• Asian Journal of Atmospheric Environment
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• v.10 no.1
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• pp.51-56
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• 2016

Particulate matter (PM) in the atmosphere has wide-ranging health, environmental, and climate effects, many of which are attributed to fine-mode secondary organic aerosols. PM concentrations are significantly enhanced by primary particle emissions from traffic sources. Recently, in order to reduce $CO_2$ and increase fuel economy, gasoline direct injected (GDI) engine technology is increasingly used in vehicle manufactures. The popularization of GDI technique has resulted in increasing of concerns on environmental protection. In order to better understand variations in chemical composition of particulate matter from emissions of GDI vehicle versus a port fuel injected (PFI) vehicle, a high time resolution chemical composition of PM emissions from GDI and PFI vehicles was measured at facility of Transport Pollution Research Center (TPRC), National Institute of Environmental Research (NIER), Korea. Continuous measurements of inorganic and organic species in PM were conducted using an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). The HR-ToF-AMS provides insight into non-refractory PM composition, including concentrations of nitrate, sulfate, hydrocarbon-like and oxygenated organic aerosol, and organic mass with 20 sec time resolution. Many cases of PM emissions during the study were dominated by organic and nitrate aerosol. An overview of observed PM characteristics will be provided along with an analysis of comparison of GDI vehicle versus PFI vehicle in PM emission rates and oxidation states.

• Journal of the Korean Ceramic Society
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• v.42 no.4
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• pp.260-268
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• 2005

A heat-resisting diatomite protection tube, using diatomite as a main component, was manufactured through an extrusion molding of ceramic slurry in different component ratios. And its mechanical strength, carbon analysis and microstructural non-homogeneity were investigated. After fixing $60wt\%$ of porous diatomite whose particle size was $50\~100\;{\mu}m$, the optimum mixture ratio with composition variables by changing $1\;wt\%$ of each component that was silica sol$(4.3\~7.3\;wt\%)$ as an inorganic binder, CMC (Sodium CarboxyMethyl Cellulose $(6\~9\;wt\%)$) as an organic binder and paper powder$(4.7\~7.7\;wt\%)$ was obtained. As a result of the investigation on a composition containing $60\;wt\%$ diatomite, $5.3\;wt\%$ silica sol, and $7\;wt\%$ CMC, a heat-resisting protection tube that could be used as a molten steel probe for measuring the temperature and components of molten steel was developed. The bending strength, compressive strength, and elastic modulus of the protection tube developed, that contained $\le2.3\;wt\%$ carbon, were 7.1 MPa, 7.5 MPa, and 1090 MPa, respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.37 no.2
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• pp.55-58
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• 2004

The objective of this study was to get information about water retention characteristics of horticultural substrates used in Korea determined by European standard method. Water retention curves were prepared at water volume (v/v, %) in relation to -10 cm, -50 cm, -100 cm water pressure head. Water retention curves showed different properties depending upon the type, the place of origin, particle size, and manufacturing processes of substrates. Peat and coir had easily available water content in the range of 30-40% and showed high water holding capacity, water buffering capacity, and aeration for plant growth. However, bark, sawdust and rice hull showed low water holding capacity about below 10%. The easily available water content of perlite and clay ball was low about 0.1-13.8%, whereas that of vermiculite and rockwool granulate was high about 25.9-52.0%. Understanding water retention characteristics of growing substrates is very important in cstablisliing optimum condition for plant growth. Further study on water retention curves for more substrates, mixture and growing media is needed.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.5
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• pp.469-484
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• 2016

HR-ToF-AMS was applied for a seasonal and size-distributional measurements for inorganic ($SO{_4}^{2-}$, $NO_3{^-}$, $NH_4{^+}$, $Cl^-$) and organic components in Baegryung Island Super Site. The average concentration of $PM_{1.0}$ remarks $12.9{\mu}g/m^3$ while $14.5{\mu}g/m^3$ in Spring time, $14.2{\mu}g/m^3$ in Winter, $13.1{\mu}g/m^3$ in Summer and $9.86{\mu}g/m^3$ in Autumn. The mass of measured $PM_{1.0}$ shows 54.6% of $PM_{2.5}$ which is similar to those of Beijing and Lanzhou, China. The highest portion of Chemical composition is $SO{_4}^{2-}$ marking 41.0%, 31.8% by organics, 13.5% by $NH_4{^+}$, 12.8% by $NO_3{^-}$ and 1% by $Cl^-$. In every seasons, except winter, $SO{_4}^{2-}$ remarks the highest level, organic components take place the highest in winter time. The size-distribution of $PM_{1.0}$ components scattered at accumulation mode of 200 nm~800 nm which means the influence of primary emission is low. In case of air stream from the industrialized area of Sandung, Shanghai, China, the concentrations of such components were distributed a bit higher.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.5
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• pp.312-320
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• 2013

Particulates in drinking water distribution system (DWDS) are mostly influenced by internal corrosion of metal pipes and sediment in pipelines due to the solution of this effect is limited. The particle size, component and properties of compounds for particulates in distributed water are different and the difference of these characteristics will be occurred by the kind of facilities, pipe condition, external factors and supply system etc. In this study, conducting the investigation of water quality in DWDS researches with particulates in the water. Monitoring sites were each water supply reservoir and the end of water supply area in DWDS. To collect particulate material at each sampling site, $47{\phi}$ glass microfiber filter type GF/C was performed using a filtration. Substances that the effect of the turbidity in the water according to particulate suspended solids and inorganic materials is due to the increasing particulates in the end of DWDS were increased. The result of compounds analysis by using X-ray diffraction (XRD) were Goethite (${\alpha}$-FeOOH), Magnetite ($Fe_3O_4$) in the end of DWDS and Quartz ($SiO_2$), Yeelimite ($Ca_4Al_6O_{12}SO_4$) at the effluent of waterworks and reservoirs. There were differences the compounds and sediments in the releasing or remaining water distribution facilities.

• Journal of Conservation Science
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• v.33 no.6
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• pp.431-442
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• 2017

The purpose of this study is to reveal that coloring status and the degree of damage and the kinds of pigments used in large buddhist painting (Gwaebultaeng) of Tongdosa temple using a scientific analysis methods. It was observed that the physical damage patterns of the Gwaebultaeng were folding, lifting, fading, and peeling. Lead red, cinnabar and organic pigments were used as red pigments. Malachite and atacamite were used as green pigments, azulite and lazulite were blue pigments, lead white and talc were white pigment. It is estimated that overlapping organic pigments on the lead white were used as the yellow pigment and carbon was the black pigment. Through the analysis of the particle status of the pigments, it was confirmed that different types of raw materials were used for the green pigment, and the crystal form was easily distinguishable. Also, the dark blue color and the light blue color differed from each other depending on the size and shape of the raw material particles. Yellow and purple colors were organic pigments which did not have a graininess. The yellow and purple colors were organic pigments free from the graininess, and the pigments of dark red pigments was found to be mixed with the orange color pigments and carbon particles.

• Journal of the Mineralogical Society of Korea
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• v.32 no.4
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• pp.259-271
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• 2019

We evaluated mineralogical, physical property and accelerated weather resistance of cinnabar, realgar and orpiment used as cultural heritages and traditional paintings. JB and JS are sample names of cinnabar and JH and UH are sample names of orpiment and Realgar, respectively. As a result of mineralogical property evaluation, Jinsa was identified cinnabar (HgS) and there was no difference in chemical composition according to the grade. UH and JH were confirmed realgar (AsS) and orpiment (As₂S₃), respectively. The polarization characteristics such as shape and color indicate that pigments using our test were natural mineral pigment observed by polarization microscope. Especially, in the case of cinnabar, it is not easy to distinguish between natural mineral pigment and synthetic pigment. But the results of polarization microscope said that cinnabar is natural occurring mineral which have authentic mineral particle and unevenly fracture. As a result of thermal analysis, JH has a higher glass transition temperature and heat stability than UH. After accelerated weather test, cinnabar, realgar and orpiment were striking result in color change because of light degradation. Red color of cinnabar turn into black and the color of realgar and orpiment became brighter than before. JB (meta-cinnabar) is more photosensitivity and faster becoming dark than JB (cinnabar). Finally light transforms realgar (red, As₄S₄) in arsenolite (As₂O₃).

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.330-339
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• 2008

Effect of additives such as NP series nonionic surfactant and cosurfactant on AgCl nanoparticles was investigated where nanoparticles were prepared using two different types of water-in-oil (W/O) microemulsions containing silver nitrate and sodium chloride, respectively. Phase behavior experiments showed that the region of one phase W/O microemulsion was found to be broadened with an increase in the ethylene oxide length of a nonionic surfactant mainly due to an increase in hydrophilic nature of a surfactant. Photomicrographs obtained by transmission electron microscopy indicated that an increase in ethylene oxide length of a nonionic surfactant results in both increases in particle size and size distribution. Phase behavior experiments for the systems containing AOT surfactant, isooctane and aqueous solution of an inorganic salt showed that addition of a cosurfactant caused a shrinkage in phase region of one phase W/O microemulsion, especially water contents contained in W/O microemulsion with an increase in the chain length or the concentration of a cosurfactant used. Photomicrographs obtained by transmission electron microscopy indicated that characteristics of AgCl nanoparticles produced were dependent both on the radius of spontaneous curvature and film rigidity of a microemulsion.

• Korean Chemical Engineering Research
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• v.54 no.6
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• pp.746-752
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• 2016

In this study, soft carbon was prepared by carbonization of carbon precursor (pitch) obtained from PFO (pyrolysis fuel oil) heat treatment. Three carbon precursors prepared by the thermal reaction were 3903 (at $390^{\circ}C$ for 3 h), 4001 (at $400^{\circ}C$ for 1 h) and 4002 (at $400^{\circ}C$ for 2 h). After the prepared soft carbon was ground to a particle size of $25{\sim}35^{\circ}C$, the soft carbon was synthesised by the chemical treatment with boric acid ($H_3BO_3$). The prepared soft carbon were analysed by XRD, FE-SEM and XPS. Also, the electrochemical performances of soft carbon were investigated by constant current charge/discharge test, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC=1:1 vol%+VC 3 wt%). The coin cell using soft carbon of $25{\sim}35^{\circ}C$ with 3903 soft carbon ($H_3BO_3$/Pitch=3:100 in weight) has better initial capacity and efficiency (330 mAh/g, 82%) than those of other coin cells. Also, it was found that the retention rate capability of 2C/0.1C was 90% after 30 cycles.

• Korean Journal of Ecology and Environment
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• v.36 no.3 s.104
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• pp.311-321
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• 2003

We surveyed physico-chemical properties of bottom water and sediment to evaluate the influence of sediment on the eutrophication in the downstream of Nagdong River from 1998 to 2000. From May to August, DO concentration of bottom waters dropped below 5 mg $O_2/l$ and $NH_4\;^+$ and $PO_4\;^{3-}$ concentrations significantly increased in the bottom waters, resulting in the great differences between surface and bottom waters. Fluxes across water-sediment interface would be substantially active in this period. The serial orders of the water fertility or eutrophication were Joman River > Sonagdong River > Nagdong River. The organic nutrient contents of sediment increased toward the lower parts of the river system. Organic contents of the sediment would be under the influence of water pollution and exhibited a negative correlation with sediment bulk-density or particle size. The concentrations of exchangeable inorganic nutrients of sediment were greater than those of pore waters, and $PO_4\;^{3-}$, $NH_4\;^+$ and $SiO_2$ increased along the sediment depth. $PO_4\;^{3-}$ and $NO_3\;^-$ concentrations of the pore water were less than the overlying waters, while NH4+ and $SiO_2$ concentrations showed opposite trends. Exchangeable nutrients of sediment could be the repository for t]me nutrient exchange in the water-sediment interface.