• Title/Summary/Keyword: hydrogen facility

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Characteristics of $H_2$/CO ratio control of syngas by waste gasification (폐기물 가스화 합성가스의 $H_2$/CO 생산비 제어 특성)

  • Gu, Jae-Hoi;Kim, Su-Hyun;Kim, Mun-Hyun;Choi, Jong-Hyea;Heo, Su-Jung;Yoon, Ki-Soo;Kim, Soung-Hyoun
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.475-478
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    • 2008
  • The 3 ton/day-scale pilot plant consists of waste press, feed channel, fixed bed type gasification & melting furnace, quench scrubber, syngas refinery facility and flare stack. $H_2$/CO ratio of gasification syngas using the solid waste and sludge in the 3 ton/day gasifier showed about 1. Gasification melting furnace was operated $1,300{\sim}1,600^{\circ}C$. $H_2$/CO ration control system was obtained $H_2$/CO ratio 2 and 3.

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Water-Side Oxide Layer Thickness Measurement of the Irradiated PWR Fuel Rod by ECT Method

  • Park, Kwang-June;Chun, Yong-Bum
    • Nuclear Engineering and Technology
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    • v.29 no.2
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    • pp.175-180
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    • 1997
  • It has been known that eater-side corrosion of fuel rods in nuclear reactor is accompanied with the metallic loss of wall thickness and hydrogen pickup in the fuel dadding tube. The fuel dad corrosion is one of the major factors to be controlled to maintain the fuel integrity during reactor operation. An oxide later thickness measuring device equipped with ECT probe system was developed by KAERI, and whose performance test was carried out in NDT(Non-destructive Test) hot-cell or PIE(Post Irradiation Examination) Facility. At first, the calibration/performance test was executed for the unirradiated standard specimen rod fabricated with several kinds of plastic thin films whose thickness ore predetermined, and the result of which showed a good precision within 10% of discrepancy. And then, hot test us peformed for the irradiated fuel rod selectively extracted from J44 fuel assembly discharged from Kori Unit-2. The data obtained with this device were compared with the metallographic result obtained from destructive examination in PIEF hot-cell on the same fuel rod to verify the validity of the measurement data.

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The Effect of pH on the Condensation Reaction of Benzaldehyde and Semicarbazide (Benzaldehyde와 Semicarbazide의 결합에 미치는 pH치의 영향)

  • 이길상;김인자
    • YAKHAK HOEJI
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    • v.6 no.1
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    • pp.5-7
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    • 1962
  • Like the condensation reaction of general aldehyde, that of benzaldehyde with semicarbazide also depends upon the concentration of carbonium ion that is produced by hydrogen ion. The lower pH value is the facility of the formation of carbonium ion in the condensation reaction, while the reactivity of semicarbazide as a reactant is reduced. In this paper, therefore we want to find out the optimum pH value in the condensation reaction of benzaldehyde with semicarbazide. This optimum pH value was determined by using the simple paper-chromatographic method. According to the result of this experiment, the condensation reaction between benzaldehyde and semicarbazide reacts with its highest point at 3.5pH value. It seems clear that at this point the benzaldehyde acquires the most suitable amount of carbonium ion for the condensation reaction with semicarbazide, and the semicarbazide also has the optimum reactivity.

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Cryogenic Distillation Apparatus for Hydrogen Isotopes Separation (수소동위원소 분리를 위한 초저온증류장치)

  • 송규민;손순환;김광신;김위수
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2001.02a
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    • pp.163-166
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    • 2001
  • KEPCO has a plan to construct TRF (tritium removal facility) in wolsong nuclear power plant site by 2005. In advance of WTRF construction, the pilot plant was installed at KEPRI in order to show process reliability of WTRF. The main processes of this pilot plant are LPCE(liquid phase catalytic exchange) and CD (cryogenic distillation). Deuterium is separated from heavy water in LPCE process and concentrated in CD process. CD process consists of cold box, where are a distillation column and heat exchangers, vacuum system, cryogenic refrigerant supply system and instrument & control system. The experience of the pilot plant will be used in WTRF design review, operating procedure revision and fundamental education for the operators.

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Odor Reduction Technology in Sewage Treatment Facility Using Biofilter with Reed Grass(Phragmites australls) (갈대(Phragmites australls)수초를 적용한 바이오필터에서의 하수처리시설 악취저감기술)

  • Chung, Jin-Do;Kim, Kyu-Yeol
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.3
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    • pp.373-382
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    • 2013
  • In this study, a biological odor treatment system was proposed to remove odor(foul smell) materials causing several problems in the closed sewage treatment plant. This odor treatment system was composed of a two-step biofilter system in one reactor. The two-step biofilter reactor was constructed with natural purification layer in upper part and artificial purification layer in lower part. The reed grasses of water purification plants were planted in the surface area and mixed porous ceramic media were filled with the lower part of biofilter reactor. By using the above experimental apparatus, the ammonia gas removal efficiency was attained to 98.3 % and the hydrogen sulfide gas removal efficiency was appeared more than 97.7 % which shows more effective than the conventional odor removal process.

Fisetin Protects C2C12 Mouse Myoblasts from Oxidative Stress-Induced Cytotoxicity through Regulation of the Nrf2/HO-1 Signaling

  • Cheol Park;Hee-Jae Cha;Da Hye Kim;Chan-Young Kwon;Shin-Hyung Park;Su Hyun Hong;EunJin Bang;Jaehun Cheong;Gi-Young Kim;Yung Hyun Choi
    • Journal of Microbiology and Biotechnology
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    • v.33 no.5
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    • pp.591-599
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    • 2023
  • Fisetin is a bioactive flavonol molecule and has been shown to have antioxidant potential, but its efficacy has not been fully validated. The aim of the present study was to investigate the protective efficacy of fisetin on C2C12 murine myoblastjdusts under hydrogen peroxide (H2O2)-induced oxidative damage. The results revealed that fisetin significantly weakened H2O2-induced cell viability inhibition and DNA damage while blocking reactive oxygen species (ROS) generation. Fisetin also significantly alleviated cell cycle arrest by H2O2 treatment through by reversing the upregulation of p21WAF1/CIP1 expression and the downregulation of cyclin A and B levels. In addition, fisetin significantly blocked apoptosis induced by H2O2 through increasing the Bcl-2/Bax ratio and attenuating mitochondrial damage, which was accompanied by inactivation of caspase-3 and suppression of poly(ADP-ribose) polymerase cleavage. Furthermore, fisetin-induced nuclear translocation and phosphorylation of Nrf2 were related to the increased expression and activation of heme oxygenase-1 (HO-1) in H2O2-stimulated C2C12 myoblasts. However, the protective efficacy of fisetin on H2O2-mediated cytotoxicity, including cell cycle arrest, apoptosis and mitochondrial dysfunction, were greatly offset when HO-1 activity was artificially inhibited. Therefore, our results indicate that fisetin as an Nrf2 activator effectively abrogated oxidative stress-mediated damage in C2C12 myoblasts.

Development of Algorithm for Vibration Analysis Automation of Rotating Equipments Based on ISO 20816 (ISO 20816 기반 회전기기 진동분석 자동화 알고리즘 개발)

  • JaeWoong Lee;Ugiyeon Lee;Jeongseok Oh
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.93-104
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    • 2024
  • Facility diagnosis is essential for the smooth operation and life extension of rotating equipment used in industrial sites. Compared to other diagnostic methods, vibration diagnosis can find most of the initial defects, such as unbalance, alignment failure, bearing defects and resonance, compared to other diagnostic methods. Therefore, vibration analysis is the most commonly used facility diagnosis method in industrial sites, and is usefully used as a predictive preservation (PdM) technology to manage the condition of the facility. However, since the vibration diagnosis method is performed based on experience based on the standard, it is carried out by experts. Therefore, it is intended to contribute to the reliability of the facility by establishing a system that anyone can easily judge defects by establishing a vibration diagnosis method performed based on experience as a knowledgeable code system. An algorithm was developed based on the ISO-20816 standard for vibration measurement, and the reliability was verified by comparing the results of vibration measurement at various demonstration sites such as petrochemical plant compressors, hydrogen charging stations, and industrial machinery with the results of analysis using a development system. The developed algorithm can contribute to predictive maintenance (PdM) technology that anyone can diagnose the condition of the rotating machine at industrial sites and identify defects early to replace parts at the exact time of replacement. Furthermore, it is expected that it will contribute to reducing maintenance costs and downtime due to the failure of rotating machines when applied to various industrial sites such as oil refining facilities, transportation, production facilities, and aviation facilities.

A Case Study on the Risk Analysis for the Installation of Measurement Error Verification Facility in Hydrogen Refueling Station (수소 충전소 계량오차 검증 설비 설치를 위한 위험성 분석 사례 연구)

  • Hwayoung, Lee;Hyeonwoo, Jang;Minkyung, Lee;Jeonghwan, Kim;Jaehun, Lee
    • Journal of the Korean Institute of Gas
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    • v.26 no.6
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    • pp.30-36
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    • 2022
  • In commercial transactions of energy sources using hydrogen charging stations, high-accuracy flow meters are needed to prevent accidents such as overcharging due to inaccurate measurements and to ensure transparency in hydrogen commercial transactions through accurate measurements. This research developed a Corioli-type flowmeter prototype and conducted a risk assessment to prevent accidents during a process change comparison experiment for existing charging stations to verify the measurement performance. A process change section was defined for the installation of measurement facilities for empirical experiments and HAZOP was conducted. In addition, JSA was also conducted to secure the safety of experimenters, such as preventing valve mis-opening during empirical experiments. Measures were established to improve the risk factors derived through HAZOP, and work procedures were established to minimize human errors and ensure the safety of workers through JSA. The design change and system manufacturing for the installation of the metering system were completed by reflecting the risk assessment results, and safety could be confirmed through the performance comparison test of the developed meter prototype. The developed prototype flow meter showed a total of 30 flow measurements under the operating conditions of 70 MPa, and the average error was -1.58% to 3.96%. Such a metering error was analyzed to have the same performance as a flow meter installed and operated for commercial use.

A study on Safety Management and Control in Wet-Etching Process for H2O2 Reactions (습식 에칭 공정에서의 과산화수소 이상반응에 대한 안전 대책 및 제어에 관한 연구)

  • Yoo, Heung-Ryol;Son, Yung-Deug
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.4
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    • pp.650-656
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    • 2018
  • The TFT-LCD industry is a kind of large-scale industrial Giant Microelectronics device industry and has a similar semiconductor process technology. Wet etching forms a relatively large proportion of the entire TFT process, but the number of published research papers on this topic is limited. The main reason for this is that the components of the etchant, in which the reaction takes place, are confidential and rarely publicized. Aluminum (Al) and copper (Cu), which have been used in recent years for the manufacture of large area LCDs, are very difficult materials to process using wet etching. Cu, a low-resistance material, can only be used in the wet etching process, and is used as a substitute for Al due to its high speed etching, low failure rate, and low power consumption. Further, the abnormal reaction of hydrogen peroxide ($H_2O_2$), which is used as an etching solution, requires additional piping and electrical safety devices. This paper proposes a method of minimizing the damage to the plant in the case of adverse reactions, though it cannot limit the adverse reaction of hydrogen peroxide. In recent years, there have been many cases in which aluminum etching equipment has been changed to copper. This paper presents a countermeasure against abnormal reactions by implementing safety PLC with a high safety grade.

Experimental Study on the NO2/NOX Ratio from Exhaust of Diesel Vehicles by Chassis Dynamometer (경유자동차에서 배출되는 NO2/NOX 비율 특성)

  • KIM, SUNMOON;KIM, JOUNGHWA;JUNG, SUNGWOON;SUNG, KIJAE;KIM, JEONGSOO;KIM, INGU
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.220-224
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    • 2017
  • Nitrogen dioxide ($NO_2$) is an important urban pollutant in Korea. Expecially, diesel vehicles are responsible for the most traffic rated nitrogen oxide ($NO_X$) emission, including nitric oxide (NO) and nitrogen dioxide ($NO_2$). Though nitrogen oxide ($NO_X$) emission from vehicle was applied a strict enforcement of emission standard, the specific $NO_2$ fraction in $NO_X$ ($NO_2/NO_X$) from various types of diesel vehicles was not understood. In order to investigate the fraction of $NO_2/NO_X$, the vehicle emission study was carried out at the facility of Transport Pollution Research Center (TPRC), National Institute of Environmental Research (NIER), Korea. Three different types of diesel vehicles(VAN, SUV, passenger) were tested on the NIER driving mode. The result of $NO_2/NO_X$ ratio was over 0.1 for all test vehicles and the highest $NO_2$ emission was observed at the van vehicle. The observation was showed that the emission trend of $NO_2/NO_X$ for passenger and SUV vehicles were inversely proportional. Also, as the emission standard has been strengthen, the emission rate of $NO_2$ has been decrease.