• Journal of the Korean Ceramic Society
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• v.23 no.6
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• pp.1-6
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• 1986

The hydration of $C_3A$ and $C_3A-CaSO_4$.$2H_2O$ was investigated with varying concentration (0.1-1.0%) of sodium gluconate solution. gluconate solution. Sodium gluconate accelerates cation dissolution from $C_3A$ for the first several minutes but depresses the rate of heat evolution in the course of $C_3A$ hydration. The hydration of $C_3A$ in the presence of sodium gluconate was modified such that the formation of the intermediate hydrate C4AH$\chi$ crystal was much reduced and most of the product became amorphous. The retardation of $C_3A-CaSO_4$.$2H_2O$ hydration in the presence of sodium gluconate was controlled by the competitive adsorption between gluconate anion and $SO_4^{-2}$ onto $C_3A$ surface.

• Journal of the Korean Ceramic Society
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• v.27 no.4
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• pp.560-566
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• 1990

The early hydration characteristics according to the C3A polymorphism and the presence of gypsum, in order to establish the hydration mechanism of the system C3S-C3A, have been studied. The hydration rate of C3A was changed according to the its crystal structure and influenced the hydration of C3S. That is, the hydration rate of C3S was accelerated in case of orthorhombic-C3A, but that was slightly retarded in case of melt-C3A than that of cubic-C3A. In the system C3S-C3A-gypsum, the retardation phenomenon of the reaction of monosulfate formation was observed in case of both orthorhombic and melt-C3A.

• Journal of the Korean Ceramic Society
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• v.26 no.4
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• pp.514-520
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• 1989

The early hydration characteristics according to the C3S/C3A ratio and presence of gypsum, in order to establish the hydration mechanism of the system C3S-C3A, have been studied. The rate of C3S dissolution in the system C3S-Gypsum was higher than that in the system C3S. Consequently, the induction period was reduced and the rate of Ca(OH)2 formation in the accleration period was increased. The hydration of C3S in the system C3S-C3A was retarded because Al3+ in the liquid phase originating from the hydration of C3A was incorporated into calcium hydrosilicates formed. The retardation phenomenon of C3S hydration was not appeared in the system C3S-C3A-gypsum because the reaction of monosulfate formation became the rate-determining step.

• Bulletin of the Korean Chemical Society
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• v.29 no.12
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• pp.2528-2530
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• 2008

• Korean Journal of Exercise Nutrition
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• v.25 no.4
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• pp.10-16
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• 2021

[Purpose] The purpose of this study was to (i) assess hydration levels in elite male football players during a national team training camp before and during qualifying matches, (ii) evaluate the effect of coaching strategies for hydration based on feedback from hydration monitoring, and (iii) assess possible relationships between hydration status and training load or wellness markers. [Methods] Thirty-one male players (age 27±4 yrs; height 185±6 cm; weight 82.9±6.7 kg; body fat 10.4±2.3%) representing a national team from the Union of European Football Associations (UEFA) participated. The players were studied during three different national team training camps related to the UEFA Nations League tournament. Urine specific gravity (U_SG) was measured to assess hydration status. During all camps, the players were actively coached on improving strategies for hydration and given individual feedback on their test results. The training load was measured using GPS technology, and wellness questionnaires were completed. [Results] U_SG decreased progressively and significantly (p<0.005) during camp 1 and hydration status improved over the three camps, with fewer dehydrated and more well-hydrated players identified during the last part of camp 3. Significantly (p<0.05) higher U_SG values were observed 2 days prior to a match (MD-2) than on match day (MD); consequently, 52% of the players were dehydrated on MD-2 and only 6% on MD. No correlations were observed between hydration status and training load or wellness markers. [Conclusion] Dehydration is a challenge in elite male football, but continuous monitoring of hydration status and coaching on hydration strategies can lead to major improvements and reduce the degree of dehydration.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.33-39
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• 1999

This study was conducted to confirm the effect of bypass dust on the hydration and mechanical properties of the cement pastes and mortar obtained from ordinary Portland cement (OPC), OPC-slag and OPC-fly ash system. The rate of heat evolution is accelerated with the content of By-pass Dust(BD). total heat evolution increased because alkali-chlorides activated the hydration of blended cement. Compressive strength and bound water content show maximum value at 5wt% By-pass Dust(BD) on each curing time in ordinary Portland cement and slag blended cement. Ca(OH)2 content of Ordinary Portland Cement increased as the content of BD and curing time. In blended cement, the formation of Ca(OH)2 is active at early hydration stage. By pozzolanic reaction, the content of Ca(OH)2 is decreased as curing time goes by. According to the BD content stable chlorides complex of Friedel's salt (C3A·CaCl2·10H2O) is created. Due to the hydration activation effect of chlorides and alkali we observed Type II C-S-H, which developed into densest microstructure.

• Journal of the Korean Ceramic Society
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• v.36 no.1
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• pp.77-81
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• 1999

In order to investigate the effect of fineness on the properties of Portland cement, we prepared five kinds of portland cements with different Blaine values(2300, 2500, 3000, 3500, 45oo $\textrm{cm}^2$/g) and measured Ca(OH)2 analysis, hydration heat, the fluidity and the physical properties of them. According to the results, as the Blain value of cement is lower, the rate of hydration is delayed, and the hydration heat and the compressive strength are decreased. But the fluidity of cement paste is improved. Especially, the hydration heat of the cement with 2500$\textrm{cm}^2$/g of Blaine value is decreased about 15% compared with 3500 $\textrm{cm}^2$/g cement.

• Advances in concrete construction
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• v.6 no.3
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• pp.297-309
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• 2018

The objective of this study was to evaluate the influence of silica fume (SF) on the hydration heat and compressive strength of concrete. Portland cement with w/(c+sf) ratios varying between 0.25 to 0.45 was substituted by 10%, 20% and 30% of SF by mass. A superplasticizer was used to maintain a fluid consistency of the concrete. The heat of hydration was monitored continuously by a semi-adiabatic calorimetric method for 10 days at $20^{\circ}C$. Compressive strengths are tested for each mixture until age of 180 days. The results show that silica fume considerably influences the evolution and the ultimate values of the compressive strengths as well as the hydration heat especially for 10% rate. The w/b ratio has a considerable effect where its decrease modifies compressive strength and hydration heat more than silica fume. The correlation of the obtained results allows deducing of ultimate properties as well as the ages to reach half of their values. The correlation coefficients are close to unity and reflect the judicious choice of these relationships to be used to predict compressive strength and hydration heat.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.799-804
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• 2002

This paper is mainly Intended to show an effect of foundation depth on heat of hydration in mass concrete. From the analysis, it was found that the foundation depth which is not affected by the heat conduction is more than 5 m. But this study shows that, an optimum foundation depth for the FEM analysis for heat of hydration in mass concrete is approximately 1 m from this study. And in order to study tile significance of various parameters, a sensitivity analysis of heat transfer in mass concrete is performed and the amount of heat liberated at complete hydration of unit weight of cement and the reaction velocity of hydration are the most sensitive parameters factors of other various parameters.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.165-166
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• 2012

A thermal stresses by heat of hydration was analyzed according to a change of a pour height in reactor containment building. In case of more than 3.6m pouring height a crack index by heat of hydration analysis resulted in less than 1 because there is not a construction joint of vertical direction and for a self-restraint effect of circumferential section shape. Therefore detailed consideration on a mixture proportion of binder type, quantity in concrete and selection of a form in seasonal air temperature is needed for a control of tensile stress by heat of hydration.