• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.665-675
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• 2007

In-situ Air Sparging (IAS, AS) is a remediation technique in which organic contaminants are volatilized from saturated zone to unsaturated layer. This study focuses on the removal and interaction of Volatile Organic Compounds (VOCs) and $CO_2$, and Total Petroleum Hydrocarbon (TPH) in saturated and unsaturated, and air space zone on the unsaturated soil surface. Soil sparging temperature of hot air has risen to $34.9{\pm}2.7^{\circ}C$ from $23.0{\pm}1.9^{\circ}C$ for 36 days. At the diffusing point, fluid TPH concentrations were reduced to 78.7% of the initial concentration in saturated zone when hot air was sparged. The TPH concentrations were decreased to 66.1% for room temperature air sparging. The amount of VOCs for hot air sparging system, in air space, was approximately 26% larger than constant air sparging system. The amount of $CO_2$ was 4,555 mg (in unsaturated zone) and 4,419 mg (in air space) when hot air was sparged was 3,015 mg (in unsaturated zone) and 3,634 mg (in air space) for room air temperature in the $CO_2$ amount. The removals of VOCs and biodegradable $CO_2$ through the hot air sparging system (modified SVE) were more effective than the room temperature air sparging. The regression equation were $Y=976.4e^{-0.015{\cdot}X}$, $R^2=0.98$ (hot air sparging) and $Y=1055e^{-0.028{\cdot}X}$, $R^2=0.90$ (room temperaure air sparging). Estimated remediation time was approximately 500 days, if final saturated soil TPH concentration was set to 1.2 mg/L application of tail effect.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.348-351
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• 2003

Trichloroethylene, which is one of the representative DNAPL, has been found in underground water sources as a result of the manufactural use, and disposal of the chemical. In this research, in situ air sparging method was chosen to reduce the TCE concentration from the source zone. The concentration reduction in the source zone resulting from air sparging is simulated using the modified STOMP Water-Air operational mode in a two dimensional axisymmetric domain and bench scale test is conducted to analyze the performance of air sparging. The results of laboratory tests are compared with numerical simulations.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.232-235
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• 1998

Air sparging system is a kind of in-situ bioremediation method in the contaminated ground water. When Air sparging, the both of water circulation and oxygen transfer happend in the same time. The hydraulic differential head is zero at the middle height of well, is negative below the height and is possitive above the height. Hydroraulic head gradient is proportioned to air superficial velocity in the well. But over 24m/min of the superficial velocity, the hydraulic head gradient increase little.

• Journal of Soil and Groundwater Environment
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• v.11 no.6
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• pp.8-17
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• 2006

Laboratory scale experiments were performed to investigate the removal efficiency of the in-situ chemical oxidation method and the air-sparging method for diesel contaminated soil and groundwater. Two kinds of diesel contaminated soils (TPH concentration : 2,401 mg/kg and 9,551 mg/kg) and groundwater sampled at Busan railroad station were used for the experiments. For batch experiments of chemical oxidation by using 50% hydrogen peroxide solution, TPH concentration of soil decreased to 18% and 15% of initial TPH concentration. For continuous column experiments, more than 70% of initial TPH in soil was removed by using soil flushing with 20% hydrogen peroxide solution, suggesting that most of diesel in soil reacted with hydrogen peroxide and degraded into $CO_2$ or $H_2O$ gases. Batch experiment for the air-sparging method with artificially contaminated groundwater (TPH concentration : 810 mg/L) was performed to evaluate the removal efficiency of the air-sparging method and TPH concentration of groundwater decreased to lower than 5 mg/L (waste water discharge tolerance limit) within 72 hours of air-sparging. For box experiment with diesel contaminated real soil and groundwater, the removal efficiency of air-sparging was very low because of the residual diesel phase existed in soil medium, suggesting that the air-sparging method should be applied to remediate groundwater after the free phase of diesel in soil medium was removed. For the last time, the in-situ box experiment for a unit process mixed the chemical oxidation process with the air-sparging process was performed to remove diesel from soil and groundwater at a time. Soil flushing with 20% hydrogen peroxide solution was applied to diesel contaminated soils in box, and subsequently contaminated groundwater was purified by the air-sparging method. With 23 L of 20% hydrogen peroxide solution and 2,160 L of air-sparging, TPH concentration of soil decreased from 9,551 mg/kg to 390 mg/kg and TPH concentration of groundwater reduced to lower than 5 mg/L. Results suggested that the combination process of the in-situ hydrogen peroxide flushing and the air-sparging has a great possibility to simultaneously remediate fuel contaminated soil and groundwater.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.11-24
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• 2003

This paper presents the results of laboratory investigation performed to study the role of different air sparging system parameters on the removal of benzene from saturated soils and groundwater. A series of one-dimensional experiments was conducted with predetermined contaminant concentrations and predetermined injected airflow rates and pressures to investigate the effect of soil type and the use of pulsed air injection on air sparging removal efficiency. On the basis of these studies, two-dimensional air sparging remediation systems were investigated to determine the effect of soil heterogeneity on the removal of benzene from three different homogeneous and heterogeneous soil profiles. This study demonstrated that the grain size of the soils affects the air sparging removal efficiency. Additionally, it was observed that pulsed air injection did not offer any appreciable enhancement to contaminant removal for the coarse sand; however, substantial reduction in system operating time was observed for fine sand. The 2-D experiments showed that air injected in coarse sand profiles traveled in channels within a parabolic zone. In well-graded sand the zone of influence was found to be wider due to high permeability and increased tortuosity of this soil type. The influence zone of heterogeneous soil (well-graded sand between coarse sand) showed the hybrid airflow patterns of the individual soil test. Overall, the mechanism of contaminant removal using air sparging from different soil conditions have been determined and discussed.

• Journal of Soil and Groundwater Environment
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• v.15 no.1
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• pp.1-8
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• 2010

Cometabolic air sparging (CAS) is a new and innovative technology that uses air sparging principles but attempts to optimize in situ contaminant degradation by adding a growth substrate to saturated zone. CAS relies on the degradation of the primary growth substrate and cometabolic substrate transformation in the saturated zone and in the vadose zone for volatilized contaminants. In this study, we have investigated to determine MTBE degradation pattern and microbial activity variation if using propane as a primary substrate at the condition of considering air injection rate and air injection pattern. Laboratory-scale two-dimentional aquifer physical model studies were used and the experimental results were represented that the optimal conditions were as air injection rate of 1,000 mL/min and pulsed air injection pattern (15 min on/off). Over 1,000 mL/min air injection rate and continuous air injection pattern was no affected to increase DO concentration. On the other hand, Injection of propane and propane-utilizing bacteria degraded MTBE partially. And also, injection of propane- and MTBE-utilizing bacteria effectively degraded MTBE and TBA production was observed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.213-217
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• 2004

Laboratory scale study for an area of influence and flowing aspect of groundwater saturated zone was conducted for three sediment grains. On the AMG(Average Modal diameter Grains) 0.34, 1.38, 3.89mm diameter samples, the affected area of the aquifer were 15.2, 37.0, 30.0%/m2 each. Air flow for AMG 0.34mm diameter grain size provides indication of pattern of channelized air flow in saturated zone and expansion state in above saturated zone. For AMG of 1.38, 3.89mm diameter grains, air flow are pervasive air flow, forming a symmetrical cone of influence around the injection point. And also AMG 1.38, 3.89mm diameter samples show onset of collapse and approach to steady state in above saturated zone, respectively. In this study, optimal sites for in situ air sparging, may be grain diameters between about AMC 1.5～2.5mm diameter.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.232-236
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• 2005

In-situ Air Sparging (IAS, AS) is a groundwater remediation technique, in which organic contaminants are volatilized into air as it rises from saturated to vadose soil zone. The purpose of this study was to investigate the effect of environmental conditions on the degradation of VOCs (Volatile Organic Compounds) and $CO_2$ in the unsaturated zone and TPH (Total Petroleum Hydrocarbons) in saturated zone of sandy loam. In the laboratory, diesel (10,000 mg TPH/kg)-contaminated saturated soil. After heating the soil for 36 days, the equilibrium temperature of soil reached to $34.9{\pm}2.7^{\circ}C$ and TPH concentration was reduced to 78.9% of the initial value, Volatilization loss of VOCs in TPH was about 2%, The reduction gradient of $CO_2$ concentration was 0.018/day in air space and 0.0007/day in unsaturated zone.

• Journal of Korean Society on Water Environment
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• v.22 no.4
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• pp.590-598
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• 2006

In-situ Air sparging (IAS) is a groundwater remediation technique, in which organic contaminants volatilize into air form the saturated to vadose zone. This study was carried out to evaluate the effect of sludge and soil microbial community structure on air sparging of Total Petroleum Hydrocarbons (TPH) contaminated groundwater soils. In the laboratory, diesel (10,000 mg TPH/kg) contaminated saturated soil. The Air was injected in intermittent (Q=1500 mL/min, 10 minute injection and 10 minute idle) modes. For Terminal-Restriction Fragment Length Polymorphism (T-RFLP) analysis of eubacterial communities in sludge of wastewater treatment plants and soil of experiment site, the 16S rDNA was amplified by Polymerase Chain Reaction (PCR) from the sludge and the soil. The obtained 16S rDNA fragments were digested with Msp I and separated by electrophoresis gel. We found various sequence types for experiment with sludge soil samples that were closely related to Agrococcus, Flavobacterium, Thermoanaerobacter, Flexibacter and Shewanella, etc, in the clone library. The results of the present study suggests that T-RFLP method may be applied as a useful tool for the monitoring in the TPH contaminated soil the fate of microorganisms in natural microbial community.

• Journal of Soil and Groundwater Environment
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• v.11 no.6
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• pp.18-27
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• 2006

Air Sparging (IAS, AS) is a ground-water remediation technique, in which organic contaminants are volatilized into air as they rise from saturated to vadose soil zone. This study was conducted to investigate the variation characteristics of TPH, VOCs and $CO_2$ for air sparging of diesel contaminated saturated soil. Initial TPH concentration was 10,000 mg/kg for saturated soil phase and 1,001 mg/L for soil aquifer phase. After 36 days of air sparging, the equilibrium temperature of 2-Dimension experiment system was $24.9{\pm}1.5^{\circ}C$. The saturated soil TPH concentration (in the C10 port close to air diffuser) was reduced to 66.0% of the initial value. The mass amount of $CO_2$ was 3,800 mg and 3,200 mg in air space (C70 port) and in unsaturated soil zone (C50 port), respectively. The VOCs production kinetic parameter was 0.164/day in the air space (C70 port) and 0.182/day in the unsaturated soils (C50 port).