• 비파괴검사학회지
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• 제15권4호
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• pp.549-560
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• 1996

본 연구의 목적은 지금까지 적용되지 않은 극소형시험편을 이용한 소형펀치(small punch : SP)시험과 비파괴시험방법(non-destructive test: NDT)으로 알려진 음항방출(acoustic emission : AE)시험에 의해 수소취화된 압력관 재료의 새로운 파괴강도 평가법으로서 SP시험의 적용 가능성을 조사하는데 있다. 시험결과, 300ppm-H까지의 수소농도에서, 수소농도에 따른 Esp의 저하가 상온보다 $-196^{\circ}C$의 경우가 뚜렷하여, 수소취화정도에 따른 Zr-2.5%Nb 압력관 재료의 파괴강도 평가는 상온보다 $-196^{\circ}C$의 저온환경하에서의 평가가 더욱 우수함을 알 수 있었다. 또한 수소농도의 증가에 따라 재료의 파괴과정에서 발생하는 AE신호의 평균에너지의 peak와 누적 평균에너지 그리고 단위 등가파괴변형률(equivalent fracture strain : ${\epsilon}_{qf}$)당 누적 평균에너지의 값이 크게 증가하였다. 그리고 하중-변위거동, Esp 거동, 거시적, 미시적 SEM 관찰 그리고 AE 시험 결과들로부터 미소시험편을 이용한 SP시험법은 수소취화된 CANDU 압력관 재료의 새로운 파괴강도 평가법으로 유용성이 있음을 알 수 있었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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• pp.11-20
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• 1999

Acoustic pressure response and NO formation of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flame let in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such non-monotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. Acoustic pressure response in each regime is investigated based on the Rayleigh criterion. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted. Emission index of NO shows similar behaviors as to the peak-temperature variation with pressure.

• 한국분무공학회지
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• 제15권4호
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• pp.182-188
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• 2010

Significant real fluid behaviors including rapid property changes take place where high pressure combustion devices such as rocket engines. The flamelet model is the reliable approach to account for the real fluid effects. In the present study, the flamelet equations are extended to treat the general fluids over transcritical and supercritical states. The real fluid flamelet model is carried out for the gaseous hydrogen and cryogenic liquid oxygen flames at the wide range of thermodynamic conditions. Based on numerical results, the precise discussions are made for effects of real fluid, pressure, and differential diffusion on the local flame structure.

• Bulletin of the Korean Chemical Society
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• 제30권3호
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• pp.589-594
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• 2009

We have performed DFT B3LYP/6-31G(d,p) calculations to investigate the complexation behaviors of the ethyl ester derivative of p-tert-butylcalix[6]arene (1) toward a variety of alkylammonium ions. We have studied the binding sites of these host-guest complexes focusing on the p-tert-butylcalix[6]arene pocket (endo) of 1. The smaller alkylammonium cations have the better complexation efficiency than the bulkier alkylammonium ions with the p-tert-butylcalix[6]aryl ester. The hydrogen-bonding of N-H$\ldots$O is one of the important factors for the complexation behavior of the p-tert-butylcalix[6]aryl ester, in addition to the NH-aromatic π, CH-aromatic π and electrostatic interactions, and the steric hindrance of alkylammonium cation. The hydrogen-bonded distances and angles of N-H$\ldots$O are reported for the complexes of the p-tert-butylcalix[6]aryl ester with various alkylammonium ions.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2003년도 춘계학술발표대회 요약집
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• pp.177-177
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• 2003

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2002년도 춘계공동학술발표회요약집
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• pp.257.2-257
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• 2002

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2004년도 요약집 춘계학술발표대회
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• pp.325-325
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• 2004

• Nuclear Engineering and Technology
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• 제45권2호
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• pp.265-276
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• 2013

Pressure tubes made of Zr-2.5 wt% Nb alloy are important components consisting reactor coolant pressure boundary of a pressurized heavy water reactor, in which unanticipated through-wall cracks and rupture may occur due to a delayed hydride cracking (DHC). The Canadian Standards Association has provided deterministic and probabilistic structural integrity evaluation procedures to protect pressure tubes against DHC. However, intuitive understanding and subsequent assessment of flaw behaviors are still insufficient due to complex degradation mechanisms and diverse influential parameters of DHC compared with those of stress corrosion cracking and fatigue crack growth phenomena. In the present study, a deterministic flaw assessment program was developed and applied for systematic integrity assessment of the pressure tubes. Based on the examination results dealing with effects of flaw shapes, pressure tube dimensional changes, hydrogen concentrations of pressure tubes and plant operation scenarios, a simple and rough method for effective cooldown operation was proposed to minimize DHC risks. The developed deterministic assessment program for pressure tubes can be used to derive further technical bases for probabilistic damage frequency assessment.

• Korean Chemical Engineering Research
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• 제51권1호
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• pp.136-143
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• 2013

본 연구에서는 악취 및 휘발성 유기화합물(VOC)를 함유하는 폐가스 처리에 있어서 개선된 바이오필터시스템의 악취 및 VOC의 제거거동 및 제거효율 등을 관찰하고, 전통적 바이오필터의 경우의 악취 및 VOC의 제거거동 및 제거효율 등과 비교하였다. 개선된 바이오필터시스템 운전 1~7단계에서 바이오필터 유효높이 차이에도 불구하고 미생물 population 분포 차이로 인하여, 정해진 시간에 각 단에서 에탄올 농도 순서가 바뀌었다. 반면에 운전 8단계에서 폐가스의 개선된 바이오필터시스템으로의 공급방향들이 바뀌었을 때에 에탄올 농도가 높은 순서는 운전 1~7단계와 다르게 바이오필터의 유효높이가 낮은 순서와 일치하였다. 황화수소 경우도 마찬가지였으나 에탄올 경우와 비교하였을 때에 농도순서가 바뀐 단의 황화수소 농도의 차이는 매우 적었다. 바이오필터 운전 8단계에서 개선된 바이오필터시스템의 에탄올 제거효율은 약 96%로서 전통적 바이오필터반응기의 에탄올 제거효율인 94%보다 약 2% 증가하였다. 개선된 바이오필터시스템 처리가스의 황화수소 농도의 거동은 전통적 바이오필터반응기와 비슷하였으나 황화수소 처리농도가 더 낮았다. 운전 8단계의 개선된 바이오필터시스템의 황화수소제거효율은 전통적 바이오필터반응기의 황화수소 제거효율보다 약 2% 가량 높았다. 따라서 개선된 바이오필터시스템의 제거효율은 에탄올과 황화수소 경우에 전통적 바이오필터반응기보다 각각 2% 제고되었음이 관찰되었다.

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.95-99
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• 2012

Two novel copper(II) complexes, [Cu(dmamhp)$(H_2O)_2(SO_4)]_n$ (1) and [Cu(dmamhp)$(NO_3)_2(H_2O)]{\cdot}H_2O$ (2) [dmamhp = 2-dimethylaminomethyl-3-hydroxypyridine] have been synthesized and structurally characterized by single crystal X-ray diffraction analysis. Compound 1 displays a double one-dimensional chains structure, in which each chain is constituted with the distorted octahedral copper(II) complex bridged through bidentate sulfate ligands resulting in a coordination polymer. The bifurcated hydrogen bonds and $\pi-\pi$ interactions play important roles in the formation of the double chains structure. On the other hand, compound 2 adopts a distorted square pyramidal geometry around copper(II) ion and exists as a discrete monomer. There are intermolecular bifurcated hydrogen bonds and $\pi-\pi$ stacking interactions between the monomeric units. The magnetic properties revealed that the paramagnetic behaviors are dominantly manifested and there are no intermolecular magnetic interactions in both compound 1 and 2.