• Title/Summary/Keyword: inorganic N

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Contribution of Rice Mill Ash and Press Mud with Inorganic Fertilizers to Sugarcane Production in Old Himalayan Piedmont Plain Soils of Bangladesh

  • Paul G. C.;Rahman M.;Khan N. U.;Rahman A. B. M. M.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.2
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    • pp.108-111
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    • 2005
  • A field study was conducted to develop an economically suitable combination of organic and inorganic fertilizers for sugarcane cultivation in sandy acidic soil of a commercial sugarcane farm under Old Himalayan Piedmont Plain of Bangladesh. Results revealed that the treatment $T_4$ which received $75\%$ of Recommended fertilizers (N 120, P 35, K 100, S 25, Zn 2 kg $ha^{-1}$) + 10 Mg $ha^{-1}$ Rice mill ash + Mg $ha^{-1}$ press mud significantly produced higher sugarcane yield (72.34 Mg $ha^{-1}$) among all the treatments except $T_5$ having $100\%$ of Recommended fertilizers + 10 Mg $ha^{-1}$ Rice mill ash + 10 Mg $ha^{-1}$ press mud, which was identical. $T_4$ also gave the highest net economic benefit at Bangladesh Taka 15,920.47 per hectare from the added nutrient management. Thus, the integrated use with organic and inorganic fertilizer is highly essential for sustainable production of sugarcane in commercial farm of the region in Bangladesh, where it has been grown year after year.

Fabrication of Organic-Inorganic Nano Hybrid Superlattice Thin Films by Molecular Layer Deposition

  • Cho, Bo-Ram;Yang, Da-Som;Sung, Myung-M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.115-115
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    • 2011
  • Nano hybrid superlattices consisting of organic and inorganic components have great potential for creation of new types of functional material by utilizing the wide variety of properties which differ from their constituents. They provide the opportunity for developing new materials with new useful properties. Herein, we fabricated new type of organic-inorganic nano hybrid superlattice thin films by a sequential, self-limiting surface chemistry process known as molecular layer depostion (MLD) combined with atomic layer deposition (ALD). An organic layer was formed at $150^{\circ}C$ using MLD with repeated sequintial adsorption of Hydroquinone and Titanium tetrachloride. A $TiO_2$ inorganic nanolayer was deposited at the same temperature using ALD with alternating surface-saturating reactions of Titanium tetrachloride and water. Using UV-Vis spectroscopy, we confirmed visible light absorption by LMCT. And FTIR spectroscopy and XPS were employed to determine the chemical composition. Ellipsometry and TEM analysis were also used to confirm linear growth of the film versus number of MLD cycles at all same temperature. In addition, p-n junction diodes domonstrated in this study suggest that the film can be suitable for n-type semiconductors.

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The Effect of PEDOT:PSS Thickness on the Characteristics of Organic-Inorganic Hybrid Solar Cells (PEDOT:PSS의 두께가 유무기 하이브리드 태양전지 성능에 미치는 영향)

  • Kim, Souk Yoon;Han, Joo Won;Oh, Joon-Ho;Kim, Yong Hyun
    • Current Photovoltaic Research
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    • v.7 no.3
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    • pp.61-64
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    • 2019
  • In this study, we investigate organic-inorganic hybrid solar cells with a very simple three-layer structure (Al/n-Si/PEDOT:PSS). The performance of hybrid solar cells is optimized by controlling the sheet resistance and optical transmittance of the PEDOT:PSS layers. As the thickness of the PEDOT:PSS layer decreases, the optical absorption of the n-Si increases, which greatly improves the short-circuit current density ($J_{SC}$) of devices, but the increase in sheet resistance leads to a decrease in the open-circuit voltage ($V_{OC}$) and the fill factor (FF). The solar cell with the 180-nm thick PEDOT:PSS layer shows a highest efficiency of 8.45% ($V_{OC}$: 0.435 V, $J_{SC}$: $33.7mA/cm^2$, FF: 57.5%). Considering these results, it is expected that the optimizing process for the sheet resistance and transmittance of the PEDOT:PSS layer is essential for producing high-efficiency organic-inorganic hybrid solar cells and will serve as an important basis for achieving low-cost, high-efficiency solar cells.

Changes of Inorganic Nutrient Contents in Leaf of 'Niitaka' Pear and Inorganic Nutrient Contents of Leaf Influenced by Meteorological Elements (배 신고 품종의 잎 내 무기성분의 시기별 함량 변화와 잎 내 무기성분 함량에 미치는 기후요인)

  • Kim Ik-Youl;Ryu Jong-Ho;Kim Mi-Young
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.3
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    • pp.192-200
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    • 2005
  • This study was conducted to investigate inorganic nutrient contents in spur leaf and shoot leaf of 'Niitaka' pear during the growing season and leaf inorganic nutrient contents as influenced by meteorological elements. The contents of N, P, K, and Mg were decreased in spur leaf during their vegetative growth, while Ca and Mn increased. The contents of N, P, K, Mg, and Fe showed no differences between spur leaf and shoot leaf. However Ca, Mn, Zn, and Cu contents were higher in spur leaf than those in shoot leaf, but B content was lower in spur leaf than those in shoot leaf. The content of N in shoot leaf was positively correlated with mean temperature, whereas negatively correlated with maximum temperature. The content of P in spur leaf was negatively correlated with maximum temperature. The content of Ca in spur leaf was negatively correlated with mean temperature, whereas positively correlated with maximum and minimum temperature. The contents of Mg and B in shoot and spur leaf were positively correlated with mean temperature, whereas negatively correlated with maximum and minimum temperature. The contents of Ca and Mn showed significant differences between spur leaf and shoot leaf at mid-July to early August. These results suggest that sampling is important to distinguish between spur leaf and shoot leaf for diagnosis of nutrient conditions in pear trees.

1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides

  • Mardani, Zahra;Golsanamlou, Vali;Jabbarzadeh, Zahra;Moeini, Keyvan;Carpenter-Warren, Cameron;Slawin, Alexandra M.Z.;Woollins, J. Derek
    • Journal of the Korean Chemical Society
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    • v.62 no.5
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    • pp.372-376
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    • 2018
  • A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$ $\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

Investigation of the fate of inorganic nitrogens in the near field of bank filtration site (강둑여과지 주변의 밭에 살포된 무기질소의 거동 연구)

  • 공인철;배진희;안호준;권오억;김승현;이철희;박영규
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.11-20
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    • 1998
  • Inorganic nitrogens resulting from fertilizers are possible contaminants of bank-filtered ground water, which is an alternative source of safe drinking water. We conducted a laboratory study to determine the fate of inorganic nitrogens in the near field of bank filtration sites and we consequently illustrated the effects of these possible contaminants on the water quailty of bank filtration. Soil properties were found to be well equivalent to those of other cultivated field soils in Korea. Surface soil pH was about 4.3 which is slightly lower than average level. Overall, diverse concentrations of $NO_3$-N and $NH_3$-N were measured, and $NO_2$-N was nearly undetected. $NH_3$-N level in the field decreased, while $NO_3$-N increased along with increasing depth of unsaturated zone. Numbers of viable and nitrifying bacteria ranged from 6.73$\times$$10^{6}$to 10.7$\times$$10^{6}$ and 0.44$\times$$10^{4}$ to 5.21$\times$$10^{4}$ respectively, and both of them were highly correlated ($R^{2}$=0.992). Nitrifying potential assayed by batch test showed relatively lower than other reported results. The oxygen uptake potential of surface and subsurface soil was measured in the presence of ${(NH_4)_2}$$SO_4$. The results demonstrated that surface soil required shorter lag period and uptaked more oxygen than subsurface's.

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A Study on the Guide Line of Quality of Waterproofing Admixture of Powder Type for Concrete (콘크리트 혼입용 분말형 구체방수재의 품질기준에 관한 연구)

  • 우영제;배기선;오상근;김형무
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.967-974
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    • 2000
  • By testing compressive strength, water absorption and water premeablity, to establish the standard of quality of waterproofing admixture of power type for concrete, we propose guide line as following ; $.$Setting time: more than 1 hour, within 10 hours $.$Slump: To be satisfied with request of user $.$Air content: To be satisfied with request of user $.$Safety: Without crack or deformation $.$Ratio of compressive strength: $\circled1$ At 3 days : more than plain specimen by 0.9 (An inorganic material) more than plain specimen by 0.4 (An inorganic material mixed organic) $\circled2$ At 7, 28 days : more than plain specimen by 1.0 $.$Ratio of water absorption Coefficient: $\circled1$An inorganic material: less than plain specimen by 1.0 $\circled2$ An inorganic material mixed organic : under than plain specimen by 0.8 $.$Ratio of water premeablity : $\circled1$ An inorganic material : less than plain specimen by 1.0 $\circled2$ An inorganic material mixed organic : under than plain specimen by 0.8

Effects of Sintering Additives on the Microwave Dielectric and Sintering Characteristics of (1-x)CaT$iO_{3}$-xLa($Zn_{1}$2/$Ti_{1}$2/)$O_{3}$ (소결조제가 (1-x)CaT$iO_{3}$-xLa($Zn_{1}$2/$Ti_{1}$2/)$O_{3}$계의 소결 및 마이크로파 유전특성에 미치는 영향)

  • Kim, Jin-Seok;Yun, Cheol-Ho;Choe, Ju-Hyeon;Lee, Gyeong-Tae;Sin, Jong-Yun;Park, Hyeon-Su;Mun, Jong-Ha
    • Korean Journal of Materials Research
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    • v.7 no.10
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    • pp.872-876
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    • 1997
  • (1-x)CaTi $O_{3}$-xLa(Z $n_{1}$2/ $Ti_{1}$2/) $O_{3}$의 마이크로 유전특성을 조사하였다. x가 증가함에 따라 비유전율과 공진주파수의 온도계수는 감소하였으며, Qㆍ $f_{0}$는 증가하였다. 그 결과 x=0.5인 (C $a_{0.5}$L $a_{0.5}$)( $Ti_{0.75}$Z $n_{0.25}$) $O_{3}$의 조성에서 $\varepsilon$$_{r}$=51, Qㆍ $f_{0}$=38,000 (at 7 GHz), $\tau$$_{f}$=+5ppm/$^{\circ}C$의 유전특성이 나타났다. (C $a_{0.5}$L $a_{0.5}$)( $Ti_{0.75}$Z $n_{0.25}$) $O_{3}$조성의 소결온도를 저하시키기 위하여 B $i_{2}$ $O_{3}$를 주조성으로한 소결체를 첨가하여 소결 및 유전특성을 조사하였다. 1wt% 0.76B $i_{2}$ $O_{3}$-0.24NiO가 첨가된 경우 소결온도는 15$0^{\circ}C$ 낮아졌으며, 비유전율 ($\varepsilon$$_{r}$), 공진주파수의 온도계수($\tau$$_{f}$), Qㆍ $f_{0}$가 각각 50+5ppm/$^{\circ}C$, 35,000인 마이크로파 유전특성이 얻어졌다. 또한 3wt%의 0.76B $i_{2}$ $O_{3}$-0.24NiO가 첨가된 경우 소결온도는 20$0^{\circ}C$ 저하되었고, 비유전율 ($\varepsilon$$_{r}$)과 공진주파수의 온도계수 ($\tau$$_{f}$)는 변하기 않았으나, Qㆍ $f_{0}$값이 38,000에서 25,000으로 저하되었다. 25,000으로 저하되었다.되었다.되었다.되었다.

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Effect of Additives of Sintering and Mechanical Properties of $Si_3 N_4$ Bonded SiC ($Si_3 N_4$ 결합 SiC의 소결과 기계적 특성에 미치는 첨가제의 영향)

  • Baik, Yong-Hyuck;Shin, Jong-Yoon;Jung, Jong-In;Han, Chang
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.511-516
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    • 1992
  • In this study, SiC powder and Si powder were used as the raw materials. Mixture was prepared with addition of Al2O3 and Fe2O3 at 0.1~0.5wt% respectively. After this step, the mixture was pressed and nitrided for 30 hrs at 140$0^{\circ}C$ under NH3-N2 atmosphere. Mechanical properties of sintered specimens were investigated from measurement of porosity, bulk density and three point bending test. nitration reaction extent was observed at the change of mass before and after reaction, and the microstructure and the change of $\alpha$-Si3N4 and $\beta$-Si3N4 were observed by XRD and SEM. In the current work, the results are as follows 1. When Fe2O3 added, the nitridation increased with the content of Fe2O3, and the bending strength was increased from 0.1 wt% to 0.3 wt%, and decreased to 0.5 wt%. 2. When Al2O3 added, the nitridation and the bending strength increased little by little with the content of Al2O3 3. The bending strength of the specimen added with Fe2O3 were higher than that with Al2O3. Because the specimens contained Fe2O3 had much more the whisker type crystal of Si3N4 contributing to strength than contained Al2O3.

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