• 한국환경보건학회지
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• 제29권1호
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• pp.51-61
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• 2003

Pollution purification using titanium dioxide (TiO$_2$) photocatalyst has attracted a great deal of attention with increasing number of relent environmental problems. Currently, the application of TiO$_2$ photocatalyst has been focused on purification and treatment of waste water. However. the use of conventional TiO$_2$ powder photocatalyst results in disadvantage of stirring during the reaction and of separation after the reaction. And the usage of artificial UV lamp has made the cost of photocatalyst treatment system high. Consequently, we herein studied the pilot-scale design to aid in optimization of the energy-saving process for more through development and reactor design by solar light/UV lamp/ TiO$_2$system. In this study, we manufactured the TiO$_2$sol by sol-gel method. According to analysis by XRD, SEM and TEM, characterization of TiO$_2$ sol were nano-size (5-6 nm) and anatase type. Inorganic binder (SiO$_2$) was added to TiO$_2$ lot to be coated for support strongly, and support of ceramic bead was used to lower separation rate that of glass bead The influences were studied of various experimental parameters such as TiO$_2$ quantity, pH, flow rate. additives, pollutants concentration, climate condition and reflection plate by means of reaction time of the main chararteristics of the obtained materials. In water treatment system, variable realtor as solar light/ or UV lamp according to climate condition such as sunny and cloudy days treated the phenol and E-coli(Escherichia coli) effectively.

• 멤브레인
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• 제20권3호
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• pp.210-216
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• 2010

IS (요오드-황)프로세스의 HI 분해반응 공정에서의 적용을 목적으로 지르코니아 코팅 지지체를 이용하여 CVD법에 의해 수소분리막을 제작하였으며, 분리막으로서의 가능성을 평가하였다. 제작한 막의 형상 및 Si의 분포를 파악하기 위해 SEM 및 EPMA를 이용하여 분석하였다. 지르코니아를 코팅한 지지체를 이용하여 제작한 막에 Zr-Si-O층이 존재한다는 것을 알 수 있었다. 제작한 막의 수소와 질소가스의 단일 성분 투과속도를 $300{\sim}600^{\circ}C$에서 측정하였다. $600^{\circ}C$에서 Z-1막에서의 수소투과속도는 $1{\times}10^{-7}\;mol{\cdot}Pa^{-1}{\cdot}m^{-2}{\cdot}s^{-1}$를 나타냈다. 질소에 대한 수소의 선택성은 Z-1 막에서 5.0, Z-2막에서 5.75를 나타냈다.

• 멤브레인
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• 제28권5호
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• pp.297-306
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• 2018

본 총설은 분리막기술이 적용된 수소생산에 대한 개론으로, 특히, 암모니아를 수소운반체로 이용하는 수소생산에 대한 연구결과를 중점적으로 서술하였다. 암모니아를 수소운반체로 적용한 수소생산은 추가적인 탄소생성이 없다는 점 외에 여러 측면에 있어 이점이 있다. 많은 연구들이 고순도 수소 분리 및 생산을 위한 분리막 개발을 위해 진행되고 있으며, 이들 중 팔라듐을 기본으로 한 분리막(예를 들어, 다공성 세라믹 또는 다공성 금속 지지체와 팔라듐 합금의 얇은 선택층으로 이루어진 분리막)에 대한 연구가 활발하다. 반면에, 효율적인 암모니아 분해를 위해서는 주로 루테늄 촉매가 적용되고 있으며, 루테늄과 지지체 및 촉진제로 이루어진 루테늄에 기반을 둔 촉매에 대한 연구발표가 다수 존재한다. 수소생산을 위한 분리막 반응기 형태로는 충전층, 유동층, 그리고 마이크로반응기 등이 있으며, 이들의 최적화 및 원활한 물질전달 연구는 현재진행형이다. 또한, 높은 암모니아 분해율, 고순도 수소생산 및 높은 수소생산율을 얻기 위해 분리막과 촉매의 다양한 조합에 대한 연구 및 분리막과 촉매의 역할을 동시에 구현할 수 있는 분리막에 대한 연구가 발표되고 있다.

• 한국제4기학회:학술대회논문집
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• 한국제4기학회 2004년도 하계학술대회
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• pp.51-51
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• 2004

As an important contribution to the planed drilling (IODP) in the central part of the Arctic Ocean, we are currently working on a refined chronostratigraphy for Marine Isotope Stage (MIS) 16 to MIS 2 on the exciting material from ODP Site 910A (Leg 151) which has been recovered from the marginal Eastern Arctic Ocean (the Yermak Plateau - the Atlantic/Arctic Ocean Gateway). Several stratigraphic age fix-points support the interpretation of the stable oxygen. isotope record of planktonic foraminifer N, pachyderma sin. that is punctuated by several short-term meltwater events. We believe that our new record will serve as 'the important correlating tool for establishing a basic stratigraphy for the Quaternary Arctic Ocean as well as for generating high-resolution paleoenvironmental reconstructions in the central Arctic Ocean. Furthermore, our study will provide reference stratigraphic data sets for interpreting the micropaleontological, sedimentological and organic / inorganic - geochemical proxies of the new boreholes that will be drilled on the Lomonosov Ridge(Central Arctic Ocean) in the frame of the "Arctic Coring Expedition' (ACEX, IODP) in summer 2004.

• 한국환경보건학회지
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• 제46권5호
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• pp.610-626
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• 2020

Objectives: This study aims to investigate the concept of microplastics and their occurrence, transport, biological effects, and management methods in the ocean. Methods: I reviewed articles on microplastics in the ocean by using the Google Scholar database. Results: Plastic litter has been reported as a ubiquitous pollutant in the ocean due to the extensive consumption of plastics and the mismanagement of plastic wastes. Microplastics are generally defined as synthetic polymer particles <5 mm in size. Microplastics generated from the degradation of plastic litter are currently a serious global concern since they spread easily all over the ocean, transfer to different tissues inside contaminated animals, and even across different trophic levels inside the food web. An additional concern is the ability of microplastics to adsorb organic and inorganic pollutants and subsequently release them into the ocean. Thus, alternatives to reduce microplastics in the ocean are discussed. Conclusions: This paper summarizes the concept of microplastics and their behavior in the ocean and suggests management methods for microplastics in support of a cleaner ocean.

• 한국농공학회지
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• 제26권3호
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• pp.59-67
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• 1984

This study was carried out to find physical and mechanical properties of soil in Yongsan project area to support basic data for tidalland reclamation. The main results are as follows. 1. Most of the soils in this area consist of clay and silt, and inorganic materials. 2. Natural moisture contents are ranged from 42.2% to 92.9% initial void ratio, from 1.4 to 2.3 Therefore it takes a longtime in Settlement of considerable depth. 3. Wet unit weights decrease with increasing of the nataral moistare contents as rt=2. 005-0. 0065wn.4. The relationships between compression index. and liquid limit, initial void ratio and natural moisture contents are found as follows respectively. Cc =0. 046+0. O12LL Cc=-0. 068+0.367eo Cc =0. 056+0. OO8Wn 5. Natural moisture content, plastic limit, plastic index, initial void ratio and liquid :limit are directly proportional to clay content ratio. The relationships are found as Wn=26. 083+0. 797Cy PL=14. 223+0. 128Cy P1=0. 457+0. 492Cy eo=0. 757+0. O2Ocy LL=14. 695+0. 620Cy. 6. Initial void ratio and liquid limit are directly proportional to natural moisture con-tent as follows. eo=0. 310+0.022wn LL=6. 275+0.592wn

• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2584-2592
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• 2011

Nickel nanoparticle-poly(N-vinyl-2-pyrrolidone)/$TiO_2-ZrO_2$ composite (Ni-PVP/$TiO_2-ZrO_2$) was prepared by in situ polymerization method. The physical and chemical properties of Ni-PVP/$TiO_2-ZrO_2$ were investigated by XRD, FT-IR, BET, TGA, SEM and TEM techniques. The catalytic performance of this novel heterogeneous catalyst was determined for the Suzuki-Miyaura cross-coupling reaction between aryl halides and phenylboronic acid in the presence of methanol-water mixture as solvent. The effects of reaction temperature, the amount of catalyst, amount of support, solvent, and amount of metal for the synthesis of Ni-PVP/$TiO_2-ZrO_2$, were investigated as well as recyclability of the heterogeneous composite. The catalyst used for this synthetically useful transformation showed considerable level of reusability besides very good activity.

• 공업화학
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• 제18권6호
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• pp.630-635
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• 2007

구조중에 1개의 tert-부틸기를 가진 새로운 형태의 키랄살렌 착체를 합성하여 비대칭반응 촉매로서 활용하였다. 알루미늄족의 금속염을 소유한 이량체형의 키랄 살렌 촉매는 에폭사이드의 산소고리를 페놀류로 여는 비대칭반응에서 매우 높은 활성과 선택성을 나타내었다. 또한 무기담체에 고정화된 살렌 착체도 이 반응에 대하여 효과적인 촉매로 사용할 수 있었다. 새로운 키랄 살렌촉매 중에 존재하는 금속염의 종류는 광학선택적 반응에서 중요한 영향을 나타내었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1304-1307
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• 1997

A hydrogen gas sensor utilizing Pt/$SnO_2$ system was fabricated by the pressed pellet method. The crystal structure, direction of the crystal, crystal size and microstructure between the catalyst and the support ($SnO_2$) were characterized with Electron Diffraction Analysis, Transmission Electron Microscopy, Scanning Electron Microscopy. After the reactor with a Pt/$SnO_2$ sample was run with a flow rate of 30sccm (a mixture of $0.5%H_2$ in $N_2$) for a while, the resistance of $SnO_2$ was saturated, but the $SnO_2$ kept absorbing $H_2$ gas. $H_2$ gas sensing properties of Pt/$SnO_2$ were investigated at several temperatures. As a result, it was observed that Pt/$SnO_2$ has high sensitivity at $300^{\circ}C$ and $400^{\circ}C$.

• 대한화학회지
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• 제57권5호
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• pp.574-590
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• 2013

A new solid complexes of Ti(IV), Y(III) and Ce(IV) have been synthesized with ofloxacin. The formulae and structure of the complexes have been proposed in the light of analytical, spectral ($^1H$ NMR, IR and UV-Visible), magnetic, molar conductivities and thermal studies. The complexes are soluble in DMSO-$d_6$ and DMF. The measured molar conductance values indicate that, the three complexes are electrolyte in nature. The results support the formation of the complexes and indicated that ofloxacin reacts as a bidentate ligand chelate to the metal ion through the pyridone oxygen and one carboxylato oxygen. The kinetic parameters of thermogravimetric and its differential have been evaluated by using Coats Redfern (CR) and Horowitz-Metzeger (HM) methods. The thermodynamic data reflect the thermal stability for all complexes. The metal- ligand binding of the Ti(IV), Y(III) and Ce(IV) complexes is predicted using density funcational theory at the B3LYP-CEP-31G level of theory and total energy, dipole moment estimation of different Ti(IV), Y(III) and Ce(IV) ofloxacin structures. The biological activities of the ofloxacin, inorganic salts and their metal complexes were assayed against different bacterial species.