• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2018.11a
• /
• pp.75-76
• /
• 2018

MiDF, Micro Defect Free concrete, is the concrete made for high strength development by minimizing the defects such as micro pore and ITZ. Since MiDF exhibits strength through hydro-thermal synthesis reaction, it is essential to select the optimum C/S mole ratio. In this study, the basic characteristics of MiDF were evaluated by controlling the C/S mole ratio by SF and QP.

• Journal of the Korea Concrete Institute
• /
• v.20 no.5
• /
• pp.543-548
• /
• 2008

Solid hydrated by hydro-thermal synthesis reaction is cured two times, the first curing is the steam curing at atmospheric pressure and the second one is a high-pressure steam curing, that is autoclaving. Steam curing is to acquire the proper strength for the resistance of treatment in the first curing process, it was not evaluated properly so far. Because of ignorance about curing, some engineers even think that the dry curing is better than the steam curing. The relation between compressive strength of solid hydrated by hydrothermal synthesis reaction and curing condition are presented in this paper. In order to investigate the effect of curing on the strength properties of specimen, the hydration behavior of solid hydrated by hydro-thermal synthesis reaction has been studied over curing condition using XRD, DT-TGA and porosimeter, SEM analysis technique. The results show that the specimens which are cured with blended method of dry and steam curing appear to have better strength properties than that of dry curing and steam curing. Also, there are significant difference of hydration behavior among curing condition in the solid hydrated by hydro-thermal synthesis reaction.

• Journal of the Korean Ceramic Society
• /
• v.23 no.3
• /
• pp.15-20
• /
• 1986

Formation of powders and electromechanical coupling factor of $Pb(Mn_{1/3} Sb_{2/3})_{0.08} Ti_{0.495}Zr_{0.425}O_3$ by hydro-thermal synthesis are described. The hydrothermal reactions each were accomplished at 12$0^{\circ}C$~25$0^{\circ}C$ for 5hours and sintering was accomplished at 1, .20$0^{\circ}C$ for 1hours. The PZT powders by hydrothermal synthesis were formed above 16$0^{\circ}C$ and the forms were cubic types. The ratio of grain size of sintered sample to powder was slowly decreased with the rising of hydrothermal reactino temperature but decreased rapidly above 22$0^{\circ}C$ Sintering density was decreased with the rising of hydrothermal reaction temperature above 16$0^{\circ}C$ but dielectric constant was increased. Electromechanical coupling factor $K_P$ was almost constant at 16$0^{\circ}C$~24$0^{\circ}C$ range and the value of $K_P$ was about 0.43-0.45.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.4
• /
• pp.103-111
• /
• 2012

One of the basic physical properties of the hardened cement paste, the rigidity, is deteriorated during concrete matrix forming, depending on the replacement rate of the crushed stone powder, and due to drying shrinkage. Therefore, the concrete containing crushed stone powder has been limitedly used as non-structural construction material. To improve these disadvantages, a hydrothermal reaction employing method can be considered. High-temperature and high-pressure water is involved in the hydrothermal reaction in the mixing with specific materials. The rigidity improving mechanism is related to the synthesis of calcium silicate. The calcium silicate is produced through reaction between calcium compounds and the silicic acid. Various kinds of calcium silicate can be produced depending on the CaO/$SiO_2$ mole ratio, the temperature of the hydrothermal synthesis, the pressure, and the reaction time. The product of the synthesis mechanism, tobermorite crystal, plays a pivotal role for the rigidity reinforcement. The crushed stone powder, analyzed in this study, contains 50 to 60% of $SiO_2$ and 10 to 20% $Al_2O_3$. The composite rate is appropriate to create the tobermorite crystal through formation of hardened cement matrix under the hydrothermal synthetic conditions and with the CaO in the cement. Moreover, further reinforcement was promoted using the property of material under the identical density through promoting the formation of tobermorite crystal.

• Journal of Korean Society of Water and Wastewater
• /
• v.19 no.4
• /
• pp.455-461
• /
• 2005

This study was designed to investigate the fundamental aspects of a possible recovery of phosphorus strategy from wastewater by using the zirconium mesoporous structured materials as a new type of ion exchangers. Zirconium mesoporous structure material was synthesized by hydro-thermal synthesis. The synthesized zirconium mesoporous structure was examined by X-ray diffraction (XRD) and Transmission electron micrograph (TEM). From the results of XRD and TEM, it was found out that hexagonal mesoporous structure, pore size was about $47{\AA}$, was synthesized. Experimental results showed that the complex of zirconium sulfate tetrahydrate and surfactant micelles had very high ability for capture of phosphorus. The amount of phosphate ions exchanged into the solid was as great as 3.4mmol/g-ZS. And the ion exchange reaction was occurred between $PO_4{^{3-}}$ and $SO_4{^{2-}}$ and also between $PO_4{^{3-}}$ and $OH^-$. Therefore, it is possible to get the higher removal efficiency than other ion exchange media and adsorbent.