• 제목/요약/키워드: hydration properties

검색결과 694건 처리시간 0.029초

비근육 단백질의 수화조건이 겔 형성에 미치는 영향 (Effect of Hydration Condition of Non-Muscle Protein on Gelling)

  • 조민성;이남걸;조영제
    • 한국수산과학회지
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    • 제35권6호
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    • pp.627-632
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    • 2002
  • [ $10\%$ ]의 단백질농도에서 5, 15, 25, 35$^{\circ}C$에서 각각 48시간까지 수화시킨 첨가단백질의 겔 형성능을 조사하였을 때 대두단백이 혈장단백, 건조난백과 같은 다른 2가지 첨가단백질 사이에는 중요한 차이가 있었으며, 이는 대두단백은 모든 조건에서 겔을 형성하지 못하였고, 수화는 5$^{\circ}C$, 12시간 24시간에서 혈장단백의 젤리강도를 $10\%$ 정도 상승시켰으며, 건조난백의 경우 5, 15, 25$^{\circ}C$에서 12, 24시간에서 $60\%$ 정도 젤리강도를 증가시켰다. 이와 같이 겔 형성능이 상승한 경우는 수화가 단백질의 인력과 척력의 적절한 균형을 제공한 것으로 추정되며, 실제 단백질의 겔 형성능을 이용하는 많은 식품이 있고 또한 가공공정이 다양하지만 적절한 수화공정의 추가는 겔 형성능을 상승시킬 수 있을 것으로 판단되었다.

혼화재를 사용한 콘크리트의 수화모델 (A Hydration Model for Blended Concrete utilizing Secondary Cementitious Powders)

  • 노재명;변근주;송하원
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.140-143
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    • 2004
  • Heat of hydration of concrete under different curing temperatures can be characterized with knowledge of the thermal activity, the heat rate at the reference temperature, and the total heat of hydration of the mixture. The so-called multi-component hydration model incorporates the effect of following variables: cement chemical composition, cement fineness, secondary cementitious powders, mixture proportions, and concrete properties. However, the model does not consider the use of silica fume as a secondary cementitious powder. Therefore, the model that quantifies the heat of hydration due to the use of silica fume is needed. In this thesis, the effects of silica fume on heat of hydration are evaluated and the influence on the heat of hydration are also quantified to be included in the model, so that the analysis using modified multi-component hydration model for silica fume concrete provides more accurate results than normal concrete.

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수화열 저감제의 종류에 따른 콘크리트 품질특성 (Properties of Concrete on the Kind of Hydration Heat Reducing Agent)

  • 전용수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 춘계 학술논문 발표대회 2부
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    • pp.59-60
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    • 2011
  • This study is investigated reduced heat hydration and fresh and hardened concrete of high strength concrete by hydration heat reducing agent that is type of alcohol, paraffin wax micro-capsules, and strontium.

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Characteristics of Hydraulic Lime using Low-grade Dolomitic Limestone

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Jin-Sang;Cho, Kye-Hong;Ahn, Ji-Whan
    • 한국세라믹학회지
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    • 제53권2호
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    • pp.206-214
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    • 2016
  • This study aims to produce dolomitic hydraulic lime (D-NHL) using domestic low grade dolomitic limestone and to determine the effect of adding blast furnace slag (BFS) and gypsum as part of an investigation of the hydration properties of D-NHL to increase the mechanical properties. The main mineral phases of D-NHL as a hydraulic lime binder were $Ca(OH)_2$, $Mg(OH)_2$, $C_2S$, $C_3S$, and MgO residues. $Ca(OH)_2$ transformed into $CaCO_3$ in D-NHL paste over the period of 28 days, but the carbonation of $Mg(OH)_2$ and the hydration of $C_2S$ did not occur until hydration, after 28 days. Through an investigation of the hydration properties of D-NHL pastes mixed with BFS and gypsum, Al-based compounds such as calcium aluminate hydrates ($C_4AH_{13}$) and ettringite were observed at early hydration time. The compressive strength was improved due to the increased quantities of these hydration products. These results show that good performance results from the application of dolomitic hydraulic lime and that a high value product can be made from domestic waste materials.

고유동 자기충전 콘크리트의 압축강도 수준에 따른 수화발열 특성 (Properties of Hydration Heat with Compressive Strength Level of High Flowing Self-Compacting Concrete)

  • 최연왕;정재권;이재남;김병권
    • 대한토목학회논문집
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    • 제29권5A호
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    • pp.531-541
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    • 2009
  • 본 연구에서는 강도수준(30, 50 및 70 MPa)에 따른 고유동 자기충전 콘크리트의 수화발열 특성을 알아보기 위하여 2성분계 및 3성분계 고유동 자기충전 콘크리트를 제조하여 일반콘크리트와 수화열, 응결 및 역학적 특성을 분석 고찰 하였으며, 콘크리트에 사용된 분체에 대한 미소수화열량을 측정하여 얻은 분체의 열특성값, 간이단열온도실험을 실시하여 얻은 콘크리트의 열특성값 및 콘크리트에 사용된 재료의 일반적인 열특성값을 간편한 방법의 추정식을 이용하여 콘크리트 단열온도를 추정하였다. 또한, 온도해석에 의하여 얻어진 수화열 및 단열온도 특성값을 MIDAS CIVIL 06 프로그램을 이용하여 3차원 온도응력 해석을 실시하여 고유동 자기충전 콘크리트의 수화발열 특성 및 수화열에 의한 온도응력을 분석 고찰하였다.

온도, 변형 및 응력 계측을 통한 초기재령 콘크리트의 임계수화도 및 열팽창계수 추정 (Estimation of Critical Degree of Hydration and Thermal Expansion Coefficient of Early-Age Concrete from Measured Temperature, Strain and Stress)

  • 오병환;최성철;신준호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.809-814
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    • 2002
  • Recently, the properties of early-age concrete are increasingly important because these properties directly influence the behavior of early-age concrete structures including stress and cracking behavior. Nevertheless, the studies on early-age concrete are limited to strength and temperature development. The purpose of present study is to propose a simple and rational method which can predict the stress and strain behavior of young age concrete. A series of test have been done to measure the temperature development, strains and stresses in concrete members. The concept of equivalent age was used to define the degree of hydration and this degree of hydration was used to calculate the strength and elastic modulus. The critical degree of hydration and thermal expansion coefficient were calculated using experimental data. It is seen that the critical degree of hydration range from 0.05 to 0.11 based on the measuring method. The thermal expansion coefficient was calculated based on the measured non-mechanical strain and it is found that the coefficient decreases slightly with the increase of age. The consideration of critical degree of hydration in calculating stresses gives more accurate results. The present study provides useful method and data in evaluating early-age behavior of concrete structure.

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An improvement on the concrete exothermic models considering self-temperature duration

  • Zhu, Zhenyang;Chen, Weimin;Qiang, Sheng;Zhang, Guoxin;Liu, Youzhi
    • Computers and Concrete
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    • 제19권6호
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    • pp.659-666
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    • 2017
  • Based on the Arrhenius equations, several hydration exothermic models that precisely calculate the influence of concrete's self-temperature duration on its hydration exothermic rate have been presented. However, the models' convergence is difficult to achieve when applied to engineering projects, especially when the activation energy of the Arrhenius equation is precisely considered. Thus, the models' convergence performance should be improved. To solve this problem and apply the model to engineering projects, the relationship between fast iteration and proper expression forms of the adiabatic temperature rise, the coupling relationship between the pipe-cooling and hydration exothermic models, and the influence of concrete's self-temperature duration on its mechanical properties were studied. Based on these results, the rapid convergence of the hydration exothermic model and its coupling with pipe-cooling models were achieved. The calculation results for a particular engineering project show that the improved concrete hydration exothermic model and the corresponding mechanical model can be suitably applied to engineering projects.

플라이애시를 대량 사용한 콘크리트의 수화열특성 및 강도특성에 관한 연구 (A Study on Hydration Heat Properties and Strength Properties of High Volume Fly-Ash Concrete)

  • 백민수;이영도;정상진
    • 한국건축시공학회지
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    • 제3권3호
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    • pp.135-142
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    • 2003
  • This study is for the great quantity use of fly-ash. For the producing of high volume concrete from the use of fly-ash, the method of replacement between bonding agents and fine aggregate by fly-ash was used at the same time. It was used that the adiabatic temperature rise of concrete about the mass member which had been produced by the method that was mentioned before, and the hydration heat of the core test pieces in concrete was measured. Also the core test pieces which were replaced with fly-ash was studied by the compressive strength's comparison between standard care test pieces and core test pieces. In the case of mass test pieces, hydration heat and the time to reach the highest temperature were decreased by an increase in replaced fly-ash's amounts of concrete. In addition, among the test pieces having the same amounts of concrete, the test pieces having more replaced amounts of fly-ash's fine aggregate showed higher hydration heat and the increased time to reach the highest temperature. Compressive strength was also increased by hydration heat's decrease according to fly-ash replacement. Replacement of fly-ash was more effective in high temperature environment.

보통 포틀랜드 시멘트 물성에 미치는 시멘트 입도의 영향 (Effect of Cement Particle Size on Properties of Ordinary Portland Cement)

  • 변승호;김형철;김재영;최현국;송종택
    • 한국세라믹학회지
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    • 제47권5호
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    • pp.394-400
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    • 2010
  • This study examined the effects of particle size on characteristics of cement by controlling the particle size of commercial cement. Through a size adjustment, the cement has increasing more of particles that are less than $10{\mu}m$ in size so the initial reaction time has been shortened as a result of improvement in the early hydration reaction. Additionally, it showed a great characteristics of strength from the early age and the initial hydration heat has been increased as well. In the upper and middle parts cements, the initial hydration reaction rate contribution is high with the $10{\mu}m$ compared to original cement. So the initial hydration reaction rate is improved and as a result, it also showed relatively high hydration heat as well. Additionally, adiabatic temperature also showed an increase rate in the results.

Effect of $Al_2O_3$ capping layer on properties of MgO protection layer for plasma display panel

  • Eun, Jae-Hwan;Lee, Jung-Heon;Kim, Soo-Gil;Kim, Hyeong-Joon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.628-631
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    • 2002
  • $Al_2O_3$ capping layer and MgO protective layer were deposited by electron beam evaporation method using single crystal source. Thickness of the capping layer, $Al_2O_3$, was varied from 5 nm to 10 nm. Surface morphology was observed by SEM and AFM before and after hydration. And microstructure of deposited $Al_2O_3$ layer and chemical shift of electron binding energy were also observed by high resolution TEM and XPS, respectively, after hydration. From these results, it was found that Mg atoms diffused into $Al_2O_3$ layer, reacted with moisture and formed $Mg(OH)_2$ during hydration. As thickness of $Al_2O_3$ increased, extent of hydration increased. $Al_2O_3$ capped MgO thin films and uncapped MgO thin films were deposited on AC-PDP test panel to characterize discharge properties. Although $Al_2O_3$ has poor discharge properties rather than MgO, because of many hydrated species on the surface of MgO, similar discharge properties were observed.

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