• Title/Summary/Keyword: impedance-based method

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Development of shock wave induced microparticle acceleration system based on laser ablation and its application on drug delivery (충격파를 이용한 레이저 어블레이션 기반의 마이크로 입자 가속 시스템 개발 및 약물전달 응용)

  • Choi, Ji-Hee;Gojani, Ardian B.;Lee, Hyun-Hee;Yoh, Jai-Ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.36 no.6
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    • pp.587-593
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    • 2008
  • Transdermal and topical drug delivery with minimal tissue damage has been an area of vigorous research for years. Our research team has initiated the development of an effective method for delivering drug particles across the skin (transdermal) for systemic circulation, and to localized (topical) areas. The device consists of a laser ablation based micro-particle acceleration system that can be integrated with endoscopic surgical techniques. We have successfully delivered 3μm size cobalt particles into gelatin models that represent soft tissue with remarkable penetration depth.

Nonenzymatic Sensor Based on a Carbon Fiber Electrode Modified with Boron-Doped Diamond for Detection of Glucose (보론 도핑 다이아몬드로 표면처리된 탄소섬유 기반의 글루코스 검출용 비효소적 바이오센서)

  • Song, Min-Jung
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.606-610
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    • 2019
  • In this study, we demonstrated that the nonenzymatic glucose sensor based on the flexible carbon fiber bundle electrode with BDD nanocomposites (CF-BDD electrode). As a nano seeding method for the deposition of BDD on flexible carbon fiber, electrostatic self-assembly technique was employed. Surface morphology of BDD coated carbon fiber electrode was observed by scanning electron microscopy. And the electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. This CF-BDD electrode exhibited a large surface area, a direct electron transfer between the redox species and the electrode surface and a high catalytic activity, resulting in a wider linear range (3.75~50 mM), a faster response time (within 3 s) and a higher sensitivity (388.8 nA/mM) in comparison to a bare CF electrode. As a durable and flexible electrochemical sensing electrode, this brand new CF-BDD scheme has promising advantages on various electrochemical and wearable sensor applications.

Electrochemical Sensor for Non-Enzymatic Glucose Detection Based on Flexible CNT Fiber Electrode Dispersed with CuO Nanoparticles (산화구리 나노입자가 분산된 CNT fiber 유연 전극 기반의 글루코스 검출용 비효소적 전기화학센서)

  • Min-Jung Song
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.52-57
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    • 2023
  • This study is a basic research for the development of high performance flexible electrode material. To enhance its electrochemical property, CuO nanoparticles (CuO NPs) were introduced and dispersed on surface of CNT fiber through electrochemical deposition method. The CNT fiber/CuO NPs electrode was fabricated and applied to electrochemical non-enzymatic glucose sensor. Surface morphology and elemental composition of the CNT fiber/CuO NPs electrode was characterized by scanning electron microscope (SEM) with energy dispersive X-ray spectrometry (EDS). And its electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fiber/CuO NPs electrode exhibited the good sensing performance for glucose detection such as high sensitivity, wide linear range, low detection limit and good selectivity due to synergetic effect of CNT fiber and CuO NPs. Based on the unique property of CNT fiber, CuO NPs were provide large surface area, enhanced electrocatalytic activity, efficient electron transport property. Therefore, it is expected to develop high performance flexible electrode materials using various nanomaterials.

Corrosion Protection Properties of Co3O4 and CoFe2O4 Nanoparticles for Water-Based Epoxy Coatings on 2024-T3 Aluminum Alloys

  • Thu Thuy Thai;Anh Truc Trinh;Thi Thanh Tam Pham;Hoan Nguyen Xuan
    • Corrosion Science and Technology
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    • v.22 no.2
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    • pp.90-98
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    • 2023
  • In this study, cobalt oxide (Co3O4) and cobalt-doped magnetite (CoFe2O4) nanoparticles were synthesized by a hydrothermal method. They were then used as corrosion inhibitors for corrosion protection of AA2024-T3 aluminum alloys. These obtained nanoparticles were characterized by x-ray diffraction, field-emission scanning electron microscopy, and Zeta potential measurements. Corrosion inhibition activities of Co3O4 and CoFe2O4 nanoparticles were determined by performing electrochemical measurements for bare AA2024-T3 aluminum alloys in 0.05 M NaCl + 0.1 M Na2SO4 solution containing Co3O4 or CoFe2O4 nanoparticles. Corrosion protection for AA2024-T3 aluminum alloys by a water-based epoxy with or without the synthesized Co3O4 or CoFe2O4 nanoparticles was investigated by electrochemical impedance spectroscopy during immersion in 0.1 M NaCl solution. The corrosion protection of epoxy coating deposited on the AA2024-T3 surface was improved by incorporating Co3O4 or CoFe2O4 nanoparticles in the coating. The corrosion protection performance of the epoxy coating containing CoFe2O4 was higher than that of the epoxy coating containing Co3O4.

Fabrication and characterization of a Flexible Polyethylene terephthalate (PET) Electrode based on Single-walled carbon nanotubes (SWNTs) (단일벽 탄소나노튜브를 이용한 플렉시블 폴리에틸렌테레프탈레이트 (PET) 전극의 제조와 특성)

  • Du, Jin Feng;Kim, Jang Hun;Kim, Yong Ryeol;Jeong, Hyeon Taek
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.587-592
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    • 2016
  • In this study, flexible acid treated single walled carbon nanotubes (A-SWCNTs) electrodes were fabricated by using gold coated PET substrate and spray coating technique. The acid-treatment method was conducted to introduce functional groups on the SWCNTs wall, which could improve dispersability of the SWCNTs and its electrochemical property. The electrochemical properties of flexible A-SWCNTs electrode were carried out by cyclic voltammetry(CV), electrochemical impedance were carried out by cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge (GCD) cycles. As a results, The specific capacitance value of the unbent A-SWCNTs electrode was $67F{\cdot}g^{-1}$, which decreased to $63F{\cdot}g^{-1}$ (94% retention) after 1000 GCD cycles. Interestingly, the specific capacitance of the unbent A-SWCNTs electrode with application of the 1000 GCD cycles was retained even after 500 bending to $30^{\circ}$ with 6000 GCD cycles.

Distributed Amplifier with Control of Stability Using Varactors (가변 커패시터를 이용하여 안정도를 조절할 수 있는 Distributed Amplifier)

  • Chu Kyong-Tae;Jeong Jin-Ho;Kwon Young-Woo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.16 no.5 s.96
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    • pp.482-487
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    • 2005
  • In this paper, we propose the control method of output impedance of each cascode unit cell of distributed amplifier by connecting varactors in the gate-terminal of common gate. Compared to common source unit cell, cascode unit cell has many advantages such as high gain and high output impedance as well as negative resistance loading. But if the transistor model which is used in design is inaccurate and process parameter is changed, oscillation sometimes can occur at band edge in which the gain start to drop. Therefore, we need control circuit which can prevent oscillation, although the circuit has already fabricated, and varactor connected to gate-terminal of common gate of cascode gain cell can play that part. Measured result of fabricated distributed amplifier shows the capability of contol of gain characteristic by adjusting of value of varactors, this can guarantee the stability of the circuit. The gain is $8.92\pm0.82dB$ over 49 GHz, the group delay is $\pm9.3 psec$ over 41 GHz. All transistor which has $0.15{\mu}m$ gate length is GaAs based p-HEMT, and distributed amplifier is put together with 4 stages.

Broadband Transmission Noise Reduction Performance of Smart Panels Featuring Piezoelectric Shunt Damping and Passive Characteristics (압전감쇠와 수동적 특성을 갖는 압전지능패널의 광대역 전달 소음저감성능)

  • 이중근;김재환
    • The Journal of the Acoustical Society of Korea
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    • v.21 no.2
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    • pp.150-159
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    • 2002
  • The possibility of a broadband noise reduction of piezoelectric smart panels is experimentally studied. Piezoelectric smart panel is basically a plate structure on which piezoelectric patch with shunt circuits is mounted and sound absorbing material is bonded on the surface of the structure. Sound absorbing materials can absorb the sound transmitted at mid frequency region effectively while the use of piezoelectric shunt damping can reduce the transmission at resonance frequencies of the panel structure. To be able to tune the piezoelectric shunt circuit, the measured electrical impedance model is adopted. Resonant shunt circuit composed of register and inductor in stories is considered and the circuit parameters are determined based on maximizing the dissipated energy through the circuit. The transmitted noise reduction performance of smart panels is investigated using an acoustic tunnel. The tunnel is a square crosses sectional tunnel and a loud speaker is mounted at one side of the tunnel as a sound source. Panels are mounted in the middle of the tunnel and the transmitted sound pressure across the panels is measured. Noise reduction performance of a double smart panel possessing absorbing material and air gap shows a good result at mid frequency region except the first resonance frequency. By enabling the piezoelectric shunt damping, noise reduction is achieved at the resonance frequency as well. Piezoelectric smart panels incorporating passive method and piezoelectric shunt damping are a promising technology for noise reduction in a broadband frequency.

Electrosorption Behavior of $TiO_2$/Activated Carbon Composite for Capacitive Deionization (축전식 이온제거에 대한 $TiO_2$/Activated Carbon 화합물의 전기흡착 거동)

  • Lee, Jeong-Won;Kim, Hong-Il;Kim, Han-Joo;Park, Soo-Gil
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.265-271
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    • 2010
  • Desalination effects of capacitive deionization (CDI) process was studied using $TiO_2$/activated carbon electrode. In order to enhance the wettability of electrode and decrease a electrode resistance, $TiO_2$ was coated on activated carbon. By means of $TiO_2$ coating on activated carbon, electric double layer to adsorption content in CDI process was increased. It was identified from TEM, XRD, and XPS that the activated carbon based on $TiO_2$ composite was fabricated successfully by means of sol-gel method. As a results of cyclic voltammetry and impedance, it was identified that $TiO_2$/activated carbon electrode has more electric double later capacitance and less diffusion resistance than activated carbon. Also charge-discharge and ion conductivity profiles showed that the ion removal ratios of $TiO_2$/activated carbon electrode in NaCl electrolyte of $1000\;{\mu}S/cm$ more increased about 39% than that of activated carbon. In conclusion it was possible to identify that the carbon electrode coated $TiO_2$ as electrode material was more effective than raw carbon electrode.

Correction of the Sea Effect in the Magnetotelluric (MT) Data Using an Iterative Tensor Stripping During Inversion (MT 자료 역산과정에서 반복적인 Tensor Stripping을 통한 해양효과 보정)

  • Yang, Jun-Mo;Lee, Chun-Ki;Yoo, Hai-Soo
    • Geophysics and Geophysical Exploration
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    • v.11 no.4
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    • pp.286-301
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    • 2008
  • When magnetotelluric (MT) data are obtained in vicinity of the coast, the sea can distort observed MT responses, especially those of deep part of subsurface. We introduce an iterative method to correct the sea effect, based on the previous topographic correction method which removes the distortions due to topographic changes in seafloor MT data. The method first corrects the sea effect in observed MT impedance, and then inverts corrected responses in a model space without the sea. Due to mutual coupling between sea and subsurface structure, the correction and inversion steps are iterated until changes in each result become negligible. The method is validated for 1-D and 2-D structure using synthetic MT data produced by 3-D forward modeling including surrounding seas. In all cases, the method closely recovers the given structure after a few iterations. To test the applicability of the proposed method to field data, we generate synthetic MT data for the Jeju Island whose 1-D conductivity structure is well known, using 3-D forward modeling. The distortions due to the surrounding sea start to appear below the frequency about 1 Hz, and are relatively severe in the electrical field perpendicular to the coastline because of the location of the observation sites. The proposed method successfully eliminates the sea effect after three iterations, and both 1-D and 2-D inversion of corrected responses closely recover the given subsurface structure of the Jeju Island model.

Comparison Analysis of Soil Structure Methods for Deciding the Position of a Deeply Driven Ground Rod (심매설 접지봉의 위치결정을 위한 대지구조 분석 방법들의 비교분석)

  • Eom, Ju-Hong;Cho, Sung-Chul;Lee, Tae-Hyung;Lee, Bok-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.7
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    • pp.37-45
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    • 2007
  • Recently, there has been an increase of the use of ground system for lightning protection called deeply driven grounding electrode. In the case of deeply driven grounding electrode, the rod electrode is equipped perpendicularly and deeply, therefore, it has a benefit to have less restriction of place compared to mesh grid electrode. However, ground impedance is largely changed by the local earth resistivity, so it requires a detailed analysis of the ground structure when planning. The measurement of earth resistivity by existing Wenner's method has been widely used, however, this method can not find out a change in the local ground resistance and it shows the result outwardly to be difficult to estimate exact depth. Therefore, this study analyzed the ground structure as 2-D image using 96 channels measurement facility and tried to analyze change in the local ground resistance and depth of the ground in order to design a deeply driven electrode effectively for lightning protection. It used Wenner alpha method dipole-dipole method and Schlumberger method for 2-D image analysis of the ground resistivity ma based on, it the result was compared with the ground structure analyzed with the result using the CDEGS and Wenner 1-D method.