• 한국수소및신에너지학회논문집
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• 제13권2호
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• pp.110-118
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• 2002

The hydrogen storage vessel having a good heat conductivity along with a simple structure and a low cost for these alloys was designed and manufactured, and then its characteristic properties were studied in this study. The various parts in hydrogen storage vessel consisted of copper pipes and stainless steel of 250 mesh reached the setting temperature after 4~5 minutes, which indicated that storage vessel had a good heat conductivity that was required in application. And also the storage vessel had a good property of hydrogen transport considering that the reaction time between hydrogen and rare-earth metal alloys in storage vessel was found to be within 10 min at $18^{\circ}C$ under 10 atmospheric pressure. It showed that the average capacity of discharged hydrogen volume was found to be $120{\ell}$ for $MmNi_{4.5}Mn_{0.5}$ under discharging conditions of $40^{\circ}C{\sim}80^{\circ}C$ at a constant flow rate of $5{\ell}$/min. It was found that the optimum discharging temperature for obtaining an appropriate pressure of 3atm was determined to be $60^{\circ}C$ for $MmNi_{4.5}Mn_{0.5}$ hydrogen storage alloy.

• 대한금속재료학회지
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• 제49권12호
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• pp.945-949
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• 2011

The cycling characteristics of $MgH_2$ made by hydriding chemical vapor deposition method have been investigated. The particle size of $MgH_2$ made by HCVD was about $1{\mu}m$. The cycling experiment was performed by measuring hydrogen quantity absorbed at 673 K and under 35 atm of hydrogen pressure for 30 min. Up to 3 cycles the hydrogen storage capacity increased, but from 4 to 6 cycles the hydrogen storage capacity decreased rapidly. During this cycling test the particle size increased gradually from $1{\mu}m$ to $6{\mu}m$. This increase was due to sintering by the high reaction temperature and the heat of reaction during hydrogen absorption. From 7 to 30 cycles, the hydrogen storage capacity was maintained at 5.8 wt%. Even after 30 cycles, the plateau pressure was constant.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.641-649
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• 2023

This study analyzes the cool-down process of liquid hydrogen storage tanks, which have advantages in terms of large-capacity transfer, storage, and utilization as hydrogen demand increases. A hydrogen liquefaction plant is selected for analysis and an efficient tank cooling method is sought by comparing the time required for the cool-down process with the gas consumption in connection with the gassing-up process required for the operation of the liquid hydrogen storage tank. The results of this study can be referred to in the operation process after the initial start-up and maintenance of the hydrogen liquefaction plant.

• Metals and materials international
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• 제24권6호
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• pp.1403-1411
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• 2018

Graphene (multilayer graphene) was chosen as an additive to improve the hydrogen uptake and release properties of magnesium (Mg). Five weight percent of graphene was added to pre-milled Mg by milling in hydrogen (reaction-involving milling). The hydrogen uptake and release properties of the graphene-added Mg were investigated. The activation of Mg-5graphene, which was prepared by adding 5 wt% graphene to Mg pre-milled for 24 h, was completed after the second cycle (cycle number, CN=2). Mg-5graphene had a high effective hydrogen-storage capacity (the quantity of hydrogen absorbed for 60 min) of 6.21 wt% at CN=3 at 593 K in 12 bar $H_2$. At CN=1, Mg-5graphene released 0.46 wt% hydrogen for 10 min and 4.99 wt% hydrogen for 60 min. Milling in hydrogen is believed to create defects (leading to facilitation of nucleation), produce cracks and clean surfaces (leading to increase in reactivity), and decrease particle size (leading to diminution of diffusion distances or increasing the flux of diffusing hydrogen atoms). The added graphene is believed to have helped the sample have higher hydrogen uptake and release rates, weakly but partly, by dispersing heat rapidly.

• 한국초전도ㆍ저온공학회논문지
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• 제25권4호
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• pp.65-69
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• 2023

Hydrogen is an eco-friendly energy source and is being actively researched in various fields around the world, including mobility and aerospace. In order to effectively utilize hydrogen energy, it should be used in a liquid state with high energy storage density, but when hydrogen is stored in a liquid state, BOG (boil-off gas) is generated due to the temperature difference with the atmosphere. This should be re-condensed when considering storage efficiency and economy. In particular, large-capacity liquid hydrogen storage tank is required a gaseous helium circulation cooling system that cools by circulating cryogenic refrigerant due to the increase in heat intrusion from external air as the heat transfer area increases and the wide distribution of the gas layer inside the tank. In order to effectively apply the system, thermo-hydraulic analysis through process analysis is required. In this study, the condenser design and system characteristics of a gaseous helium circulation cooling system for BOG recondensation of a liquefied hydrogen storage tank were compared.

• 한국수소및신에너지학회논문집
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• 제18권3호
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• pp.250-255
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• 2007

Hydrogen storage properties of $Ti_{0.32}Cr_{0.43-X}V_{0.25}M_X$($0{\leq}X{\leq}0.1$, M=Fe, Mn, Si) have been investigated. With varing of Mn content, the lattice parameter of the alloy was unchanged and similar to that of $Ti_{0.32}Cr_{0.43}V_{0.25}$ alloy. With increase of Fe, Si content, the lattice parameters of the BCC phases decreased. When the Fe content was 8 at%, the desorption plateau pressure increased to several atmospheres without decrease of the effective hydrogen storage capacity of the alloy. When the Mn content was 8 at%, the effective hydrogen storage capacity showed approximately 2.5 wt% without change in the desorption plateau pressure. With increase of Si content, hysteresis increased and hydrogen storage capacity decreased rapidly. A study was also made on how desorption temperature affected the usable hydrogen of the $Ti_{0.32}Cr_{0.35}V_{0.25}Mn_{0.08}$ alloy. The temperature was varied from 293 to 413 K, and the pressure from 5 to 0.002 MPa. The usable hydrogen of the alloy was 2.7 wt% when absorbed and desorbed at 293 K and 373 K., respectively. The heat of hydride formation of the alloy was approximately -35.5 kJ/mol $H_2$.

• 한국수소및신에너지학회논문집
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• 제10권2호
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• pp.131-139
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• 1999

The objective of this works was to synthesize the$Mg_2Ni$ hydrogen storage materials economically and to eliminate the intial activation process. $Mg_2NiH_x$ was mechanically alloyed under purified hydrogen gas atmosphere using pure Mg and Ni chips. M.A(Mechanical Alloying) was carried out using planetary ball mill for times varying from 12h to 96h under 20bars of hydrogen gas pressure. $Mg_2NiH_x$ started to form after 48h and the homogeneous $Mg_2NiH_x$ composites was synthesized after 96h. From TG analysis, the dehydriding reaction of $Mg_2NiH_x$ started at around $200^{\circ}C$. The result of P-C-T at $300^{\circ}C$ revealed the hydrogen storage capacity of $Mg_2NiH_c$ reached 3.68 wt% and the effective hydrogen storage was 2.38 wt%. The enthalpy difference of absorption-desorption cycling for the hydride formation and the hysteresis were reduced and the plateau flatness and the sloping were improved according to M.A time.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.744-744
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• 2009

The development of safe and suitable hydrogen storage materials is one of key issues for commercializing hydrogen as an energy carrier. Carbon based materials have been investigated for many years to store hydrogen by the adsorption of the gas on the surface of the carbon structure. Recently, it is reported that carbon nitride nanobells have high hydrogen storage capacity since the nitrogen atom plays an important role on attracting hydrogen molecules. Here we report carbon nitride microporous spheres (CNMS) which have the maximum surface area of 995.3 $m^2/g$. Melamine-Formaldehyde resin is the source of carbon and nitrogen in CNMS. Most of the CNMS pores have diameters in the range of 6 to 8 A which could give a penetration energy barrier to a certain molecule. In addition, the maximum hydrogen storage capacities of carbon nitride spheres are 1.9 wt% under 77 K and 1 atm.

• 한국수소및신에너지학회논문집
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• 제19권1호
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• pp.64-70
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• 2008

This paper briefly discusses the main sources of errors and their solutions for measuring hydrogen uptake from gas phase by the Sieverts technique. Correction of volumetric errors of apparatus, density of hydrogen storage material, estimation of temperature gradient are investigated. Systematic errors and the change of density of the host material according to the pressure have been the subject of much controversy in recent years. We considered the standard ball calibration, temperature gradient distribution, pretreatment of hydrogen storage materials to minimize errors. We could lessen the miscalculations after applying those methods to Equilibrium pressure-composition isotherm data.

• 한국분말재료학회지
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• 제15권3호
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• pp.188-195
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• 2008

Carbon nanotube (CNT)/$Mg_2Ni$ composites were synthesized to enhance the hydrogen storage properties. The emphasis was made on the effect of different shortening methods of CNTs on the open-tip structure and the resulting properties. The use of open CNTs as a starting material resulted in an enhanced hydrogen properties of CNT/$Mg_2Ni$ composites. Among the employed methods for the shortening of CNTs, wet milling using ethanol was the most efficient, while ultrasonic acid treatment or thermal decomposition resulted in a less hydrogen storage capacity.