• 제목/요약/키워드: hydration properties

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Properties of Reaction Rim on Blast Furnace Slag Grain with Alkali Activator according to Hydration Reaction (알칼리 자극제(刺戟劑)에 의해 고로(讀爐) 수쇄(水碎) 슬래그의 주위(周圍)에 형성(形成)된 Reaction Rim의 특성(特性))

  • Lee, Seung-Heun;Mun, Young-Bum
    • Resources Recycling
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    • v.18 no.3
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    • pp.42-48
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    • 2009
  • Since there are $OH^-,\;[SiO_4]^{4-}$ ion of high concentration at early hydration in the system added with activator (NaOH+$Na_2OSiO_2$) in the blast furnace slag, different from cement hydration, hydration progresses fast without induction period and forms reaction rim around the blast furnace slag grain. $0.6{\mu}m$ reaction rim was formed around the blast furnace slag grain from the 1 day of reaction period, and the thickness of reaction rim increases over the reaction time, growing to $1{\mu}m$ on the 28 days. Unreacted blast furnace slag grain deformed from angular shape to the spherical shape. Mole ratio of Ca/Si tends to decrease from inside of blast furnace slag grain to reaction rim. Difference of Ca/Si mole ratio between reaction rim and inside the blast furnace slag grain decreased and generated hydrate was a poor crystalline CSH(I) with Ca/Si mole ratio less than 1.5.

Hydration Properties of Korean Soybeans (우리나라 재래종 콩의 수분 흡수 특성)

  • Kim, Jong-Goon;Kim, Woo-Jung;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.20 no.2
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    • pp.256-262
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    • 1988
  • During soaking of 4 varieties of Korean soybeans in water at $4-98^{\circ}C$, an equilibrium state was reached after 3 hr at $60-98^{\circ}C$ but no equilibrium state was observed at $4-40^{\circ}C$ during soaking for 10 hrs. The moisture gain of soybeans held a linear relation with the square root of soaking time regardless of soaking temperatures, which indicated that the basic mechanism of water absorption was diffusion of water. The log time to reach a fixed moisture content showed a linear relation with the soaking temperature during soaking of soybeans at $4-60^{\circ}C$. The z-value decreased in proportions to the increase of hydration. The z-value to reach 50% hydration was the same in all soybeans.

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Effect of Fiber Addition for Improving the Properties of Lightweight Foamed Concrete (경량 기포콘크리트의 성능향상에 대한 섬유혼입의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.383-389
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    • 2015
  • The objective of this study is to develop mixture proportioning approach of crack controlled lightweight foamed concrete without using high-pressure steam curing processes, as an alternative to autoclaved lightweight concrete blocks (class 0.6 specified in KS). To control thermal cracks owing to hydration heat of cementitious materials, 30% ground granulated blast-furnace slag (GGBS) was used as a partial replacement of ordinary portland cement (OPC). Furthermore, polyvinyl alcohol (PVA) and polyamid (PA) fibers were added to improve the crack resistance of foamed concrete. The use of 30% GGBS reduced the peak value of hydration production rate measured from isothermal tests by 28% and the peak temperature of foamed concrete measured from semi-adiabatic hydration tests by 9%. Considering the compressive strength development, internal void structure, and flexural strength of the lightweight foamed concrete, the optimum addition amount of PVA or PA fibers could be recommended to be $0.6kg/m^3$, although PA fiber slightly preferred to PVA fiber in enhancing the flexural strength of foamed concrete.

Comparison of the effect of lithium bentonite and sodium bentonite on the engineering properties of bentonite-cement-sodium silicate grout

  • Zhou, Yao;Wang, Gui H.;Chang, Yong H.
    • Advances in concrete construction
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    • v.9 no.3
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    • pp.279-287
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    • 2020
  • This paper focuses on the engineering properties of Bentonite-Cement-Sodium silicate (BCS) grout, which was prepared by partially replacing the ordinary Portland cement in Cement-Sodium silicate grout with lithium bentonite (Li-bent) and sodium bentonite (Na-bent), respectively. The effect of different Water-to-Solid ratio (W/S) and various replacement percentages of bentonite on the apparent viscosity, bleeding, setting time, and early compressive strength of BCS grout were investigated. The XRD method was used to detect its hydration products. The results showed that both bentonites played a positive role in the stability of BCS grout, increased its apparent viscosity. Na-bent prolonged the setting time of BCS, while 5% of Li-bent shortened the setting time of BCS. The XRD analysis indicated that the hydration products between the mixture containing Na-bent and Li-bent did not differ much. Using bentonite as supplementary cementitious material (SCM) to replace partial cement is a promising way to cut down on carbon dioxide emissions and to produce low-cost, eco-friendly, non-toxic, and water-resistant grout. In addition, Li-bent was superior to Na-bent in improving the strength and the thickening of BCS grouts.

Hydration of Expansive Materials with CSA-System (CSA계 팽창재료의 수화특성)

  • 정성철;송명신;이경희;한천구
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.631-637
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    • 2002
  • This paper deals with hydration properties of the OPC with CSA-system expansive materials. In OPC using CSA, that was formed monosulfate for the main part. but In OPCs using CSA and gypsum, using CSA and gypsum and lime, that were formed ettringite for the main part. On the shrinkage ratio, the former is larger than the latter And CSA-system with gypsum and lime is smallest of all systems. According to dimension of shrinkage ratios are as follows; OPC using CSA only> OPC only> OPC using CSA and gypsum> OPC using CSA, gypsum and lime. And "R"s are 0.32, 0.37, 0.8, 0.8, 0.8 each others. In OPC with CSA-system expansive materials, we know that expansive properties were depend upon the value of "R". "R" means supplying quantities about demanding quantities for ettringite. In the case of expansive materials with CSA-system and lime, it is to be rich Ca(OH)$_2$ in the solution. so, it is formed small ettringite as the needle shapes. they are contribute to expansive.

Properties of Blast Furnace Slag Cement Modified with Electric Arc Furnace Slag (전기로 슬래그를 치환한 고로 슬래그 시멘트의 특성)

  • Lee, Seung-Heun;Hwang, Hae-Jeong;Kwon, Sung-Ku
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.408-414
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    • 2006
  • Properties of slag cement that contained 50 wt% of blast furnace slag were studied when replaced blast furnace slag powder with electric arc furnace slag powder. Electric arc furnace slag was aged for about 2 months in the air by being crushed to be 1-3 mm in size. As a result of the experiment, it was proven that the water content for obtaining the same consistency became decreased as slag is replaced with electric arc furnace slag instead of blast furnace slag. Also, the workability of mortar increased about 30% at the same ratio of water to binder when blast furnace slag was completely replaced with electric arc furnace slag. The compressive strength of mortar on the 28 days increased when a slag replacement rate became 10 wt%, however, it rather decreased when the slag replacement rate exceeded 10 wt%. The heat of hydration became higher for the first 14 h in case of the replacement of slag cement by electric arc furnace slag. Yet, it decreased when 14 h had passed. Therefore, when all blast furnace slag was replaced with electric arc furnace slag, about 15 cal/g heat of hydration decreased when it passed about 72 h.

Effect of Extracting Conditions on the Soluble Solid's Yield of Korean Red Ginseng (추출 조건이 홍미삼(紅尾蔘)의 가용성 물질의 용출률에 미치는 영향)

  • Sung, Hyun-Soon;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.18 no.2
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    • pp.168-172
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    • 1986
  • The swelling and hydration properties of Korean red ginseng tails and yield of total solids in extract were studied during extraction with ethanol solution having a concentration of 0-90% at $60-100^{\circ}C$. Extraction was carried out 5 times which was taken 8 hours per each time of extraction. The swelling, hydration and total solids yield were increased as the ethanol concentration decreased and as the extraction temperature raised. The cumulative value of solids yield suggested that three times of extractions with water or 70% ethanol were effective to recover more than 84%. Linear regression analysis on the properties investigated and extraction conditions showed a linear logarithmic relationship .

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Field Mock up Test of High Strength Concrete for Busan Lotte Town (부산롯데타운용 고강도 콘크리트 현장 적용을 위한 Mock-up Test)

  • Moon, Hyung-Jae;Park, Soon-Jeon;Heo, Jin-Wook;Koo, Ja-Sul;Jeong, Youn-Sung;Lee, Yang-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.223-224
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    • 2009
  • This study was performed to development 80MPa high strength concrete using local raw material of Busan and to estimate field application ability. As the result of three types of mixture, fresh and hardened properties were satisfied with target requirement properties. Hydration temperature was revealed mean 75$\sim$85$\circ$C. Additionally, in case of compressive strength, core specimen's strength is six times higher than field curing specimen by very high hydration heat.

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Modeling of Mechanical Properties of Concrete Mixed with Expansive Additive

  • Choi, Hyeonggil;Noguchi, Takafumi
    • International Journal of Concrete Structures and Materials
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    • v.9 no.4
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    • pp.391-399
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    • 2015
  • This study modeled the compressive strength and elastic modulus of hardened cement that had been treated with an expansive additive to reduce shrinkage, in order to determine the mechanical properties of the material. In hardened cement paste with an expansive additive, hydrates are generated as a result of the hydration between the cement and expansive additive. These hydrates then fill up the pores in the hardened cement. Consequently, a dense, compact structure is formed through the contact between the particles of the expansive additive and the cement, which leads to the manifestation of the strength and elastic modulus. Hence, in this study, the compressive strength and elastic modulus were modeled based on the concept of the mutual contact area of the particles, taking into consideration the extent of the cohesion between particles and the structure formation by the particles. The compressive strength of the material was modeled by considering the relationship between the porosity and the distributional probability of the weakest points, i.e., points that could lead to fracture, in the continuum. The approach used for modeling the elastic modulus considered the pore structure between the particles, which are responsible for transmitting the tensile force, along with the state of compaction of the hydration products, as described by the coefficient of the effective radius. The results of an experimental verification of the model showed that the values predicted by the model correlated closely with the experimental values.

Fire resistance evaluation of fiber-reinforced cement composites using cellulose nanocrystals

  • Lee, Hyung-Joo;Kim, Seung-Ki;Lee, Heon-Seok;Kang, Yong-Hak;Kim, Woosuk;Kang, Thomas H.K.
    • Advances in concrete construction
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    • v.8 no.4
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    • pp.311-320
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    • 2019
  • In this study, the effect of cellulose nanocrystals (CNCs) on the fire resistance properties of fiber-reinforced cement composites was investigated. The main variables were CNCs content (0.4, 0.8 and 1.2vol.% compared with cement), steel fiber ratio, and exposure temperature (100, 200, 400, 600 and 800℃). The fire resistance properties, i.e., residual compressive strength, flexural strength, and porosity, were evaluated in relation with the exposure temperature of the specimens. The CNCs suspensions were prepared to composited dispersion method of magnetic stirring and ultra-sonication. CNCs are effective for increasing the compressive strength at high temperatures but CNCs do not seem to have a significant effect on flexural reinforcement. Porosity test result showed CNCs reduce the non-hydration area inside the cement and promote hydration.