• Title/Summary/Keyword: hydrochloric acid solubility

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Influences of Several Chemicals on the Solubility of Cocoon Sericin in Water (제사용수(製絲用水)에 대(對)한 몇가지 화학약제(化學藥劑)의 처리(處理)가 견층(繭層) Sericin의 용해성(溶解性)에 미치는 영향(影響))

  • Rhee, In Jeon;Lee, Dong Soo
    • Current Research on Agriculture and Life Sciences
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    • v.1
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    • pp.55-65
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    • 1983
  • The purpose of this study is to find out influences of several chemicals on the solubility of cocoon sericin in water, and there are several results of use to control the solubility of cocoon sericin in water. The results obtained are summarized as follows : The chemical which shows the strongest accelerating power of the solubility of cocoon sericin in water is Sodium Hydroxide (NaOH), the second is Potassium Hydroxide (KOH), the third is Sodium Silicate ($Na_2SiO_3$), and the weakest is Sodium Bicarbonate ($NaHCO_3$) in order among noticed silk-reeling accelerators. The chemical which shows the strongest inhibiting power of the solubility of cocoon sericin in water is Form Aldehyde (HCHO), the second is Ammonium Alum ($Al_2(SO_4)_2{\cdot}(NH_4)_2SO_4{\cdot}24H_2O$), the third is Acetic Acid ($CH_3COOH$), the weakest is Hydrochloric Acid(HCl) in order among noticed silk-reeling inhibitors. Particulary Hydrochloric Acid (HCl), which is expected to show strong inhibiting power of the solubility of cocoon sericin in water, shows accelerating power of the solubility of cocoon sericin at high temperature over 80 degrees of Celsius thermometer in water.

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Vital Wheat Gluten by Hot Air Drying (Vital Wheat Gluten 의 제조)

  • Suh, Hong-Kyl
    • Korean Journal of Food Science and Technology
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    • v.5 no.1
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    • pp.1-5
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    • 1973
  • Dry vital wheat gluten was prepared by atmospheric hot air drying of wet gluten blended with salt and acid. Products of good quality were obtained over a wide range of conditions, as shown by dough expansion, nitrogen solubility, rehydration test, and easinass of smashing and drying after blending. Gluten of good quality was produced by atmospheric hot air drying at $60^{\circ}C$, after blending wet gluten with salt in the range of 5 to 10% and acid, preferably, hydrochloric, at 0.12%.

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Preliminary Research on Securing the Stability of Sandy Beaches in Gyeonggi Province (경기도 해수욕장 모래의 안전성 확보를 위한 선행연구)

  • Choi, Yun-Ho;Byun, Joo-Hyeong;Won, Jong-Moo;Kim, Jong-Sung;Shin, Jong-Hyun;You, Chang-Suk;Jeong, Yun-Ha;Park, Min-Been;Oh, Jo-Gyo
    • Journal of Environmental Health Sciences
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    • v.46 no.6
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    • pp.694-701
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    • 2020
  • Objectives: The main purpose of this study is to evaluate heavy metal concentrations (Cd, As, Hg, Pb, Cr6+), particle size distribution, hydrochloric acid solubility, and parasite eggs in sand in five non-designated sandy beaches in Gyeonggi Province. Methods: The sampling sites are five non-designated Gyeonggi-do sandy beaches located in Ansan and Hwaseong. ICP-OES and UV, a Vibratory Sieve Shaker, and PCM were respectively used to analyze heavy metal concentrations, particle size distribution, and parasite eggs in the sand. Results: Heavy metals were detected within the beach's safety management standards and some of the detected As and Pb before and after beach opening were lower than one-quarter of the average value. In addition, the results of the T-test to confirm the As and Pb concentration changes before and after opening showed a significant difference in some beaches. The composition of sand was 86.53% according to the particle size distribution standard (2.0-0.02 mm), and the hydrochloric acid solubility was the highest at Gubongsolsup (4.9%) and the lowest at Bangameo-li (0.2%). Parasite eggs were undetected in all beach sand before and after opening. Conclusions: The safety of heavy metal concentrations in sandy beaches was secured in the selected five beaches in Gyeonggi Province. However, continuous efforts are required to make Gyeonggi-do's beaches suitable according to the Act on the Use and Management of Beaches.

A Study on the Desorption Behaviors of Some Heavy Metals on Duolite GT-73 Chelating Resin

  • Kim, Sook-Young;Lee, Jae-Suk;Kim, Young-Man;Choi, Beom-Suk
    • Analytical Science and Technology
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    • v.14 no.6
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    • pp.530-534
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    • 2001
  • Effect of stripping solutions on the Duolite GT-73 chelating resin for ten elements, Ag(I), Al(III), Ca(II), Cd(II), Cu(II), Fe(II), Hg(II), Mn(II), Pb(II), and Zn(II), was investigated. Relation between affinities of the metal ions and solubility products of metal sulfides was studied. The smaller the solubility product of metal sulfideis, the larger the affinitie with the ionsis. The ions which have the solubility products larger than $10^{-23}$ could be effectively desorbed with nitric acid. Complexation with chloride ion enhanced the desorption efficiencies of the ions having moderately strong affinity with the resin. The ions which have very strong affinity by the chelating resin can be desorbed by complextion with thiourea and hydrochloric acid.

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A STUDY ON THE MICROSCOPIC CHANGE OF THE ENAMEL SURFACE AFTER ACID ETCHING (법랑질(琺瑯質)의 산탈회(酸脱灰)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Min, Byoung-Duck
    • Restorative Dentistry and Endodontics
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    • v.6 no.1
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    • pp.37-50
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    • 1980
  • Scanning Electron Microscopic (SEM) examination on the labial surface of 91 permanent upper incisors were made after etching procedure with phosphoric acid, sulfuric acid, nitric acid, hydro chloric acid, oxalic acid, formic acid, citric acid and zinc phosphate liquid for 2 minutes. Following results were obtained. 1. In the surfaces etched by 10%. 50% phosphoric acid, 50% sulfuric acid, 10%. 30% nitric acid, 10%. 50% oxalic acid, 10%. 30%. 50% formic acid, 30%. 50% citric acid and zinc phosphate liquid, there appeared to be a preferential removal of prism cores, but in the surfaces etched by 10% phosphoric acid, 50% nitric acid, 10%. 30% hydrochloric acid and 30% oxalic acid, the prism peripheries were removed preferentially. 2. According to Silverstone classification on enamel etching pattern the surface treated by zinc phosphate liquid, 30. 50% citric acid, 10%. 30%. 50% formic acid, 10%. 50% oxalic acid, 10%. 30% nitric acid, 50% sulfuric acid and 10%. 50%. phosphoric acid showed Type 1, and etched by 30% oxalic acid, 10%. 30% hydrochloric acid, 50% nitric acid and 10% phosphoric acid showed Type II. Etching of prism cores was by far the most common occurence. The changes produced could be related to intrinsic differences in histology and / or solubility of enamel.

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Effect of Weak Acid Pretreatment on the Enzymic Hydrolysis against Wheat Gluten of High Concentration (고농도 소맥 글루텐의 효소적 가수분해와 약산에 의한 전처리 효과)

  • 이기영;홍영식;이철호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.6
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    • pp.1110-1116
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    • 1998
  • To determine the optimum conditions for the enzymic hydrolysis against wheat gluten of high con centrations (6~14%, w/w, protein), a hydrolysis system combining weak acid pretreatment and enzymic hydrolysis was investigated. Alcalase showed the highest DH(degree of hydrolysis) of the tested proteases. After hydrolysis by alcalase, subsequently peptidases were applied for the better DH of the wheat gluten hydrolyzate. Peptidase NP2 showed the highest DH of the tested peptidases, but flavour zyme was shown for the lowest bitter taste of the resulting hydrolyzate. In order to minimize aggregation or gelling at higher initial substrate concentration during heat treatment, wheat gluten suspension was pretreated with possibly low concentrations of hydrochloric acid at 105oC for 1 hour, and then enzy matically hydrolysed with alcalase and subsequently with flavourzyme. Each required minimum concen tration of hydrochloric acid in the wheat gluten suspension of 6, 8, 10, 12, and 14%(w/w, protein) was 0.10, 0.15, 0.20, 0.225, and 0.275N, respectively. After the subsequent enzymic treatment by alcalase and peptidase NP2 for 24 hrs, the nitrogen solubility in the final wheat gluten hydrolysates was increased to 94.9, 86.4, 85.3, 89.3 and 95.0%, and their amino nitrogen content was increased to 2.87, 5.68, 7.34, 9.71 and 12.50mg/m, respectively.

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A Study on Purification of Chitin and Chitosan for Textile Finishing Agent from Crab Shell (게껍질로부터 섬유가공용 Chitin.Chitosan 정제에 관한 연구)

  • Lee, Seok-Young;Park, Sung-Woo;Cho, Hwan;Gu, Kang
    • Textile Coloration and Finishing
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    • v.11 no.2
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    • pp.55-63
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    • 1999
  • The purpose of this study was to investigate the purification of chitin and chitosan for textile finishing agent from crab shell. Weight loss rate(removing Ca and protein), degree of deacetylation, solubility and MIC(Minimum growth inhibitory concentration) value of chitosan and molecular weight of the treated crab shell were measured. The results of this study were as follows : 1) Weight loss rate(removing Ca) of crab shell treated with HCI increased with the concentration of HCI and treatment time, but it became constant over 60 min. of treatment time. 2) Weight loss rate(removing protein) of crab shell treated with NaOH(0.5N∼2N) increased with the concentration of NaOH and treatment temperature and time, but it became constant above loot of temperature and over 200 min. of treatment time. 3) Degree of deacetylation of chitin treated with NaOH increased with the concentration of NaOH(40∼60%), but molecular weight decreased and thus MIC value increased. 4) Concentration of acetic acid should be above 0.3% to dissolve chitosan easily. Solubility for chitosan was the highest with formic acid, and the next was acetic acid, hydrochloric acid, lactic acid and sulfuric acid in order.

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Preparation and Identification of Crystal Modification of Piroxicam

  • Suh, Jung-Jin;Kim, Bong-Hee;Ko, Jung-Gil
    • Journal of Pharmaceutical Investigation
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    • v.15 no.1
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    • pp.8-14
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    • 1985
  • Data obtained from X-ray diffractometry, thermal analysis, IR spectroscopy and microscopic observation were used for the identification and characterization of four crystalline modifications of piroxicam. form a was crystallized from sodium hydroxide-hydrochloric acid and from c was obtained by crystallization from toluene. Form b and d was crystallized from methanol under the different temperature conditions. Relative rates of dissolution and solubility of four crystal forms of piroxicam in distilled water were measured.

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Changes of Silk Protein Compositions by Solubility Condition (용해조건에 따른 견 단백질의 조성 변화)

  • Yeo, Joo-Hong;Lee, Kwang-Gill;Lee, Yong-Woo;Nam, Jin;Kim, Sun-Yeou
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.306-311
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    • 1999
  • Changes of silk protein compositions of average molecular weight (Mw) and free amino acid composition to different solubility conditions were studied by SDS-polyacrylamide electropholesis, gel permeation chromatography (GPC), and free amino acid analysis method. We can not detected average molecular weight distribution of different hydrochloric acid (HCl) conditions as SDS-polyacrylamide method, but as using GPC method, molecular weight distribution of 2N-HCl, 1N-HCl and 0.5N-HCl (3 hrs at $110^{\circ}C$ treated) are confirmed Mw 800, 1,500 and 3,700, respectively. The average molecular weight of calcium chroride and calcium chloride-enzyme treated samples are shown Mw 46,800 and 12,500, respectively. The degree of hydrolysis and the composition of the free amino acid in the fibroin hydrolysates effected significantly composition of free amino acids of the fibroin powder. The increase of the degree of hydrolysis and ratio of free amino acids and oligopeptides were found to be directly related to the concentration of hydrochloric acid and treatment of enzyme, resulting in the increase of water solubility.

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Dissolution and Stability Enhancements of Trimethoprim by ${\beta}-Cyclodextrin$ Polymer Inclusion Complexation (트리메토프림과 ${\beta}$-시클로덱스트린 고분자 간의 포접복합체 형성에 의한 용출 및 안정성 향상)

  • Kim, Hyung-Tae;Park, Kyung-Ock;Seo, Seong-Hoon
    • Journal of Pharmaceutical Investigation
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    • v.22 no.2
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    • pp.105-113
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    • 1992
  • To improve the solubility and dissolution rate of trimethoprim (TMP), which is slightly soluble drug, its inclusion complexes were prepared and studied in this experiment. Inclusion complexes of TMP with ${\beta}-cyclodextrin$ and ${\beta}-cyclodextrin$ polymer (CDPS) were prepared according to Fenyvesi method. These were compared with TMP and its physical mixture with CDPS. Water, diluted hydrochloric acid and phosphate buffer solution were used as dissolution media. And accelerated stability test was studied at $50,\;70\;and \;80^{\circ}C$. It was found that solubility and dissolution rate of inclusion complexes were increased in water. Especially, the solubility and dissolution rate of TMP was found to be markedly increased by inclusion complexation with CDPS. In stability test, ${\beta}-cyclodextrin$ inclusion complexes were more or less stable than TMP alone. This tendency was not led in CDPS. Consequently, CDPS was useful in increasing dissolution rate and stability of TMP.

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