• Title/Summary/Keyword: hydration properties

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Effect of Ground Granulated Blast Furnace Slag, Pulverized Fuel Ash, Silica Fume on Sulfuric Acid Corrosion Resistance of Cement Matrix

  • Jeon, Joong-Kyu;Moon, Han-Young;Ann, Ki-Yong;Kim, Hong-Sam;Kim, Yang-Bea
    • International Journal of Concrete Structures and Materials
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    • v.18 no.2E
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    • pp.97-102
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    • 2006
  • In this study, the effect of supplementary materials(GGBS, PFA, SF) on sulfuric acid corrosion resistance was assessed by measuring the compressive strength, corroded depth and weight change at 7, 28, 56, 91, 180 and 250 days of immersion in sulfuric acid solution with the pH of 0.5, 1.0, 2.0 and 3.0. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders: increased corroded depth and weight change, and lowered the compressive strength. 60% GGBS mortar specimen was the most resistant to acid corrosion in terms of the corroded depth, weight change and compressive strength, due to the latent hydraulic characteristics and lower portion of calcium hydroxide. The order of resistance to acid was 60% GGBS>20% PFA>10% SF>OPC. In a microscopic examination, it was found that acid corrosion of cement matrix produced gypsum, as a result of decomposition of hydration products, which may loose the structure of cement matrix, thereby leading to a remarkable decrease of concrete properties.

Effect of Morphology and Dispersibility of Silica Nanoparticles on the Mechanical Behaviour of Cement Mortar

  • Singh, Lok Pratap;Goel, Anjali;Bhattachharyya, Sriman Kumar;Ahalawat, Saurabh;Sharma, Usha;Mishra, Geetika
    • International Journal of Concrete Structures and Materials
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    • v.9 no.2
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    • pp.207-217
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    • 2015
  • The influence of powdered and colloidal nano-silica (NS) on the mechanical properties of cement mortar has been investigated. Powdered-NS (~40 nm) was synthesized by employing the sol-gel method and compared with commercially available colloidal NS (~20 nm). SEM and XRD studies revealed that the powdered-NS is non-agglomerated and amorphous, while colloidal-NS is agglomerated in nature. Further, these nanoparticles were incorporated into cement mortar for evaluating compressive strength, gel/space ratio, portlandite quantification, C-S-H quantification and chloride diffusion. Approximately, 27 and 37 % enhancement in compressive strength was observed using colloidal and powdered-NS, respectively, whereas the same was up to 19 % only when silica fume was used. Gel/space ratio was also determined on the basis of degree of hydration of cement mortar and it increases linearly with the compressive strength. Furthermore, DTG results revealed that lime consumption capacity of powdered-NS is significantly higher than colloidal-NS, which results in the formation of additional calcium-silicate-hydrate (C-S-H). Chloride penetration studies revealed that the powdered-NS significantly reduces the ingress of chloride ion as the microstructure is considerably improved by incorporating into cement mortar.

The Plastic Cracking Properties of Fly Ash Concrete with Various Curing Conditions (양생조건에 따른 플라이애쉬 콘크리트의 소성수축균열 특성)

  • Nam, Jae-Hyun;Park, Jong-Hwa
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.1 s.23
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    • pp.91-98
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    • 2007
  • In this study, the property and plastic cracking pattern of concrete were compared and analyzed with the replacement ratio of fly ash 0, 5, 10, 15, 20% by cement weight. And curing conditions of concrete were given variously such as indoors(with wind speed as 0, 300, 500m/min), outdoors and chamber. The hydration temperature had a tendency to decrease as the replacement ratio of fly ash increased, and in the case of the wind speed 0m/min, it was showed that the moment that the amount of evaporation of water from surface of reference concrete was more than the volume of bleeding was 90 min since casting concrete. The time that the crack initiated had a tendency to be more quickly as the replacement ratio of fly ash increased. The number, length, width and area of crack in the indoor curing, exposed outdoor curing, enclosed outdoor curing had a tendency to decrease as the replacement ratio of fly ash increased. The crack had a tendency to decrease in sequence of exposed outdoor, enclosed outdoor curing, indoors curing. The outbreak of cracking by the change of temperature and humidity was affected by relative humidity more than temperature and the cracking had a tendency to increase as relative humidity lowered.

The Strength Properties of Cement-Bentonite Soil Mixtures with Geosynthetics and Metakaolin (토목섬유 및 메타카올린 첨가 시멘트-벤토나이트 혼합토의 강도 특성)

  • Lee, Jae-Deuk;Yeon, Kyu-Seok;Kim, Kwang-Woo;Kim, Yong Seong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.6
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    • pp.159-167
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    • 2012
  • In the present study, an investigation has been made on the application of cement-bentonite soil mixtures as the countermeasure against leachate produced by buried animal carcasses. For this purpose, the strength characteristics of the cement-bentonite soil mixtures mixed with geotextile and metakaolin. After the mixtures with different contents of the cement (0 %, 10 %), bentonite (0 %, 5 %, 10 %, 15 %, 20 %), and weathered soil (100 %, 95 %, 90 %, 85 %, 80 %) were prepared, metakaolin and geotextile were added with different contents (metakaolin : 0 %, 5 %, 10 %, 15 %, 20 % of the cement weight; geotextile : 0 %, 0.5 %, 1 %, 1.5 %, 2 %). Experimental results suggested that the early strength of the mixture increases due to the pore filling, the hydration acceleration, and the pozzolan reaction when metakaolin of 5~10 % of the cement weight was added. In addition, the compressive strength increase when 0.5~1 % geotextile contents were added, and the above these contents, the rate of strength increase was gradually decreased because of the fibrous tangles.

In-Situ Application of High-Strength Antiwashout Underwater Concrete

  • Moon Han-Young;Song Yong-Kyu
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.283-291
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    • 2004
  • Recently, the construction of underwater structures has been gradually increased, but underwater concrete got some problems of quality deterioration and water contamination around cast-in-situ of construction. In addition, massive underwater structures such as LNG tank, underwater concrete structures of large and continuous high- strength subterranean wall under water are being demanded lower heat of hydration. In this paper, the mechanical properties of high-strength antiwashout underwater concrete (HAWC) containing with two kinds of mineral admixtures respectively were investigated. On the basis of these results, the pH value and suspended solids of HAWC manufactured in the mock-up test were 10.0$\Box$11.0 and 51 mg/${\iota}$ at 30 minutes later, respectively, initial and final setting time were about 30,37 hours, and the slump flow was 530$\pm$20Tm. In the placement at a speed of $27 m^3/hr$, there was no large difference in flowing velocity with or without reinforcing bar, and flowing slope was maintained at horizontal level. Compressive strength and elastic modulus of the cored specimen somewhat decreased as flowing distance was far; however, those of central area showed the highest value.

Cooking Characteristics and Firming Rate of Cooked Parboiled Rice (파보일미(Parboiled rice)의 이화학적 특성 -III. 파보일미(추청벼)의 취반 및 노화특성-)

  • 이명선;조은자
    • Korean journal of food and cookery science
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    • v.12 no.1
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    • pp.46-53
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    • 1996
  • To investigate physicochemical and cooking properties of parboiled rice, choochung paddy processed to parboiled rice by three methods (PL, PT, PA) milled and examined hydration, cooking qualities and firming rate of cooked parboiled rice. The results were obtained as follows. The longer the steaming time during parboiling the larger EMC of soaked parboiled rice. Water uptake rate constants (k) of all the parboiled rice during soaking except for PT rice were generally increased than those of raw rice. The longer the steaming time during parboiling the greater volume increase rate constants ( $k_{v}$) of parboiled rice samples. The glelatinization temperature of parboiled rice flour by DSC was more increased than that of raw rice flour. Gelatinized entalpy was decreased and gelatinization content (%SG: degree of starch gelatinization) was increased by parboiling process. In cooking tests, parboiled rices were harder than raw rice and softness (reciprocal of hardness) was greater PT30, PA, PL30 in turns the cooking time of the parboiled rice took longer 3-10 min than that of raw rice, PL30 took longer time than anyother rices. Cooking water of parboiled rices could be observed lighter turbidities than that of raw rice. Firming rate constants of cooked rice during storage 24 hours were generally decreased by parboiling-processing. The time constants, reciprocal of firming constants of cooked PL30 rice were 2 times slower than those of cooked raw rice.e.

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Study on Utilization of Converter Slag as Concrete Admixture

  • Satou, Masaki;Tsuyuki, Naomitsu;Umemura, Yasuhiro;Harada, Hiroshi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.514-519
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    • 2001
  • Converter has been slag produced 10 million tons per year in Japan. It is a steel making by product produced in the same way as the blast-furnace slag. Though blast-furnace slag is being used effectively as a concrete admixture, the converter stag has never been used effectively because of the expansion action of contained free lime and iron oxide. This is an important environmental problem in the steel industry. Beta-2CaOSiO$_2$(beta-C$_2$S) is contained 40 percent in converter slag, therefore it is very promising as a concrete admixture. We proposed an accelerated aging processes capable of stabilizing the converter slag in a short time. The converter slag is dipped into alkali aqueous solution after heating at low temperature. It was subsequently ground to a grain size of 75 ${\mu}{\textrm}{m}$ , inner 30 percent of OPC. The properties of mortar and concrete using the blended cement were determined. As a result, it has become apparent that the expansion was reduced and long term compressive strength was increased while that at early ages was not so remarkable. The hydration exotherm rate was lower than that of the OPC.

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Study on the Properties of Field Applied Non-Curing Concrete in Winter Season (동절기 무양생 콘크리트의 현장적용 성능 평가에 관한 연구)

  • Yoo, Jo-Hyeong;Kim, Woo-Jae;Hong, Seok-Beom;Kim, Hyeong-Cheol;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.5
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    • pp.413-419
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    • 2016
  • In the cold-weathering concrete construction, it is important to ensure stable strength development of concrete in a low temperature environment. In this study, Non-curing cement(NCC) using the classified high fineness cement and self-heating powder was investigated for stable strength development without curing in a low temperature environment (less than $0^{\circ}C$). The actual size Mock-Up tests by various cement type and curing condition are performed to evaluate the strength development and hydration heat of concrete.

Porosity and Electrical Resistivity of Formed Cokes Made from Anthracite and Phenolic resin (무연탄(無煙炭)과 페놀수지(樹脂)로부터 제조(製造)된 성형(成形)코크스의 기공율(氣孔率)과 전기저항율(電氣抵抗率))

  • Lee, Gye-Seung;Song, Young-Jun
    • Resources Recycling
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    • v.17 no.5
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    • pp.19-27
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    • 2008
  • In this study, the porosity and electrical resistivity of the formed coke produced by sintering the mixture of domestic anthracite and phenolic resin were mainly investigated, when the effect of the amount of binder, the hydration temperature and time, the hardening temperature and time, sintering temperature and time, the particle size of anthracite, the grade of anthracite, and the mixing ratio of phenolic resin on the physical properties of the coke were studied. As a result, It was found that the electrical resistivity and porosity of the formed coke are varied in the range of $0.3\sim1.2\Omega{\cdot}cm$ of $10\sim30%$, respectively, in accordance with the variation of factors.

An Experimental Study for Basic Properity of Ultra High-strength Concrete (초고강도 콘크리트의 기초물성에 관한 실험적 연구)

  • Kim Ji-Man;Gong Min-Ho;Yang Dong-Il;Jung Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.39-42
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    • 2006
  • Recently, more highly effective construction materials are needed for the reasonable and economical structure system is required as the construction structures become more multi storied, large-sized and diversified. That is to say, the highly qualified concrete, the molt universal construction material is positively promoted as a part of plan to establish the effective space according to the dead load of structures and diminish of segment profile and to build up the economic structures. In particular, it is tendency of that the study for high strength concrete increases and construction example of reinforced concrete (RC) using the high strength concrete partially increases. However, the high strength concrete has the problems such high brittleness and low ductility. Specially, for the high strength concrete, it has different strength from normal concrete as the internal temperature goes up steadily due to high heat of hydration by the quantities of highly level of cement, so the concrete which is mixed with various scible materials is used. This study conducted a basic experiment to conclude an adequate selection of materials and to calculate an optimal mixing proportion of those materials to produce High-strength concrete. And also we conducted an experiment to find out basic properties of this concrete such as slump-flow, strength.

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