• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.750-754
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• 2014

Quantitative risk analysis has been performed for a pervaporation process for production of high test peroxide. Potential main accidents are explosion and fire caused by a decomposition reaction. As the target process has a laboratory scale, the consequence is considered to belong to Category 3. An event tree has been developed as a model for occurrence of a decomposition reaction in the target process. The probability functions of the accident causes have been established based on the frequency data of similar events. Using the constructed model, the failure rate has been calculated. The result indicates that additional safety devices are required in order to achieve an acceptable risk level, i.e. an accident frequency less than $10^{-4}/yr$. Therefore, a layer of protection analysis has been applied. As a result, it is suggested to introduce inherently safer design to avoid catalytic reaction, a safety instrumented function to prevent overheating, and a relief system that prevents explosion even if a decomposition reaction occurs. The proposed method is expected to contribute to developing safety management systems for various chemical processes including concentration of hydrogen peroxide.

• Journal of Powder Materials
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• v.13 no.4 s.57
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• pp.269-277
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• 2006

[ ${\beta}-W(W_3O)$ ] oxide layer on the surface of each W(tungsten) nanopowder produced by the electric explosion of wire(EEW) process were formed during the 1vol.% air passivation process. The oxide layer hindered sintering densification of compacts during SPS process. The oxide phase was reduced to the pure W phase during SPS. The W nanopowder's compacts treated by the hydrogen reduction showed high sintered density of 94.5%. after SPS process at $1900^{\circ}C$.

• Journal of the Korean Institute of Gas
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• v.16 no.6
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• pp.29-33
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• 2012

This paper is an attempt to give a concise overview of the state-of-the-art in the recent liquid hydrogen safety researches with unwanted event progress. The vessel of liquified hydrogen may fail and liquid hydrogen spilled. The hydrogen will immediately start to evaporate above a pool and make a hydrogen cloud. The cloud will disperse and can produce a vapor cloud explosion. The vessel containing the liquid hydrogen may not be able to cope with the boil-off due to heat influx, especially in case of a fire, and a BLEVE may occur. In equipment where it exists as compressed gas, a leak generates a jet of gas that can self-ignite immediately or after a short delay and produce a jet flame, or in case it ignites at a source a certain distance from the leak (delayed ignition), a flash fire occurs in the open and with confinement a deflagration or even detonation may develop. The up-to-date knowledge in these events, recent progress and future research are discussed in brief.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.203-204
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• 2022

This study reviewed the impact resistance properties according to the thickness of concrete as part of a research on the protection technology for high-velocity projectile that may occur during an explosion of small green energy facilities such as a hydrogen station and an energy storage system.

• Nuclear Engineering and Technology
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• v.41 no.5
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• pp.617-648
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• 2009

Under the government supported long-term nuclear R&D program, the severe accident research program at KAERI is directed to investigate unresolved severe accident issues such as core debris coolability, steam explosions, and hydrogen combustion both experimentally and numerically. Extensive studies have been performed to evaluate the in-vessel retention of core debris through external reactor vessel cooling concept for APR1400 as a severe accident management strategy. Additionally, an improvement of the insulator design outside the vessel was investigated. To address steam explosions, a series of experiments using a prototypic material was performed in the TROI facility. Major parameters such as material composition and void fraction as well as the relevant physics affecting the energetics of steam explosions were investigated. For hydrogen control in Korean nuclear power plants, evaluation of the hydrogen concentration and the possibility of deflagration-to-detonation transition occurrence in the containment using three-dimensional analysis code, GASFLOW, were performed. Finally, the integrated severe accident analysis code, MIDAS, has been developed for domestication based on MELCOR. The data transfer scheme using pointers was restructured with the modules and the derived-type direct variables using FORTRAN90. New models were implemented to extend the capability of MIDAS.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.3
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• pp.188-193
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• 2009

Fuel cell vehicles are equipped with Pressure Relief Devices(PRDs) installed in pressure tank cylinder to prevent the explosion of the tank during a fire. PRDs are safety devices that perceive a fire and release gas in the pressure tank cylinder before it is exploded. But if the PRD does not actuate, because either the PRD fails or can't be surrounded by the flame of a fire, the tank will rupture and produce a blast wave and hydrogen fire ball. In this paper, we observed the fire behavior of actual fuel cell vehicle, comparing with that of gasoline vehicle.

• Journal of the Korean Society of Safety
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• v.23 no.1
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• pp.1-11
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• 2008

In this study, small punch test and tensile test were performed with specimens directly machined from an ASTM A53 grade B carbon steel pipe at which an explosion accident was occurred in the Heavy Oil Unit. Main damage mechanism of the pipe was known as a high temperature hydrogen attack(HTHA). Effects of HTHA on the mechanical strength change of the A53B steel were studied in detail. Small punch test results have showed that maximum reaction forces, SP energy and ductility were decreased at hydrogen attacked part of the pipe compared with sound part of the pipe. Yield strength and tensile ultimate strength were calculated with the obtained small punch test curve results using different methods and compared the estimation methods. Small punch test simulation has been also performed with the finite element method and then mechanical strength, equivalent strain and fracture toughness were calculated with the obtained numerical analysis results. It was shown that the fracture toughness data calculated from small punch equivalent energy obtained by the finite element analysis for SP test was very low at the hydrogen attacked part.

• Journal of the Korean Institute of Gas
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• v.8 no.4 s.25
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• pp.55-61
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• 2004

This paper provided a counter measures against the troubles and accidents that are likely to take place in the power plant using hydrogen gas as a coolant for the cooling system of the generator. Because of the extremely wide flammability limits of hydrogen in comparison to the other flammable gases, the safety measures against the hydrogen accidents is very important to ensure the normal operation of electric-power facility. This study's purpose was a presentation of standard model of safety management of hydrogen equipments in the coal firing power plant such as following items: 1) providing the technical prevention manual of the hydrogen explosions and hydrogen fires occurring in the cooling system of power generator; 2) the selection of explosion-proof equipments in terms of the risk level of operating environment; 3) the establishment of regulations and counter measures, such as the incorporation of gas leakage alarm device, for preventing the accidents from arising, 4) the establishment of safety management system to ensure the normal operation of the power plant.

• Fire Science and Engineering
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• v.18 no.4
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• pp.22-26
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• 2004

The static eliminator is used for prevention of disasters by static discharge, improvement of production efficiency, protection of a sensitive electronic element on the discharge of static, and it is handled for elimination of static in the painting plant, the film manufacturing plant, the producing semi-conductor factory. This study described on the explosion appearance by discharge phenomena on the voltage input type eliminator's ion generation bar of inflammable gas through an experimental tests. It was used Hydrogen, Ethylene, Propane, Methane gas with the inflammable gas and it was studied on the ignition phenomena by the length of ion-generation static bar, the number of ion-generation electrode and the variation of input voltage to the ion-generation electrode. As a result of this study it was confirmed that the shorter of the bar's length, the greater of explosion danger. And it is considered that there will not ignite at general using inflammable gas, in case of more than 900 mm bar and one electrode.

• Fire Science and Engineering
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• v.25 no.6
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• pp.32-38
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• 2011

As the using rate of an explosive gas has been increased in the industrial site, the regional residents adjacent to the site as well as the site workers have frequently fallen into a dangerous situation. Damage caused by accident in the process using hydrogen gas is not confined only to the relevant process, but also is linked to a large scale of fire or explosion and it bring about heavy casualties. Therefore, personnel in charge should investigate the kinds and causes of the accident, forecast the scale of damage and also, shall establish and manage safety countermeasures. We, in Anti-Calamity Research Center, forecasted the scope of danger if break out a fire or/and explosion in hydrogen gas facilities of MLCC firing process. We selected piping leak accident, which is the most frequent accident case based on an actual analysis of accident data occurred. We select and apply piping leak accident which is the most frequent case based on an actual accident data as a model of damage forecasting scenario caused by accident. A jet fire breaks out if hydrogen gas leaks through pipe size of 10 mm ${\Phi}$ under pressure of 120 bar, and in case of $4kw/m^2$ of radiation level, the radiation heat can produce an effect on up to distance of maximum 12.45 meter. Herein, we are going to recommend safety security and countermeasures for improvement through forecasting of accident damages.