• Title/Summary/Keyword: initial surface absorption

Search Result 80, Processing Time 0.03 seconds

A Study on the Photoisomerization of Fatty Acid and Polyamic Acid Mixture (지방산과 폴리아미드산 혼합물의 광이성질화 현상에 관한 연구)

  • 박근호;박태곤
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.8
    • /
    • pp.695-701
    • /
    • 2002
  • Maxwell displacement current (MDC) measuring technique has been applied on the study of monolayers of fatty acid and polyamic acid mixture. The displacement current was generated from monolayers on the water surface by monolayer compression and expansion. Displacement current was generated when the area per molecule was about 132 $^2$and 115 $^2$just before the initial rise of the surface pressure during the 1st and 2nd mixed monolayer compressions cycle, respectively. Maxwell displacement currents were investigated in connection with mixed monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. Ultra thin film of fatty acid and polyamic acid mixture was prepared on the hydrophilic quartz plate by Langmuir-Blodgett (LB) method. The precursor LB film was heated in a vacuum dry oven at 12$0^{\circ}C$ in order to convert it into the LB film of polyimide. The absorption spectra of LB films were also induced photoisomerization by UV and visible light irradiation.

A Study on the Photoisomerization of Functional Polyimide Monolayers (기능성 폴리이미드 단분자막의 광이성화 현상에 관한 연구)

  • 박근호;강동완;김성일;박태곤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.07a
    • /
    • pp.475-478
    • /
    • 2000
  • Maxwell displacement current(MDC) was generated when the area per molecule was about 140${\AA}$$^2$and 100${\AA}$$^2$. MDC were investigated in connection with monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. The absorption spectra of polyamic acid containing p-methoxyazobenzene in a mixture of N,N-dimethylacetamide(DMAc) and benzene(1:1 by volume) solution was induced photoisomerization by UV and visible light irradiation. The precursor LB film was heated in a vacuum dry oven at 120$^{\circ}C$ in order to convert it into the LB film of polyimide. The absorption spectra of LB films were also induced photoisomerization by UV and visible light irradiation.

  • PDF

A Study on the Surface Characteristics of Phenolic Resin by Water Treatment (수처리에 의한 페놀수지의 표면특성에 관한 연구)

  • Choi, Chung-Seog;Shong, Kil-Mok;Kim, Hyung-Rae;Kim, Dong-Woo;Kim, Hyang-Kon;Kim, Dong-Ook
    • Proceedings of the KIEE Conference
    • /
    • 2002.07c
    • /
    • pp.1431-1433
    • /
    • 2002
  • In this paper, we studied the characteristics of surface structure of phenolic resin by water treatment. Phenolic resin which is used as indoor insulators is easily deteriorated by humidity. Water treated sample for 200 hours is subjected to the penetration of water and cracked partially. Water treated sample for 400 hours is found more cracks than that for 200 hours. The initial leakage current of virgin sample is 0.11A, that of water treated sample for 200 hours is 0.07A, and that of water treated sample for 400 hours is 0.05A. FT-IR analysis indicates that absorption peak of carbonyl group appears in virgin sample, but the absorption peak does not appear in water treated sample for 200 hours.

  • PDF

Total Phosphorus Removal in Cattail Wetland Purifying Effluent from a Night Soil Treatment Plant during Its Initial Operation (분뇨처리장 방류수를 정화하는 부들습지의 초기운영 단계에서 총인의 제거)

  • Yang, Hongmo
    • Journal of the Korean Society of Environmental Restoration Technology
    • /
    • v.8 no.1
    • /
    • pp.45-51
    • /
    • 2005
  • Total phosphorus(TP) removal was examined in a surface-flow wetland constructed in April 2003 during its initial operating stage from June to November 2003. Its dimensions were 87mL by 14mW. It was a part of a four-wetland-cell treatment system constructed near the Kohung Estuarine Lake located in the southern part of Korea. Effluent from a night soil treatment plant was discharged into the wetland and purified effluent from the wetland was discharged into Sinyang Stream flowing into the Lake. Cattails(Typha angustifolia ) from natural wetlands were cut at about 40 cm height and transplanted into the wetland. An average of 25.0$m^3$/day of effluent flowed from the plant into the wetland. Water depth was maintained about 0.2m and hydraulic detention time was about 5.2 days. Average heights of the cattail stems in June and October 2003 were 47.2 and 164.6cm, respectively. The average number of stems was 10.2 stems/$m^2$ in June 2003 and 18.8 stems/$m^2$ in October 2003. Average temperature of influent and effluent ranged 23.4 and $24.2^{\circ}C$, respectively. The average TP concentrations of influent and effluent were about 1.31, 0.50mg/L, respectively. TP loading rate of influent into the wetland averaged 26.81mg/$m^2$, day and average TP loading rate of effluent was 10.04mg/$m^2$, day. Monthly average TP removal by the wetland during the warm growing season of cattails(June to September) ranged 16.28~19.57mg/$m^2$, day and during the cold senescent period (October to November) ranged 12.62~13.90mg/$m^2$, day. TP removal in the wetland continued during the cold winter months and was primarily done by sedimentation and precipitation of phosphorus rather than phosphorus absorption by cattails and microorganisms.

Optimization and investigations of low-velocity bending impact of thin-walled beams

  • Hossein Taghipoor;Mahdi Sefidi
    • Steel and Composite Structures
    • /
    • v.50 no.2
    • /
    • pp.159-181
    • /
    • 2024
  • In the present study, the effect of geometrical parameters of two different types of aluminum thin-walled structures on energy absorption under three-bending impact loading has been investigated experimentally and numerically. To evaluate the effect of parameters on the specific energy absorption (SEA), initial peak crushing force (IPCF), and the maximum crushing distance (δ), a design of experiment technique (DOE) with response surface method (RSM) was applied. Four different thin-walled structures have been tested under the low-velocity impact, and then they have simulated by ABAQUS software. An acceptable consistency between the numerical and experimental results was obtained. In this study, statistical analysis has been performed on various parameters of three different types of tubes. In the first and the second statistical analysis, the dimensional parameters of the cross-section, the number of holes, and the dimensional parameter of holes were considered as the design variables. The diameter reduction rate and the number of sections with different diameters are related to the third statistical analysis. All design points of the statistical method have been simulated by the finite element package, ABAQUS/Explicit. The final result shows that the height and thickness of tubes were more effective than other geometrical parameters, and despite the fact that the deformations of the cylindrical tubes were around forty percent greater than the rectangular tubes, the top desirability was relevant to the cylindrical tubes with reduced cross-sections.

NUMERICAL SIMULATION OF TWO-DIMENSIONAL FREE-SURFACE FLOW AND WAVE TRANSFORMATION OVER CONSTANT-SLOPE BOTTOM TOPOGRAPHY

  • DIMAKOPOULOS AGGELOS S;DIMAS ATHANASSIOS A
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2005.09b
    • /
    • pp.842-845
    • /
    • 2005
  • A method for the numerical simulation of two-dimensional free-surface flow resulting from the propagation of regular gravity waves over topography with arbitrary bottom shape is presented. The method is based on the numerical solution of the Euler equations subject to the fully nonlinear free-surface boundary conditions and the appropriate bottom, inflow and outflow conditions using a hybrid finite-differences and spectral-method scheme. The formulation includes a boundary-fitted transformation, and is suitable for extension to incorporate large-eddy simulation (LES) and large-wave simulation (LWS) terms for turbulence and breaking wave modeling, respectively. Results are presented for the simulation of the free-surface flow over two different bottom topographies, with constant slope values of 1:10 and 1:20, two different inflow wave lengths and two different inflow wave heights. An absorption outflow zone is utilized and the results indicate minimum wave reflection from the outflow boundary. Over the bottom slope, lengths of waves in the linear regime are modified according to linear theory dispersion, while wave heights remain more or less unchanged. For waves in the nonlinear regime, wave lengths are becoming shorter, while the free surface elevation deviates from its initial sinusoidal shape.

  • PDF

Optimization of Maillard Reaction in Model System of Glucosamine and Cysteine Using Response Surface Methodology

  • Arachchi, Shanika Jeewantha Thewarapperuma;Kim, Ye-Joo;Kim, Dae-Wook;Oh, Sang-Chul;Lee, Yang-Bong
    • Preventive Nutrition and Food Science
    • /
    • v.22 no.1
    • /
    • pp.37-44
    • /
    • 2017
  • Sulfur-containing amino acids play important roles in good flavor generation in Maillard reaction of non-enzymatic browning, so aqueous model systems of glucosamine and cysteine were studied to investigate the effects of reaction temperature, initial pH, reaction time, and concentration ratio of glucosamine and cysteine. Response surface methodology was applied to optimize the independent reaction parameters of cysteine and glucosamine in Maillard reaction. Box-Behnken factorial design was used with 30 runs of 16 factorial levels, 8 axial levels and 6 central levels. The degree of Maillard reaction was determined by reading absorption at 425 nm in a spectrophotometer and Hunter's L, a, and b values. ${\Delta}E$ was consequently set as the fifth response factor. In the statistical analyses, determination coefficients ($R^2$) for their absorbance, Hunter's L, a, b values, and ${\Delta}E$ were 0.94, 0.79, 0.73, 0.96, and 0.79, respectively, showing that the absorbance and Hunter's b value were good dependent variables for this model system. The optimum processing parameters were determined to yield glucosamine-cysteine Maillard reaction product with higher absorbance and higher colour change. The optimum estimated absorbance was achieved at the condition of initial pH 8.0, $111^{\circ}C$ reaction temperature, 2.47 h reaction time, and 1.30 concentration ratio. The optimum condition for colour change measured by Hunter's b value was 2.41 h reaction time, $114^{\circ}C$ reaction temperature, initial pH 8.3, and 1.26 concentration ratio. These results can provide the basic information for Maillard reaction of aqueous model system between glucosamine and cysteine.

Formulation of Erythromycin Enteric-coated Pellets (에리스로마이신 장용성 펠렛의 제제 설계)

  • 이승우;박은석;지상철
    • YAKHAK HOEJI
    • /
    • v.39 no.6
    • /
    • pp.593-599
    • /
    • 1995
  • Erythromycin was formulated as enteric-coated pellets in order to reduce degradation in stomach and gastromtestmal irritation, and to maximize the absorption in intestine followmg its oral administration. Core pellets were prepared using fluid-bed granulator with two different methods (powder layering and solvent spraying) and enteric-coated with two different coating polymers (HPMCP and Eudragit E30D). Physical characteristics md dissolution rates of core pellets and enteric-coated pellets were evaluated to optimize the formulation. Powder layering method resulted in shorter initial dissolution time than solvent spraying method, but physicochmical properties of the product were worse than solvent spraying method with respect to hardness, ftiability and density. The dissolution rate of the drug was increased with the addition of surfactants, showing concentration-dependence. The scanning electron microscopic observation of pellets revealed significant differences on the surface appearances prepared with solvent spraying method. The core pellet made with powder layering method had crystals on the surface, which resulted in poor physical properties of the pellets. The dissolution profiles of erythromycin pellets coated with HPMCP or Eudragit L30D were close to that of commercially available erythromycin enteric-coated product.

  • PDF

Experimental Study on Watertightness Properties of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 사용한 콘크리트의 수밀특성에 관한 실험적 연구)

  • Joung, Won-Seoup;Park, Dong-Su;Kwon, Ki-Joo;Kim, Joung-Woo;Kim, Do-Soo
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.04a
    • /
    • pp.429-432
    • /
    • 2008
  • Large area members such as foundation concrete of underground structures in power plants have an effect on structural stability and durability of the structure due to danger of crack occurrence and shrinkage crack that occur owing to the difference of temperature by heat of hydration between inside and outside of the members at initial age. And a construction for waterproofness is performed additionally to protect marine structures from osmosis of seawater because the structures adjoin below the surface of sea. So, if a rise of the heat of hydration, crack, and corrosion of bars are controled effectively using a composite such as fluosilicate salt in concrete production process of a initial construction, expenses are cut down and construction hours are reduced by securing durability through improvement of watertightness. The property tests of adiabatic temperature by hydration are carried out at initial age about standard concrete and test concrete using a fluosilicate salt composite to evaluate an effect on improvement of watertightness for concrete structures in this study. And the experiments such as a permeability test of hardened concrete, a water absorption test, a compression strength test and a elongation test are carried out and the results from these are described.

  • PDF

AN EXPERIMENTAL STUDY ON THE INITIAL AMALGAM CORROSION IN ARTIFICIAL SALIVA (인공타액에서 아말감 초기부식에 대한 실험적 연구)

  • Kim, Mi-Ja;Lee, Myung-Jong
    • Restorative Dentistry and Endodontics
    • /
    • v.17 no.2
    • /
    • pp.287-306
    • /
    • 1992
  • The amounts of copper, mercury, silver, tin, and zinc released from conventional, dispersed phase and spherical high copper content amalgam immersed in artificial saliva soln. for periods of 2 hours, 1 day, 7 days, 30 days has been measured using Neutron Activation analysis and Atomic Absorption Spectrophotometry. The second electron image and EDX of the surface of samples immersed in artificial saliva were observed using SEM. The following results were obtained. 1. The dispersed non-$\gamma_2$ amalgam released more Hg, Ag than the $\gamma_2$-amalgams. Later a decrease of the release rate could be observed. 2. The dispersed high copper amalgam released more copper than low-copper amalgam and the release rate was decreased with time. But the amounts of copper released from Tytin increased with time. 3. Zinc was released all the experiment time. 4. EDAX showed that surface was composed of Ca,P, Sn, Ag, Zn, and Cu, but C1 was not detected. 5. The discontinued destructed surface was observed from the polished amalgam surface. High copper amalgam was destructed more than low copper amalgam.

  • PDF