범희;박해정
    • Investigative Magnetic Resonance Imaging
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    • 제15권2호
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    • pp.110-122
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    • 2011
  • 목적 : 본 연구의 목적은 확산텐서영상에 기반하여 한국 아동 집단의 해부학적 뇌연결성 지도를 확립하고 뇌신경망의 효율성을 평가하는 기법을 개발하는 것이다. 대상 및 방법 : 건강한 아동 12명에서 얻은 확산텐서영상과 뇌구획영상을 바탕으로 구조 연결 행렬을 구하여 집단의 구조 연결성을 평가하였다. 일표본 t-검정을 시행하여 평균적인 구조 연결성을 파악하였고 이 때 얻은 각 피험자의 백질 다발을 표준공간으로 정규화하여 집단의 해부학적 뇌연결망 지도를 확립했다. 뇌신경망의 군집정도(clustering coefficient), 평균이동거리(characteristic path length), 전체/부분 연결망 효율성(global/local efficiency) 등 연결망 속성을 계산한 후 시각화 하였다. 결과 : 연결망 측면에서 한국 아동 집단의 뇌연결성이 작은세상속성을 가짐을 밝혔다. 또한 해부학적 뇌연결망 지도를 얻었는데 대뇌 반구 내의 연결성이 높게 나타남과 뇌간과 운동/감각 영역간에 많은 신경 연결이 집중되어 있음을 확인하였다. 결론 : 한국 아동 집단의 해부학적 뇌연결망 지도를 작성하는 방법론을 제시하여 뇌를 연결성 측면에서 이해하고 발달 장애와 성인 뇌신경망의 효율성을 평가할 수 있는 기본 도구를 확립하게되었다.