• Title/Summary/Keyword: industrial wastes

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Environmentally Adaptive Stabilization of the Hazardous Heavy Metal Waste by Cementious Materials(I) (산업폐기물 중의 유해중금속의 환경친화적 안정화 처리(I))

  • 원종한;안태호;최광휘;최상흘;손진군;심광보
    • Journal of the Korean Ceramic Society
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    • v.39 no.7
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    • pp.680-686
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    • 2002
  • The solidification/stabilization mechanism of each cementious material was investigated. It was found that when $C_3$S was hydrated , the Pb element could be transferred to the insoluble Ca[Pb(OH)$_3$.$H_2O$]$_2$and the Cr element to the CaCr $O_4$$H_2O$. The addition of heavy metal tends to delay the hydration until initial 7 days. The Pb element as also delayed the hydration and the Cr element was substituted for the ettringite. On the occasion of the hydration of $C_4$ $A_3$ $S^{S}$, the Pb and Cr ions were solidified/stabilized by the substitution into the ettringite and/or monosulfate. Leaching of the Pb, Cr and Zn elements in the solidified material was extremely little, indicating that heavy metals were effectively solidified/stabilized in the hydrated cementious materials. Solidification/stabilization of heavy metal ions in the industrial wastes such as the STS, BF and COREX sludge was investigated. In case of the mixing ratio of cement and slag was 3 : 7, leaching of hazardous heavy metal ions was very little, indications that the solidification and stabilization was very successful.l.

On Preparation and Effects of Composts from Industrial Wastes via High Temperature and Aerobic conditions (유기성 산업폐기물의 고온·호기성 퇴비화 및 비효평가)

  • Kweon, Jin-Wook;Lee, Kyu-Seung;Park, Seung-Heui
    • Korean Journal of Agricultural Science
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    • v.22 no.2
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    • pp.143-150
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    • 1995
  • In order to find a way to utilize paper mill sludge, its composting was conducted with anaerobic waste of kraft paper sludge, raw kraft paper sludge, and CMC sludge(CMC : Sodium Carboxymethylcellulose) under aerobic condition at $50^{\circ}C$. It took 3 days for initial fermentation with anaerobic waste and CMC sludge, and six days with raw kraft paper sludge. Each compost was applied to radish(Rhaphanus Stativus L.), and absorption rate of staple nutrients increased 6.7~9.3 times higher in N, 17~21 times in P and 2~3 times in K than control at the harvesting stage. Also, organic matter contents were increased 1.5~2.3 times 4.5~5.3 times in CEC compared to control soil.

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Levels of Persistent Organic Pollutants in Waste Paper and Waste Lumber and Evaluation of their Sources (폐지와 폐목재에서의 잔류성 유기오염물질의 농도 및 배출원 추정)

  • Hwang, In-Kyu;Lee, In-Seok;Oh, Kwang-Joong;Kim, Ji-Won;Park, Hung-Suck;Oh, Jeong-Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.870-878
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    • 2010
  • We investigated the concentration and the sources of ubiquitous persistent organic pollutants [i.e., 17 toxic polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), 12 coplanar polychlorinated biphenyls (Co-PCBs), and 16 priority polycyclic aromatic hydrocarbons (PAHs)] in waste papers and lumbers from industrial complexes. The total concentrations in waste papers and lumbers ranged from 9.69~176.77 pg/g-dry and 0.14~0.25 pg/g-dry for 17 PCDD/Fs, 109.95~4097.25 pg/g-dry and 28.23~59.88 pg/g-dry for 12 Co-PCBs and 9.30~52.18 ng/g-dry and 0.82~1.82 ng/g-dry for 16 PAHs respectively. Generally, the concentration of these pollutants in waste papers was higher than those in waste lumbers. OCDD was dominant in waste papers and lumbers and the PCDD/F patterns of these samples were similar with that of stack gas. The distribution patterns of Co-PCBs in wastes were related with commercial PCB products, indicating the effect of commercial PCB products on ubiquitous environment. The diagnostic ratios of several PAH compounds in waste paper showed that they were related with pyrogenic sources.

Acute Toxicity of Oncheon Stream Water to the Sea Urchin, Hemicentrotus pulcherrimus (말똥성게에 대한 온천천수의 급성독성)

  • LEE Suk-MO;PARK Chung-Kil
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.5
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    • pp.414-422
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    • 1984
  • This research was conducted to evaluate the effect of polluted Oncheon Stream on the marine organisms in the Suyeong Bay. Water quality and 96 hr acute toxicity to the sea urchin, Hemicentrotns pulcherrimus by recirculation bioassay were examined from Feb. 20 to Apr. 15, 1984. The 96 hr $50\%$ effective concentration($EC_{50}$) on the attachment of the podia of the sea urchin was observed to occur at test concentrations between 40.0 and $51.0\%$ (v/v), and safe concentrations may be assumed to be within 4.0 and $5.1\%$. These values indicate as follows : 1. Oncheon Stream was extremely polluted by oxygen-demanding wastes and synthetic organic compounds from sewage and industrial waste water. 2. Linear alkylbenzene sulfonate(LAS) which has not been yet included in water quality standard was discharged above the TLm. 3. Unknown toxicity may be synergy among complex substances. In consideration of the relationship between COD values of Oncheon Stream and dilution water, the effect of toxicity of Oncheon Stream water reached to the area of the Suyeong Bay where the COD value was found to be 12.2 ppm.

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A Study on Profitability of Power Plant for Landfill Gas (매립가스 자원화를 위한 가스엔진 발전의 수익성에 관한 연구)

  • Kim, Oh-Woo;Lee, Jeong-Il
    • Korean Business Review
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    • v.19 no.2
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    • pp.69-94
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    • 2006
  • Landfill gas is a mixture of methane and carbon dioxide produced by the bacterial decomposition of organic wastes, and it is considered to produce bad smells and pollute the environment. Economic trials and the developments of landfill gas, as an alternative energy resource, become known at the recent years. Resource development of landfill gas, which is managed by Korea up to now, is for the most part generation using gas engine. Medium BTU and High BTU are considered for the power generation as well. I\10st income of generation using gas engine is selling charge through a power plant. Expecting to manage the power plant for up to 10 years, the analysis based on revenue and expenditure shows when the unit price is 65.2 Won and the operating rate reaches 90%, it is possible to be into the black in 2012 without considering additional financial expense. It was also analyzed that the profit at a unit price of 85 Won under the anticipated rising unit price by the operating rate of 71% is larger than at the operating rate of 90% under limited unit price of 65.2 Won. It means to manage the power plant at a unit price of 65.2 Won and the operating rate must be higher than 90% for economic logicality. If we assume that the operating rate is 90% and it increases the unit price, the unit price must be higher than 85 Won for the management of a power plant. Analysis of changing a unit price, however, might be expected to have a gradual rise of prices. If there is no price rising and additional income related to CDM(Clean Development Mechanism) and emission trading upon Kyoto protocol, the management of a power plant using gas engine will get financial difficulties because of many operating expenses. However, since landfill gas is considered as a worthy energy resource for the guarantee of sustainable development and for the equity between recent generation and future generation, the development of it must be accomplished by the government's additional supporting and efforts under the interest of all stakeholder who are involved.

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Study on the Correlation between Air Emission Gas and Alternative Fuels Used in Cement Sintering Process (시멘트 소성공정에 사용된 대체연료와 대기배출가스간 상관관계 연구)

  • Choi, Jaewon;Baek, Ju-Ik;Kwon, Sang-Jin;Won, Pil-Sung;Kang, Bong-Hee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.286-293
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    • 2020
  • In this study, we tried to verify the correlation of the amount of combustible industrial by-products, household waste used as fuels on cement sintering process and the amount of NOx, and CO, harmful components in the exhaust gas. The analysis uses coal as natural fuel, soft plastics (plastics with properties that tend to be scattered by wind, such as vinyls), hard plastics (plastics with properties that are not scattered by wind, such as PETs, wate rubbers), and reclaimed oils as alternative fuels. Utilizing the response surface analysis (RSM) technique using the process data of 2019, such as the fuel input and combustion temperature of a domestic A cement manufacturer's sintering facilities as independent variables, and the NOx, and CO emissions to the stack as dependent variables. Correlation was analyzed. As a result, it was confirmed that the impact on the emission material differs for each waste. In particular, it was analyzed that the hard plastics increase the CO emission but have an excellent effect of reducing NOx.

Developing Aged-Housing Remodeling Technology for Improving Structural and Equipment performance;Introduction of Center for Aged-housing Remodeling Technology (노후 공동주택 구조 및 설비성능개선 기술 개발;2차년도 실적 및 차년도 연구계획 소개)

  • Han, Ju-Yeoun;Kim, Kyung-Rai
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2007.11a
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    • pp.190-196
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    • 2007
  • As the number of aged-housing has been rapidly increased, many kinds of defects and problems such as degeneration of housing environment, structural performance, and equipment performance have been appeared. The reconstruction as the way to improve the aged-housing has been used mostly because the legal process of the reconstruction is relatively easy. On the other hand, it has caused problems such as the lack of natural aggregates, the environmental damages owing to construction wastes, the loss of national resources, and the lack of the housing for rent nearby the reconstruction area. This problems limit active tying into the reconstruction business at present in the industrial and political perspective. In this context, it is necessary to revitalize the remodeling rather than the reconstruction. In order to reach this objective, this research aims at identifying the user-oriented performance for the housing and deducing the core technology. It is expected that the result of this research can contribute to more revitalize the remodeling as tying researches in terms of design, structure, equipment, and construction.

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Preparation of KCl through Removal of Heavy Metals from Chlorine By-Pass Dust (염소 바이패스 더스트를 이용한 염화칼륨 제조 및 중금속 제거)

  • Yun, Youngmin;Yeom, Nari;Lee, Kabsoo;Eom, Seonhui;Lee, Yonghyun;Chu, Yongsik
    • Resources Recycling
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    • v.26 no.2
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    • pp.11-17
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    • 2017
  • Many problems are occurred by using industrial by-product and municipal solid waste in the cement manufacturing process. The main components of chlorine by-pass dust generated by the use of the wastes are $K^+$, $Cl^-$, and a slight amount of heavy metals is also contained. In terms of waste recycling, it is necessary to eliminate the heavy metals. Therefore, in this study, the experiments for the removal of heavy metals from KCl which was produced by chlorine by-pass dust were conducted. In order to find optimum conditions for the removal of heavy metals, we have controlled the amount of water and precipitator. The type and concentration of heavy metals in KCl were analyzed. The concentration of heavy metals decreased as amount of precipitator increased. The heavy metals such as Pb, Cd, and As were not detected in dust A and B, when the mixing ratios between dust A(B) and water were controlled to be 1:2 (1:2, 1:3.5) with the addition of 3% precipitator (NaOCl).

A Sustainable and Viable Method to Recycle Oyster Shell Waste as an Alternative of Limestone in Limestone Calcined Clay Cement (LC3) (석회석 소성 점토 시멘트(LC3) 내 석회석 대체재로서 굴 패각의 친환경적인 재활용 방안)

  • Her, Sung-Wun;Suh, Heong-Won;Park, Jae-Yeon;Im, Su-Min;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.219-226
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    • 2020
  • Over the last decades, great efforts have been devoted to reuse industrial wastes and by-products from various industries as supplementary cementitious materials in order to reduce carbon dioxide(CO2) emission by reducing the use of Portland cement in construction. Oyster shell waste, originating from the fishery industry, is available in huge quantities in certain areas, and is generally discarded or landfilled. In this study, we aimed to reuse oyster shell as an alternative to limestone in limestone calcined clay cement(LC3). The oyster shell calcined clay cement(OC3) paste were produced and were characterized via X-ray diffraction, isothermal calorimetry, compressive strength tests, and thermogravimetry. The results revealed that OC3 pastes exhibited similar strength development and reactivities by pozzolanic reaction with LC3, which implies that oyster shell could be used as a substitute for limestone in LC3.

Trend on the Recycling Technologies for Waste Magnesium by the Patent and Paper Analysis (특허(特許)와 논문(論文)으로 본 폐(廢)마그네슘 재활용(再活用) 기술(技術) 동향(動向))

  • Moon, Byoung-Gi;You, Bong-Sun;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.22 no.3
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    • pp.73-80
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    • 2013
  • Metal prices are rapidly rising due to increasing demand of metals and limited available resources according to the industrial requirement. As a result, securing a stable supply of these metal resources has been recognized as a core element of national competitiveness and sustained economic growth. In the case of magnesium and its alloys which are entirely depending on import, low-grade magnesium scraps from end-of-life vehicles and 3C(Camera, Computer, Communication) parts and magnesium wastes such as sludge and dross generated during melting process are hardly recycled. Accordingly, the development and commercialization of recycling technology of low-grade magnesium scrap is desperately needed to improve efficiency of resource circulation and to establish the required proprietary of resource metal supply and demand. In this study, papers and patents on recycling technologies of waste magnesium were analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1974 to 2012. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals was analyzed by the years, countries, companies, and technologies.