• Title/Summary/Keyword: hydrogen donor

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Anaerobic Treatment of Wastewater containing Nitrate by Upflow Process (질산염을 함유한 폐수의 상향류식 공법에 의한 혐기성 처리)

  • 이원식;은종극
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.95-105
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    • 1998
  • This research was investigated which denitrification of wastewater containing nitrate, using upflow anaerobic sludge blanket process. The upflow anaerobic sludge blanket process is also used for both artifical and industrial wastewater. Main ingredients investigated in the artifical and industrial wastewater experiment were the determination of optimum organism/nitrate ratios, nitrate removal efficiency by various hydrogen donor addition and characteristics of granular sludge and gas production in case of various hydrogen donor addition. From the experimental results the following conclusions were made: In case of adding methanol, ethanol and sodium acetate as hydrogen donor granular sludge was formed 50 days after seeding. Average diameter of granular sludge was 4.0 mm and settling velocity was 37 cm/min. Production rate of gas 3.3 L/d in case of adding methanol as hydrogen donor in wastewater containing 150mg/L nitrate. However adding ethanol and sodium acetate as hydrogen donor, gas production rate were 2.2-2.7L/d respectively. In case of adding methanol as hydrogen donor treatability of artifical wastewater contained 150mg/L as nitrate was about 93%. But in addition of sodium acetate in wastewater contained 40mg.L as nitrate, nitrate removal efficiency was 80%.

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Treatment of wastewater containing nitrate using upflow sludge blanket process (USB 공법에 의한 $NO_3^--N$ 함유 폐수처리)

  • Kim, Hyeong-Seok;Eun, Jong-Keug;Park, Seung-Cho
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.87-87
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

Treatment of wastewater containing nitrate using upflow sludge blanket process (USB 공법에 의한 $NO_3^--N$ 함유 폐수처리)

  • Kim, Hyeong-Seok;Eun, Jong-Keug;Park, Seung-Cho
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.239-247
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

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Denitrification of the wastewater containing nitrate by various hydrogen donor addition (각종 수소공여체의 첨가에 의한 $NO_3^--N$ 함유 폐수의 탈질)

  • Kim, Hyeong-Seok;Eun, Jong-Keug;Park, Seung-Cho
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.229-237
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the NO3--N removal efficiency by various hydrogen donor addition, determination of optimum COD/$NO_3^--N$ ratio and characteristics of granular sludge.

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Denitrification of the wastewater containing nitrate by various hydrogen donor addition (각종 수소공여체의 첨가에 의한 $NO_3^--N$ 함유 폐수의 탈질)

  • Kim, Hyeong-Seok;Eun, Jong-Keug;Park, Seung-Cho
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.77-77
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the NO3--N removal efficiency by various hydrogen donor addition, determination of optimum COD/$NO_3^--N$ ratio and characteristics of granular sludge.

Enantioselective Recognition of Amino Alcohols and Amino Acids by Chiral Binol-Based Aldehydes with Conjugated Rings at the Hydrogen Bonding Donor Sites

  • Kim, Ji-Young;Nandhakumar, Raju;Kim, Kwan-Mook
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1263-1267
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    • 2011
  • Novel binol-based uryl and guanidinium receptors having higher ring conjugation at the periphery of the hydrogen bonding donor sites have been synthesized and utilized to study the enantioselective recognition of 1,2-aminoalcohols and chirality conversion of natural amino acids via imine bond formation. There is a remarkable decrease in the stereoselectivites as the conjugation increases at the periphery of hydrogen bonding donor sites. The guanidinium-based receptors show more selectivity towards the amino alcohol than that of the uryl based ones due to its charge reinforced hydrogen bonds. The conversion efficiency of L-amino acids to Damino acids by the uryl-based receptors is higher than that of the guanidinium-based ones.

Properties of Deep Eutectic Solvents (DESs) and Their Applications (깊은 공융 용매 (DESs) 물성과 응용)

  • Seo, Ho Seong;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.5 no.2
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    • pp.43-48
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    • 2015
  • Deep eutectic solvents (DESs) are now broadly understood as a new kind of ionic liquid (IL) because they exhibit many characteristics and properties similar with ILs. The DESs made of quaternary ammonium salt blended with one of hydrogen bonding donor (HBD) compounds behave as ILs even at very low temperature. In this study, properties such as density, viscosity, surface tension, conductivity, and electrochemical behavior of DESs were reported and their applications were reviewed. Study on DESs has been drawn attention on application in metal finishing, but these solvents can be used in a variety of synthesis, and their potentials have been demonstrated in various areas. DESs are expected to offer applicability by extending the types of salts and hydrogen bond donor mixtures.

A Study on the Nitrogen Control in the Wastewater by Upflow Anaerobic Sludge Blanket. (혐기성 슬러지에 의한 폐수의 질소 제거에 관한 연구)

  • 은종극
    • Journal of environmental and Sanitary engineering
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    • v.12 no.2
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    • pp.75-81
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    • 1997
  • The study was investigated with denitrification of wastewater containing nitrate using upflow anaerobic sludge blanket process. Contents of this study were the determination of nitrate removal efficiency by various hydrogen donor addition, relationship between HRT, nitrate loading rate and growth constant of microorganism in case or various hydrogen donor addition etc. Results from this study were summurized as follows. In case of adding methanol, ethanol, sodium acetate as hydrogen donor, treatability of wastewater contained 200mg/l as nitrate was about 91%. But in addition of ethanol, sodium acetate in wastewater contained 40mg/l as nitrate, nitrate removal efficiency was 80%. While the treatment of nitrate showed the yield coefficient of microorganisms(Y) as 234.8, 234.35, and 247.68 g/VSS/g nitrate, respectively, showed specific growth rate(K) as 0.885, 0.934 and 0.917 respectively.

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Intermolecular Hydrogen Bond between Phenol and DMAs (Phenol과 DMA 간의 수소결합)

  • Kim, Pock-Hye;Lee, Ik-Choon
    • Journal of the Korean Chemical Society
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    • v.10 no.1
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    • pp.15-17
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    • 1966
  • Intermolecular hydrogen-bonding between phenol and N,N'-dimethylanilines (DMA) has been studied by infrared spectrophotometry. Results show that DMA acts as n-and ${\pi}$-donor although n-complex predominates. O-H stretching frequency shifts (${\Delta}{\nu}$) were proportional to basicitys of DMA and excellent linearity was observed between ${\Delta}{\nu}$ and the Hammett substituent constant, ${\sigma}$.

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Studies on Rhodopesudomonas palustris in Korea (한국산 Rhodopseudomonas palustris에 관한 연구)

  • 김경식;이현순
    • Korean Journal of Microbiology
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    • v.14 no.4
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    • pp.167-175
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    • 1976
  • Twenty one strains of Rhodopseudomonas palustris from 7 different regions in Korea have been isolated and identified on the basis of Bergey's Manual in order to study their regional variation. They can use fructose as carbon source (or hydrogen donor). Capacity to produce molecular hydrogen during photosynthesis was tested using liquid medium, modified by omission of $NH_4Cl$ and addition of L0glutamic acid. As nitrogen source nitrate can be used, and isopropanol can be used as hydrogen donor. their pH ranges are 5.9 - 9.1. Their growth are inhibited in the medium that contains 100 units of penicillin G/ml. as for the growing test in dark aerobic condition, the period needed for adptation is longer than that of Korea strain of Rhodopseudomonas gelatinosa.

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