• Carbon letters
• /
• 제25권
• /
• pp.14-24
• /
• 2018

Electrochemical properties and performance of composites performed by incorporating metal oxide or metal hydroxide on carbon materials based on graphene and carbon nanotube (CNT) were analyzed. From the surface analysis by field emission scanning electron microscopy and field emission transmission electron microscopy, it was confirmed that graphene, CNT and metal materials are well dispersed in the ternary composites. In addition, structural and elemental analyses of the composite were conducted. The electrochemical characteristics of the ternary composites were analyzed by cyclic voltammetry, galvanostatic charge-discharge tests, and electrochemical impedance spectroscopy in 6 M KOH, or $1M\;Na_2SO_4$ electrolyte solution. The highest specific capacitance was $1622F\;g^{-1}$ obtained for NiCo-containing graphene with NiCo ratio of 2 to 1 (GNiCo 2:1) and the GNS/single-walled carbon $nanotubes/Ni(OH)_2$ (20 wt%) composite had the maximum specific capacitance of $1149F\;g^{-1}$. The specific capacitance and rate-capability of the $CNT/MnO_2/reduced$ graphene oxide (RGO) composites were improved as compared to the $MnO_2/RGO$ composites without CNTs. The $MnO_2/RGO$ composite containing 20 wt% CNT with reference to RGO exhibited the best specific capacitance of $208.9F\;g^{-1}$ at a current density of $0.5A\;g^{-1}$ and 77.2% capacitance retention at a current density of $10A\;g^{-1}$.

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2002년도 봄 학술발표회 논문집
• /
• pp.321-324
• /
• 2002

Recently, organic-inorganic nanocomposites have attracted great interest from researchers since they frequently exhibit unexpected hybrid properties synergistically derived from two components[1]. The addition of highly dispersed inorganic nano-sized fillers permits improvement of certain properties of polymers as compared with conventional particulate composites; increase of modulus and strength, improved barrier properties, increase in solvent and heat resistance, and good optical properties[2]. (omitted)

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
• /
• pp.73-76
• /
• 2002

This study developed SiC/Al composites for electronic packaging to which reinforcements were added with the volume fractions of 49%, 56% and 63% by the squeeze casting method. 0.8 wt.% of the inorganic binder as well as the $Al_2O_3$ fiber and SiC particles with the volume fraction of 1:10 were added to the SiC/Al composites For the produced SiC/Al composites, the CTEs (coefficients of thermal expansion) were measured from 30 to $300^{\circ}C$ and compared with the FEM numerical simulation to analyze the temperature dependent properties. The experiment showed the CTEs of SiC/Al composites that were intermediate values of those of Rule of Mixture and Turner's Model. The CTEs were close to Turner's Model in the room temperature and approached the Rule of Mixture as the temperature increases. These properties analyzed from the difference of the average stress acting between the matrix and the reinforcements proposed in this study

• KSBB Journal
• /
• 제25권5호
• /
• pp.409-420
• /
• 2010

Biopolymer-based materials recently have garnered considerable interest as they can decrease dependency on fossil fuel. Biopolymers are naturally obtainable macromolecules including polysaccharides, polyphenols, polyesters, polyamides, and proteins, that play an important role in biomedical applications such as tissue engineering, regenerative medicine, drug-delivery systems, and biosensors, because of their inherent biocompatibility and biodegradability. However, the insolubility of unmodified biopolymers in most organic solvents has limited the applications of biopolymer-based materials and composites. Ionic liquids (ILs) are good solvents for polar organic, nonpolar organic, inorganic and polymeric compounds. Biopolymers such as cellulose, chitin/chitiosan, silk, and DNA can be fabricated from ILs into films, membranes, fibers, spheres, and molded shapes. Various biopolymer/biopolymer and biopolymer/synthetic polymer composites also can be prepared by co-dissolution of polymers into IL mixtures. Heparin/biopolymer composites are especially of interest in preparing materials with enhanced blood compatibility.

• 한국세라믹학회지
• /
• 제45권8호
• /
• pp.443-452
• /
• 2008

Shrinkage crack is a major concern for cement materials, especially for flat structures such as Korean On-Dol floor system, flooring for garages, and wall. One of the methods to reduce the adverse effects of shrinkage cracking is to reinforce cement materials with shot randomly distributed fibers. The efficiency of inorganic fibrous material to arresting cracks in cementitious composites was studied. Cement materials reinforced with five different qualities of inorganic fibrous material were tested. Contents of inorganic fibrous material were 1.0 kg, 1.5 kg, 2.0 kg, 2.5 kg, 3.0 kg by weight of cement mortar and C : S types of cement mortar were 1:3 and 1:4. W/C were 60% and 80%. Cement mortar of inorganic fibrous material reinforcement showed an ability to reduce the crack width and crack length significantly as compared to unreinforced cement mortar. $40%{\sim}60%$ drop in shrinkage crack of 1:4 cement mortar with 1.5 kg over was observed.

• Elastomers and Composites
• /
• 제46권2호
• /
• pp.138-143
• /
• 2011

EPDM에 카본블랙과 더불어 무기 충전제인 탈크, 탄산칼슘, 혹은 클레이를 함께 혼합하여 EPDM 배합물과 가황물을 제조하여, 무기 충전제가 EPDM 배합물과 가황물의 특성에 미치는 영향을 조사하였다. 무기 충전제를 추가해도 결합 고무 함량(bound rubber content)에는 큰 차이가 없었다. 무기 충전제 함량이 높을수록 큰 입자로 존재함을 확인하였다. 무기 충전제를 추가하면 가교 시간은 전반적으로 증가하는 경향을 보였으며, 델타 토크(delta torque)는 감소하였다. 무기 충전제를 추가하면 모듈러스는 전반적으로 감소하였으나, 신율과 인장강도 그리고 인열강도는 증가하였다. 모듈러스의 감소와 신율의 증가는 가교밀도의 감소로 설명하였으며, 인장강도와 인열강도의 증가는 신율의 증가로 설명하였다. 무기 충전제의 첨가에 의해 보강성은 증가하지 않았고 가교밀도는 감소하였다.

• 자연과학논문집
• /
• 제8권1호
• /
• pp.53-59
• /
• 1995

Alumina 세라믹스의 기계적 물성 증진을 위하여 SiC whisker로 강화시키고 소결 조제 및 소결 온도의 영향을 고찰하였다. Whiker의 소결억제 효과로 인하여 고상소결을 촉진하는 MgO나 $TiO_2$를 소결조제로 사용한 경우에서는 치밀한 소결체를 얻을 수 없었으나, 액상을 형성하는 $Y_2O_3$를 2wt% 첨가한 경우에 양호한 소결밀도를 얻을 수 있었다. whisker 첨가에 의한 기지의 기계적 물성의 증진 효과도 함께 얻을 수 있었다. 강화 효과는 보강재인 whiker 자체의 보강 효과와 함께 입성장 억제 효과가 복합적으로 작용한 것으로 판단되었다. 소결체를 HIP 처리한 경우에는 거의 이론 밀도까지 이르는 아주 치밀한 소결체의 제조가 가능하였으며, 기계적 물성은 상압소결 후의 결과에 비하여 향상됨을 확인할 수 있었다.

• Elastomers and Composites
• /
• 제45권2호
• /
• pp.87-93
• /
• 2010

내화재료는 건축물에서 화재사고로부터 화염을 차단하기 위해 사용된다. 본 연구에서는 실리콘 고무에 무기계 난연제인 aluminium trihydroxide(ATH, $Al(OH)_3$)와 magnesium dihydroxide(MDH, $Mg(OH)_2$)를 첨가한 복합체를 기계적 교반으로 제조한 후 내화성능향상에 관한 연구를 진행하였다. 내화재료의 열 특성분석을 위해 TGA를 사용하였고, rheometer를 이용해 유변학적 분석을 하였다. 내화특성을 분석하기 위해 gas torch를 이용하였다. 본 연구를 통하여 ATH와 MDH가 첨가되면 실리콘 고무의 내화성능이 향상됨을 알 수 있었다.

• 한국재료학회지
• /
• 제19권1호
• /
• pp.33-36
• /
• 2009

Inorganic-organic composite thin-film-transistors (TFTs) of ZnO nanowire/Poly(3-hexylthiophene) (P3HT) were investigated by changing the nanowire densities inside the composites. Crystalline ZnO nanowires were synthesized via an aqueous solution method at a low temperature, and the nanowire densities inside the composites were controlled by changing the ultrasonifiaction time. The channel layers were prepared with composites by spin-coating at 2000 rpm, which was followed by annealing in a vacuum at $100^{\circ}C$ for 10 hours. Au/inorganic-organic composite layer/$SiO_2$ structures were fabricated and the mobility, $I_{on}/I_{off}$ ratio, and threshold voltage were then measured to analyze the electrical characteristics of the channel layer. Compared with a P3HT TFT, the electrical properties of TFT were found to be improved after increasing the nanowire density inside the composites. The mobility of the P3HT TFT was approximately $10^{-4}cm^2/V{\cdot}s$. However, the mobility of the ZnO nanowire/P3HT composite TFT was increased by two orders compared to that of the P3HT TFT. In terms of the $I_{on}/I_{off}$ ratio, the composite device showed a two-fold increase compared to that of the P3HT TFT.

• 한국전기전자재료학회논문지
• /
• 제31권7호
• /
• pp.496-501
• /
• 2018

In this study, we prepared 40, 45, 50, 55, 60, 65, and 70 wt% content composites filled in epoxy matrix for two micro silica and three micro alumina types for use as a GIS heavy electric machine. As a filler type of epoxy composite, micro silica composites showed excellent AC breakdown strength properties compared to micro alumina composites in the case of electrical properties of micro silica and alumina. The electrical breakdown properties of micro silica composites increased with increasing filler content, whereas those of micro alumina decreased with increasing filler content. In the case of mechanical properties, the micro silica composite showed improved tensile strength and flexural strength compared with the micro alumina composite. In addition, mechanical properties such as tensile strength and flexural strength of micro silica and alumina composites decreased with increasing filler content. This is probably because O-H groups are present on the surface of silica in the case of micro silica but are not present on the surface of alumina in the case of micro alumina.