• Korean Chemical Engineering Research
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• v.44 no.3
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• pp.243-247
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• 2006

MFI zeolite membranes were prepared on anodic alumina (Anodisc) as support. First, silicalite-1(${\approx}1.2{\mu}m$) seed crystals were attached to the surface of the support via chemical bonding, and the a- and b-axis oriented zeolite membranes could be synthesized on the support coated with the monolayer of the seed crystals by secondary growth hydrothermal synthesis. The zeolite membranes prepared were characterized using scanning electron microscope and analyzed by X-ray diffraction.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.421.2-421.2
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• 2014

We report on the growth of ZnO nanorods (NRs) grown on graphite and silicon substrates via an all-solution process and characteristics of their heterojunctions. Structural investigations indicated that morphological and crystalline properties were not significantly different for the ZnO NRs on both substrates. However, optical properties from photoluminescence spectra showed that the ZnO NRs on graphite substrate contained more point defects than that on Si substrate. The ZnO NRs on both substrates showed typical rectification properties exhibiting successful diode formation. The heterojunction between the ZnO NRs and the graphite substrate showed a Schottky diode characteristic and photoresponse under ultraviolet illumination at a small reverse bias of -0.1 V. The results showed that the graphite substrate could be a good candidate for a Schottky contact electrode as well as a conducting substrate for electronic and optoelectronic applications of ZnO NRs.

• Proceedings of the KIEE Conference
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• 1999.11d
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• pp.994-996
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• 1999

Hygrothermal aging at the elevated temperature induces the long-term degradation of the epoxy resin. We investigated the effects of hydrothermal stress on the dielectric breakdown phenomena of epoxy composite filled with natural zeolite. The cured specimens absorbed the moisture in the autoclave at $120^{\circ}C$. $T_g$ of the deteriorated composite by moisture absorption decreased. The dielectric breakdown strength decreased with the moisture absorption cycle. It was concluded that the thermal stress and the high water-vapour-pressure deteriorated the natural zeolite filled epoxy resin system, consequently and the tree growth rate increased.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.475-475
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• 2011

현재 수열합성법으로 이용하여 1차원으로 수직 성장한 ZnO 나노와이어는 밴드 갭이 3.37ev로 큰 밴드 갭을 갖는 물질이며 밀도 조절이 매우 어려운 것으로 알려져 있다. ZnO 나노와이어는 기존의 리소그래피 기반을 둔 Top-Down 방식과 달리 자발적인 형성과정으로 높은 결정성을 가지게 되는데, 이는 ZnO 나노와이어가 큰 종횡비 와 전자친화도를 가지고 있어 높은 전계방출 효과를 기대하게 되는 부분이다. 본 연구에서는 실버를 열처리하여 형성된 실버 나노파티클을 마스킹층으로 사용하여 ZnO 나노와어의 밀도 조절을 하고자 하였다. 실버막을 AZO seed layer 기판 위에 증착한뒤 $200{\sim}600^{\circ}C$ 까지 열처리 후 수열합성법을 이용하여 ZnO nanowire를 성장하였다. 또한 전구체인 ZN(NO3)2${\cdot}$6H2O 와 HMT 에 각각 Ammonium chloride와 PEI를 첨가하였고, PEI 의 몰농도를 변화하여 성장된 ZnO 나노와이어의 구조적, 광학적 특성을 평가함으로서 전자소자 적용 가능성을 확인하였다.

• Korean Journal of Crystallography
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• v.1 no.1
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• pp.8-13
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• 1990

Synthetic citrines were grown by hydrothermal method. For the establishment of grown conditions of large citrine, various types and/or amount of nutrients, seed orientations, mineralizers, colorants and temperature gradients were studied. For the evaluation of the quality of as grown citrine, color tone, crystal form, macro-and micro-defects were observed and crystal structure and absorption spectrums were analyzed. As a result, large sized citrines of 205mm L x 58mm W x 35mm T with excellent color tone and minium defects were grown.

• Proceedings of the Korean Magnestics Society Conference
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• 2000.09a
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• pp.433-440
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• 2000

Barium ferrite particles were synthesized from Ba(NO$_3$)$_2$, Fe(NO$_3$)$_3$ and KOH mixed solutions using hydrothermal crystallization in supercritical water. The experimental apparatus for production of barium ferrite is a flow-type apparatus. Fine barium ferrite particles were produced because supercritical water causes the metal hydroxides to be rapidly dehydrated before significant growth takes place. The effects of Fe/Ba ratio and reaction time on the formation, particle size, and magnetic properties of barium ferrite were studied. When Fe/Ba ratio were varied from 0.5 to 12, single-phase barium ferrite powder was only produced in the range of 0.5〈Fe/Ba〈2. Also, with elevating reaction time, the BaO.6Fe$_2$O$_3$ particle size grew smaller. Especially, uniform barium hexaferrite particles of size 100-200nm were obtained at 80sec. In this study, therefore, single-phase barium ferrite particles are highly stable and can be produced continuously in a reaction time of less then 2min.

• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.3977-3980
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• 2012

Nanostructured thermoelectric bismuth telluride ($Bi_2Te_3$) powders with various morphologies, such as nanoplates, nanorods, and nanotubes, were prepared by a hydrothermal method based on the reaction between $BiCl_3$, Te, and sodium ethylenediaminetetraacetate ($Na_2$-EDTA) at 150, 180, and $210^{\circ}C$. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), and selected area electron diffraction (SAED). The effect of reaction temperature on the morphology of the $Bi_2Te_3$ particles was investigated, and the possible mechanism of morphology control was proposed.

• The Korean Journal of Food And Nutrition
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• v.7 no.4
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• pp.259-266
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• 1994

The hyperthermophilic archaebacterium Thermococcus profundus Isolated from a deep-sea hydrothermal vent system, produced several amylolytic enzymes such as extracellular amylase and pullulanase, intracellular a-1,4-91ucosidase in respone to the presence of complex carbohydrates In the growth medium. This strain showed high activities on 0.5% maltose than on complex carbohydrates One of the amylases was partially purified by ammonium sulfate precipitation, DEAE-Toyopearl chromatography. The amylase exhibited maximal activity at pH 5.5 and 80$^{\circ}C$, and was stable in the range of pH 5.5 to 9.5 and up to 80$^{\circ}C$ for 30 min. The enzyme activity was no dependence on Ca2+ and not inhibited by detergents. The amylase hydrolyzed soluble starch, amylose, amylopectin and glycogen to produce maltose and maltotriose with trace amounts of glucose, but not pullulan and ${\alpha}$-, ${\beta}$-, ${\gamma}$-cyclodextrin. Malto-oligosaccharides ranging from maltotetraose to maltoheptaose were hydrolyzed in an endo fashion.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.1
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• pp.97-101
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• 2016

ZnO has nanostructured material because of unique properties suitable for various applications. Amongst all chemical and physics methods of synthesis of ZnO nanostructure, the hydrothermal method is attractive for its simplicity and environment friendly condition. Nanostructure ZnO thin films have been successfully synthesized on fluorine doped tin oxide (FTO) substrate using hydrothermal method. A possible growth mechanism of the various nanostructures ZnO is discussed in schematics. The prepared materials were characterized by standard analytical techniques, i.e., X-ray diffraction (XRD) and Field-emission scanning electron microscopy (SEM). The XRD study showed that the obtained ZnO nanostructure thin films are in crystalline nature with hexagonal wurtzite phase. The SEM image shows substrate surface covered with nanostructure ZnO nanrod. The UV-vis absorption spectrum of the synthesized nanostructure ZnO shows a strong excitonic absorption band at 365 nm which indicate formation nanostructure ZnO thin film. Photoluminescence spectra illustrated two emission peaks, with the first one at 424 nm due to the band edge emission of ZnO and the second broad peak centered around 500 nm possibly due to oxygen vacancies in nanostructure ZnO. The Raman measurements peaks observed at $325cm^{-1}$, $418cm^{-1}$, $518cm^{-1}$ and $584cm^{-1}$ indicated that nanostrusture ZnO thin film is high crystalline quality. We trust that nanostructure ZnO material can be effectively will be used as a highly active and stable phtocatalysis application.

• Membrane Journal
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• v.17 no.3
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• pp.254-268
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• 2007

Sodium type faujasite(FAU) zeolite layers with diverse materials characteristics(Si/Al ratio, thickness, and structural discontinuity) were hydrothermally grown on a porous $\alpha-Al_2O_3$ tube, and then the $CO_2/N_2$ separation was evaluated at $30^{\circ}C$ for an equimolar mixture of $CO_2$ and $N_2$. Among hydrothermal conditions, $SiO_2$ content in hydrothermal solution seriously affected materials characteristics: with an increment in the $SiO_2$ content, Si/Al ratio, thickness, and structural discontinuity of grown FAU zeolite layer simultaneously increased. The present study reveals that structural discontinuity(intercrystalline voids due to an incomplete densification and cracks induced by GIS Na-P1 phase) is the most important variable affecting the $CO_2/N_2$ separation. Also, it was suggested that the $CO_2$ desorption in permeate side be the rate-determining(slowest) step in the overall $CO_2$ permeation.