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Study on Determination of Design Factor of Bioreactor for Sulfate Reduction in Mine Drainage (광산배수 내 황산염 저감을 위한 생물반응기의 설계인자 도출 연구)

  • Kim, Kang-Ho;Kang, Chan-Ung;Kim, Sun-Joon;Kim, Tae-Heok;Ji, Won-Hyun;Jang, Hang-Seok;Park, Hyun-Sung
    • Journal of the Korean Society of Mineral and Energy Resources Engineers
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    • v.55 no.6
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    • pp.527-537
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    • 2018
  • Column tests of a sulfate reducing bacteria (SRB) bioreactor were conducted to determine the design factors for sulfate-rich mine drainage. Various substrates were applied to the bioreactor, including cow manure and its mixture with a mushroom compost, with rice straw and limestone as subsidiary materials. This procedure provided a removal efficiency of up to 82% of the total sulfur with the mixture of cow manure (70%), mushroom compost (10%) and rice straw (20%), and higher efficiencies were observed after 2 days of retention time. In the downflow condition of the flow direction, oxygen supply and re-oxidation of the sulfates occurred, causing a decrease in sulfate removal efficiency. The addition of an inorganic sludge containing heavy metals, which was intended for production of metal-sulfides in the bioreactor, had a negative effect on the long-term operation owing to arsenic release and toxicity to the SRB. The results thus show that a bioreactor using a mixed substrate with cow manure and operating in the downflow direction could reduce sulfates and total dissolved sulfur content; this process confirms the applicability of the SRB bioreactor to sulfate-rich saline drainage.

Study on Electrochemical Performances of PEO-based Composite Electrolyte by Contents of Oxide Solid Electrolyte (산화물계 고체전해질 함량에 따른 PEO 기반 복합전해질 전기화학 성능 연구)

  • Lee, Myeong Ju;Kim, Ju Young;Oh, Jimin;Kim, Ju Mi;Kim, Kwang Man;Lee, Young-Gi;Shin, Dong Ok
    • Journal of the Korean Electrochemical Society
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    • v.21 no.4
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    • pp.80-87
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    • 2018
  • Safety issues in Li-ion battery system have been prime concerns, as demands for power supply device applicable to wearable device, electrical vehicles and energy storage system have increased. To solve safety problems, promising strategy is to replace organic liquid electrolyte with non-flammable solid electrolyte, leading to the development of all-solid-state battery. However, relative low conductivity and high resistance from rigid solid-solid interface hinder a wide application of solid electrolyte. Composite electrolytes composed of organic and inorganic parts could be alternative solution, which in turn bring about the increase of conductivity and conformal contact at physically rough interfaces. In our study, composite electrolytes were prepared by combining poly(ethylene oxide)(PEO) and $Li_7La_3Zr_2O_{12}$ (LLZO). The crystallinity, morphology and electrochemical performances were investigated with the control of LLZO contents from 0 wt% to 50 wt%. From the results, it is concluded that optimum content and uniform dispersion of LLZO in polymer matrix are significant to improve overall conductivity of composite electrolyte.

Effect of Organic Materials Use Recommendation System on Soil N Mineralization and Rice Productivity in Organic Paddy (유기자원 사용처방 기준 적용에 따른 토양 질소 무기화 및 유기 벼 생산성)

  • Lee, Cho-Rong;Lee, Sang-min;Hwang, Hyeon-Yeong;Kwon, Hyeok-Gyu;Jung, Jung A;An, Nan-Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.2
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    • pp.15-23
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    • 2021
  • This study was conducted to evaluate the field application of the developed recommendation system in organic rice (Oriza sativa L.) paddy and to investigate the mineral nitrogen content in soil and rice productivity. According to the developed system, hairy vetch (HV), rye+rapeseed oil cake (R+OC), rapeseed oil cake (OC) for only basal fertilization (OC-B), OC for split application (OC-S), pig manure compost (PMC), and chemical fertilizer (CHM) were applied to paddy soil at the rate of 107~133 kg N/ha. Results were followed, unhulled rice yield of OC-S (111%), OC-B (110), R+OC (106), HV (101), and PMC (96) were no significantly different with CHM (100). Also there was positive correlation (R2=0.803*) between unhulled rice yield and cumulative inorganic N in soil. For nitrogen use efficiency of rice, OC-B, OC-S, and R+OC were not significantly different with CHM. In conclusions, the developed organic materials use recommendation system was effective for organic rice productivity. It could be useful for organic farmer to apply the organic materials use recommendation system for rice.

Comparative Analysis of the Nutritional and Bioactive Components of White and Brown Button Mushrooms (백색양송이와 갈색양송이의 영양성분 및 생리활성 성분 비교 분석)

  • Oh, Youn-Lee;Kim, Minseek;Jang, Kab-Yeul;Oh, Min Ji;Im, Ji-Hoon;Lee, Jong-Won
    • Journal of Mushroom
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    • v.20 no.3
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    • pp.119-126
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    • 2022
  • As the importance of public health increases with the spread of infectious diseases, functionality has become a factor affecting consumers' purchase of mushrooms. Therefore, the bioactive components of button mushrooms (Agaricus bisporus), which are generally known to promote button mushroom consumption, were analyzed. White and brown button mushrooms were compared and white beech mushroom (Hypsizygus marmoreus) were used as a control. White button mushrooms had higher sugar and inorganic potassium concentrations than brown button mushrooms, whereas sodium, magnesium, and vitamin C concentrations were not significantly different between the different button mushrooms. Moreover, there was approximately twice as much ergosterol in white button mushrooms than brown button mushrooms. Brown button mushrooms had higher concentrations of 𝛽-glucan and oxalic acid than white button mushrooms, but there was no significant difference in total organic acid content between the two mushroom types. High concentrations of the essential amino acids, ergothioneine, isoleucine, and leucine and the non-essential amino acids, glycine and alanine, were observed. Concentrations of the vitamin B group and total polyphenols were also high.

Effect of γ-Aminobutyric Acid and Probiotics on the Egg Quality, Blood Parameter, Stress Level in Broiler Breeder (γ-Aminobutyric Acid 및 생균제 급여가 여름철 육용 종계의 계란 품질 및 혈액 성상에 미치는 영향)

  • Yoo Don, Ko;Ji Heon, Kim;Ha Guyn, Sung
    • Korean Journal of Poultry Science
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    • v.49 no.4
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    • pp.247-253
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    • 2022
  • This study was conducted to investigate the effects of γ-aminobutyric acid (GABA) and a probiotic mixture on egg quality, blood parameters, and corticosterone content in broiler breeder stock in summer in Korea. A total of 72 broiler breeders (Arbor Acres) at 49 weeks old were randomly divided into the following three groups of 24 heads each: control, GABA, and probiotics (1 × 108/g Bacillus licheniformis, 1 × 107/g Lactiplantibacillus plantaru, and 1 × 107/g Clostridium butyricum). The hens were fed a diet containing 50 mg of GABA/kg of feed and 0.1% probiotics for 6 weeks. Egg quality, blood parameters, and stress levels (corticosterone concentration) of the broiler breeders were evaluated. No significant differences were observed in the egg weight, albumen height, Haugh units, yolk color, shell thickness, or shell strength between the groups. There were no significant between-group differences in the blood biochemical profile, including total cholesterol, triglyceride, glucose, total protein, aspartate aminotransferase, alanine aminotransferase, albumin, and inorganic phosphorus concentrations. The corticosterone concentration was significantly lower in the GABA and probiotics groups than the control group (P < 0.05) at 6 weeks of age. In conclusion, these results suggest that dietary probiotics and GABA significantly improve the stress levels of broiler breeders in summer in Korea.

Evaluation of Characteristics of Sludge generated from Active Treatment System of Mine Drainage (광산배수의 적극적 처리시설에서 발생하는 슬러지 특성 평가)

  • Jung-Eun Kim;Won Hyun Ji
    • Economic and Environmental Geology
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    • v.56 no.4
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    • pp.409-419
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    • 2023
  • Acid mine drainage(AMD) treatment is classified as both passive and active treatment. During the treatment, about 5,000 tons of neutralization sludge is generated as a by-product per year in Korea. This study was conducted to evaluate the characteristics of sludge generated from physico·chemical treatment processes as an active treatment from 5 different sources (D, H, S, T, Y) and the possibility of the sludges being recycled. The sludges have a pH range of 5.86 ~ pH 7.89, and a water content range of 51% ~ 82%. Most of particle sizes were less than 25 ㎛. In analysis of inorganic elements, the concentration of Al, Fe, and Mn were between 1,189 mg/kg ~ 129,344 mg/kg, 106,132 mg/kg ~ 338,011 mg/kg, and 3,472 mg/kg ~ 11,743 mg/kg, respectively. The concentration of As and Zn in sludge-T, Cd in sludge-D, Ni in sludge-H, Zn in sludge-S, and Cd in sludge-Y exceeded the soil contamination standards of Korea. The results from 2 separate kinds of leaching test, the Korea Standard Leaching Test(KSLT) and Toxicity Characteristic Leaching Procedure(TCLP), showed that all the sludges met the Korea groundwater standards. From the XRD and SEM-EDS analysis, the peaks of calcite and quartz were found in the sludges. The sludge also had a high proportion of Fe and O, and the majority of the composition was amorphous iron hydroxide.

Studies on the Improvement of RiceCultivation in the Ill-drained Paddy Field II. The Effects of Fertilizations and Planting Densities on Growth and Yield of Ricein the Underchannel Drainage (습답도작기술향상에 관한 연구 제2보 지하수가 시비량과 재배밀도를 달리한 수도의 생육 및 수량에 미치는 영향)

  • Goo, Y.S.;Nho, S.P.;Whang, C.J.;Nha, J.S.;Lee, J.B.;Jung, J.Y.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.21 no.1
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    • pp.43-51
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    • 1976
  • Marine deposite soil was studied to evaluate morohological changes of paddy rice under subdrainage control. The content of organic and inorganic mate rial were low at high temperature in the mid-summer. This soil lacked air and accumulated more H$_2$ S. Thus rice root was rotted with high infection of virus and insect and yield was relatively low.

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Experimental Study on the Manufacturing and Waterproofing Properties of Self-healing Concrete Waterproofing Agent Using Microcapsules (마이크로캡슐을 활용한 자기치유 구체방수제의 제조 및 방수특성에 관한 실험적 연구)

  • Yun-Wang Choi;Jae-Heun Lee;Neung-Won Yang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.289-298
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    • 2023
  • In this study, the development of a self-healing concrete waterproofing agent was examined, focusing on its manufacturing and waterproofing properties. The optimal ratio using microcapsules for the concrete waterproofing agent was determined through assessments of flow, compressive strength, and permeability conducted during the mortar stage. These findings aimed to provide fundamental data for evaluating the self-healing properties of the concrete waterproofing agent designed for use in concrete structures. The self-healing concrete waterproofing agent was comprised of three types of inorganic materials commonly used for repair purposes. From experimental results, a composition ratio with a high potassium silicate content, referred to as SIM-2, was found suitable. A surfactant mixing ratio of 0.03 % was identified to enhance the dispersibility of the concrete waterproofing agent, while a mixing ratio of 0.2 % distilled water was deemed suitable for viscosity adjustment. For the magnetic self-healing concrete waterproofing agent's healing agent, using microcapsules in the range of 0.5 % to 0.7 % met the KS F 4949 and KS F 4926 standards.

Organic Manure Compost and Inorganic Fertilizer Levels Affect Maize Growth in Barren Soils (척박지에서 퇴비와 무기질 비료가 옥수수 생장에 미치는 영향)

  • Kyung-Hee Kim;Gyu Won Kim;Sang-Ryong Lee;Byung-Moo Lee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.68 no.4
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    • pp.383-391
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    • 2023
  • This study aimed to investigate the effect of manure compost content on early growth of maize in barren soils, to establish cultivation techniques that can increase maize yields on barren soils and to provide information on cultivation techniques. The results showed that in the manure compost treatments (1,500 and 1,000 kg/10a), yields increased with increasing amounts of manure compost compared to those of standard fertilization and decreased with decreasing amounts of manure compost. In addition, in fields with the no manure compost treatment (0 kg/10a), yields decreased overall compared to yields of fields treated with manure compost (1,500 and 1,000 kg/10a) regardless of the amount of fertilization. Maize growth was good irrespective of variety when compost was applied in high amounts to the barren soil, but poor initial growth was observed in all varieties in the untreated plots where no compost was applied to the barren soil. These results confirm that maize is affected by organic (manure compost) fertilizer in all aspects of its growth, and that a minimum of 1,000 kg/10a of manure compost and two-thirds (0.6) of chemical fertilizer should be applied to ensure stable maize yields, particularly when maize is grown on barren soils.

Photosynthetic Characteristics of Benthic Microalgae Measured by HPLC and Diving Pulse Amplitude Modulated (PAM) Fluorometry on the Nakdong River Estuary of the Korean Peninsula (HPLC 및 Diving-PAM을 이용한 낙동강 하구 저서미세조류의 광합성 특성)

  • Jeong Bae Kim;Mi Hee Chung;Jung-Im Park
    • Korean Journal of Ecology and Environment
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    • v.57 no.2
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    • pp.61-74
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    • 2024
  • Daemadeung, located in the estuary of the Nakdong River, is formed by sand dunes and possesses well-developed intertidal flats. This study aimed to investigate the habitat of benthic microalgae, photosynthetic pigments, and photosynthetic efficiency in the intertidal flats of Daemadeung from January to December 2011. The inorganic nitrogen content in the sediment pore water was primarily composed of ammonium, while nitrate + nitrite was dominant in the upper layer water. The concentration of chlorophyll a and fucoxanthin in the sediment surface was significantly higher than the mean of all the sediment layer. The average Fv/Fm of benthic microalgae during the entire survey period was 0.52±0.03, with the highest value (0.61±0.08) observed in February. The rETRmax showed a seasonal trend, being high from spring to early autumn (April to October) and low from winter to early spring (January to March, November, December), with the highest value (153.05±2.30 µmol electrons m-2 s-1) in July and the lowest (38.49±5.17 µmol electrons m-2 s-1) in January. The average Fv/Fm of diurnal microalgae was 0.48±0.03, with the highest value (0.61±0.08) observed at noon. The rETRmax showed a highest peak at noon (54.24±11.35 µmol electrons m-2 s-1) and reached its lowest point at 16:00 (26.17±4.75 µmol electrons m-2 s-1). These findings suggest that the productivity of benthic microalgae varies significantly depending on the survey time and sediment depth. Therefore, to quantify the productivity of benthic microalgae using Diving-PAM, surveys should be conducted based on tidal conditions, and simultaneous pigment analysis of sediment layers should also be performed.