• Computers and Concrete
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• 제9권3호
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• pp.179-193
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• 2012

The hydration of cement contributes to the performance characteristics of concrete, such as strength and durability. In order to improve the utilization efficiency of cement and its early properties, the particle size distribution (PSD) of cement varies considerably, and the effects of the particle size distribution of cement on the hydration process should be considered. In order to evaluate effects of PSD separately, experiments testing the isothermal heat generated during the hydration of cements with different particle size distributions but the same chemical composition have been carried out. The measurable hydration depth for cement hydration was proposed and deduced based on the experimental results, and a PSD hydration model was developed in this paper for simulating the effects of particle size distribution on the hydration process of cement. First, a reference hydration rate was derived from the isothermal heat generated by the hydration of ordinary Portland cement. Then, the model was extended to take into account the effect of water-to-cement ratio, hereinafter which was referred to as PSD hydration model. Finally, the PSD hydration model was applied to simulate experiments measuring the isothermal heat generated by the hydration of cement with different particle size distributions at different water-to-cement ratios. This showed that the PSD hydration model had simulated the effects of particle size distribution and water-to-cement ratio on the hydration process of cement with satisfactory accuracy.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표대회 논문집(III)
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• pp.883-887
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• 1998

Hydration is the main reason for the growth of the material properties. A exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development all material properties should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The latter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration.

• Applied Biological Chemistry
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• 제28권2호
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• pp.62-67
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• 1985

일반계(35 품종) 및 다수계(24 품종) 쌀의 수분 흡수 속도에 미치는 인자에 대하여 조사하였다. 각 품종마다 독특한 수분 흡수 속도를 보였으나, 대체로 다수계 품종이 일반계 품종에 비하여 수분 흡수 속도가 빨랐다. 쌀의 수분 흡수 속도는 단백질, 아밀로스, 쌀알의 표면적 및 부피와 상관 관계를 보이지 않았으나, 쌀알의 길이와 폭의 비와는 부의 상관을 보였다.

• 한국세라믹학회지
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• 제26권4호
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• pp.514-520
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• 1989

The early hydration characteristics according to the C3S/C3A ratio and presence of gypsum, in order to establish the hydration mechanism of the system C3S-C3A, have been studied. The rate of C3S dissolution in the system C3S-Gypsum was higher than that in the system C3S. Consequently, the induction period was reduced and the rate of Ca(OH)2 formation in the accleration period was increased. The hydration of C3S in the system C3S-C3A was retarded because Al3+ in the liquid phase originating from the hydration of C3A was incorporated into calcium hydrosilicates formed. The retardation phenomenon of C3S hydration was not appeared in the system C3S-C3A-gypsum because the reaction of monosulfate formation became the rate-determining step.

• 한국식품과학회지
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• 제35권4호
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• pp.660-665
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• 2003

은하콩과 태광콩의 수화속도 및 콩나물 생육 특성에 대한 동결처리의 효과를 수화반응에 대한 속도론적 연구와 콩나물의 재배실험을 통하여 조사하였다. 수화시간에 대한 동결처리의 영향은 침지온도에 따라 달랐는데, $60^{\circ}C$ 이하의 침지온도에서는 수화시간이 15-50% 정도 감소하였으며, $60^{\circ}C$ 이상의 침지온도에서는 수화시간이 감소하지 않았다. 동결 처리한 은하콩과 태광콩의 수화반응에 대한 활성화 에너지는 각각 39.79 및 39.25 kJ/mol로서 동결처리를 하지 않은 콩에 비해 약 20%정도 감소하였다. 은하콩과 태광콩은 동결처리에 의해 콩나물의 발아율, 길이 및 무게는 증가하였으며, 콩나물의 수율은 약간 감소하였고, 굵기는 콩의 품종에 따라 달랐다.

• 한국세라믹학회지
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• 제27권4호
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• pp.560-566
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• 1990

The early hydration characteristics according to the C3A polymorphism and the presence of gypsum, in order to establish the hydration mechanism of the system C3S-C3A, have been studied. The hydration rate of C3A was changed according to the its crystal structure and influenced the hydration of C3S. That is, the hydration rate of C3S was accelerated in case of orthorhombic-C3A, but that was slightly retarded in case of melt-C3A than that of cubic-C3A. In the system C3S-C3A-gypsum, the retardation phenomenon of the reaction of monosulfate formation was observed in case of both orthorhombic and melt-C3A.

• 콘크리트학회논문집
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• 제14권1호
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• pp.118-125
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• 2002

콘크리트는 수화과정을 통하여 재료가 성숙되고, 경화된다. 수화의 진행은 엄밀한 의미에서 재령에 의하지 않고 수화도에 의해 제어되므로, 경화가 진행되는 콘크리트의 모든 재료특성과 미세구조 형성과정은 수화도에 의해 정식화되는 것이 바람직하다. 기존 연구는 주로 양생온도가 수화발열속도에 미치는 영향을 고려한 반응함수 개념을 주로 사용하였고, 또한 내부 수분상태의 영향을 습도함수의 형태로 고려한 연구결과는 실제 수화기구를 반영하지 못하고 단지 각 연구자의 실험조건과 배합조건에만 부합하는 결과를 보인다. 따라서 본 연구는 기존 제안식의 단점을 보완하기 위하여 수화기구와 미세구조 형성 과정에 기초하여 반응속도함수를 모델링하였다. 수화반응속도는 온도 및 수분상태에 따라 변화하므로, 본 연구에서는 수화발열 속도에 영향을 미치는 인자로, 시멘트 종류, 물-시멘트비 등의 배합특성과 양생온도 빛 세공조직의 내부수분상태를 고려하였다. 똔 연구에서 제시한 콘크리트의 수화도 예측모델은 기존의 온도영향만을 주로 고려하는 반응속도함수를 콘크리트내부의 수분분포 상태를 고려하여 모델을 개선하였으며, 이는 실제 측정한 수화도에 매우 근접하여 그 유용성을 검증하였다. 또한 수화도의 정의와 제시한 모델을 이용하여 콘크리트 요소내의 온도, 습도 덴 수화도를 수치적으로 결정하여 단열온도상승곡선을 정확히 모사 할 수 있었다. 제안된 모델은 수화가 진행되는 콘크리트의 여러 역학적 특성 및 미세구조 형성과정을 적절히 표현하고, 수화과정이 온도 및 습도상태를 결정하는 초기재령 콘크리트의 단면 내 온 습도상태를 추정하여 궁극적으로 초기재령 콘크리트의 균열 위험성을 평가하는데 유용하게 이용될 수 있을 것으로 사료된다.

• 한국세라믹학회지
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• 제47권5호
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• pp.394-400
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• 2010

This study examined the effects of particle size on characteristics of cement by controlling the particle size of commercial cement. Through a size adjustment, the cement has increasing more of particles that are less than $10{\mu}m$ in size so the initial reaction time has been shortened as a result of improvement in the early hydration reaction. Additionally, it showed a great characteristics of strength from the early age and the initial hydration heat has been increased as well. In the upper and middle parts cements, the initial hydration reaction rate contribution is high with the $10{\mu}m$ compared to original cement. So the initial hydration reaction rate is improved and as a result, it also showed relatively high hydration heat as well. Additionally, adiabatic temperature also showed an increase rate in the results.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2008년도 춘계 학술논문 발표대회
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• pp.61-65
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• 2008

This study, having combined and displaced blast furnace slag("BS" hereinafter) known as admixture material that delays hydration reaction with coarse particle cement("CC" hereinafter) collected in particle classification method during ordinary portland cement("OPC" hereinafter), reviewed the hydration heat characteristics affecting the concrete. To reduce hydration heat, the study plain-mixed which used 100% OPC for W/B 50% level 1, displaced CC at level 3 of 25%, 50% and 75% for OPC, and by displacing BS with admixture material at level 5 of 0%, 20%, 40%, 60% and 80% for cement(OPC+CC), experimented totally 16 batches. As a result of experiment, in the case of flow, the more CC displacement rate increased, the more it tended to decrease, and the more BS displacement rate increased, the more it decreased. Also, as for simple adiabatic temperature rise by the CC and BS displacement rates, it decreased as displacement rate increased, and particularly in the case of displaced BS of 80%, It showed temperature reduction effect of about 63% companing with plain. Compressive strength decreased in proportion to displacement rate, however strength reduction increment was shown to decrease with age progress.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 추계 학술논문 발표대회
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• pp.176-177
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• 2019

As a result of the Rietveld analysis to determine the effect of carbon nanotubes on the hydration products of cement composites, the quantitative difference of hydration products according to the addition rate of carbon nanotubes was not significant. Ettringite, an early hydration product, was measured to be slightly higher than the planes with carbon nanotubes over all ages. Therefore, it seems that carbon nanotubes have no effect on the hydration production in cement paste.