• 한국건축시공학회지
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• 제20권4호
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• pp.321-330
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• 2020

지오폴리머의 반응성은 원재료의 구성성분 및 Si/Al비, Na/Al비, 물-결합재비, 비정질 요소 등을 고려하여 명확한 메커니즘을 규명하는 것은 매우 중요하다. 따라서 원재료 및 알칼리 활성화제의 구성성분을 고려한 %Na₂O, M_s는 반응성을 결정하는 중요한 요소가 된다. 하지만 다수의 연구에서는 알칼리 활성화제의 농도와 양생 조건 등의 기본적인 요소만을 고려하는 한계점을 나타내고 있다. 따라서 본 연구에서는 %Na₂O, Ms 및 고로슬래그 미분말의 혼입량에 따른 지오폴리머 페이스트의 강도특성, 반응열, 길이변화, 미세구조 분석을 실시하였다.

• 한국건축시공학회지
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• 제14권3호
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• pp.273-284
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• 2014

Ultra-high-performance concrete (UHPC) consists of cement, silica fume (SF), sand, fibers, water and superplasticizer. Typical water/binder ratios are 0.15 to 0.20 with 20 to 30% silica fume. In the production of ultra-high performance concrete, a significant temperature rise at an early age can be observed because of the higher cement content per unit mass of concrete. In this paper, by considering the production of calcium hydroxide in cement hydration and its consumption in the pozzolanic reaction, a numerical model is proposed to simulate the hydration of ultra-high performance concrete. The heat evolution rate of UHPC is determined from the contributions of cement hydration and the pozzolanic reaction. Furthermore, by combining a blended-cement hydration model with the finite-element method, the temperature history in the hardening of UHPC is evaluated using the degree of hydration of the cement and the silica fume. The predicted temperature-history curves were compared with experimental data, and a good correlation was found.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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• pp.257-258
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• 2010

본 연구는 매스 콘크리트의 수화열 저감을 위해 혼화재를 다량 치환한 사용한 배합(LHC)에 대하여 실험을 실시하였으며, 그 결과는 다음과 같다. 동일 유동성을 만족하기 위한 감수제량은 약 50% 정도 감소하였으며, 압축강도는 OPC의 약 95% 정도를 발현하였다. 또한 수화열에 의한 온도상승은 OPC 및 FA25에 비해 36~48% 저하하는 것으로 나타나 매스 콘크리트의 수화열 저감에 큰 효과가 있을 것으로 판단된다.

• 한국식품과학회지
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• 제28권5호
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• pp.959-964
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• 1996

동진 품종의 현미를 2분도미, 5분도미, 7분도미로 도정하여, 도정도에 따른 쌀의 수화와 쌀가루의 이화학적 성질 및 호화 특성을 조사하였다. 쌀의 도정도가 증가하면 일반성분 중에서 단백질, 회분, 지방질, 섬유소의 함량이 감소되고, 쌀의 수분 증가량은 감소되고 SEM으로 관찰하였을 때 틈이 점점 현저하였다. 도정도가 증가할수록 쌀가루의 물결합능력, 팽윤력과 용해도는 증가하였다. 아밀로그람에서의 초기 호화온도는 도정도가 증가할수록 낮아졌고 최고점도, breakdown과 consistency는 높아졌다.

• Computers and Concrete
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• 제13권1호
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• pp.97-115
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• 2014

Silica fume is a by-product of induction arc furnaces and has long been used as a mineral admixture to produce high-strength, high-performance concrete. Due to the pozzolanic reaction between calcium hydroxide and silica fume, compared with that of Portland cement, the hydration of concrete containing silica fume is much more complex. In this paper, by considering the production of calcium hydroxide in cement hydration and its consumption in the pozzolanic reaction, a numerical model is proposed to simulate the hydration of concrete containing silica fume. The heat evolution rate of silica fume concrete is determined from the contribution of cement hydration and the pozzolanic reaction. Furthermore, the temperature distribution and temperature history in hardening blended concrete are evaluated based on the degree of hydration of the cement and the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.

• 한국해양공학회지
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• 제23권4호
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• pp.85-90
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• 2009

Although most of existing hydration heat control methods show a certain degree of hydration heat control, generally, there are many problems as mentioned above. Therefore, our laboratory previously developed a hydration heat control method using an exposed heat pipe, which solves most of these problems and simultaneously displays excellent hydration heat control. Unfortunately, even this method had some problems such as the processing, transport, and assembly of heat pipes, and the surface treatment of a cut plane after pouring, and hardening concrete. Therefore, in this study, a hydration heat control method using an embedded pipe has been developed with the expectation that this method solves those problems in hydration heat control using an exposed heat pipe. As a result of the experiment, the peak temperature of ECHP and ICHP specimen about $4.5{\sim}6.5^{\circ}C$ than the OPC specimen and the probability of thermal cracked generated in ECHP and ICHP specimen decreased up to $13{\sim}20%$. Finally, it was confirmed in this study that the hydration heat control method using an embedded heat pipe is significantly more superior and cost effective than the existing method of an exposed one.

• Computers and Concrete
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• 제13권3호
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• pp.361-375
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• 2014

The moisture transport in underground concrete was experimentally investigated and the nonlinear model of moisture transport considering the effects of water diffusion, hydration of cementicious materials and water permeability was proposed. The consumed moisture content by self-desiccation could be firstly calculated according to evolved hydration degree of cement and mineral admixtures. Furthermore, the finite differential method was adopted to solve the moisture transport model by linearizing the nonlinear moisture diffusion coefficient. The comparison between experimental and calculated results showed a good agreement, which indicated that the proposed moisture model could be used to predict moisture content evolution in underground concrete members with drying-wetting boundaries.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.533-535
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• 2004

We suggest the use of a self-assembled ultra thin organic film that can suppress the hydration of MgO protective layer in AC-PDP. We analyzed the degree of hydration of MgO layer in AC-PDP by XPS when exposed to air after vacuum deposition which proved the effectiveness of the hydration prevention. We also made PDP test panels to demonstrate the improvement in the luminance and luminous efficiency when the hydration of MgO surface is suppressed by the use of self-assembled ultra thin organic film.

• 한국구조물진단유지관리공학회 논문집
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• 제8권2호
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• pp.177-183
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• 2004

적산온도은 시멘트 수화의 결과로서 시간이 경과함에 따라 콘크리트 강도가 얻어진다는 것으로 콘크리트의 강도는 시멘트의 수화반응과 관계가 있다. 시멘트의 수화반응은 온도와 경과시간에 큰 영향을 받는다. 따라서 본 연구에서는 콘크리트 강도예측에 있어서 양생시간과 온도의 함수인 적산온도와 고강도콘크리트 강도의 상관성을 검토하고자 하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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• pp.50-51
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• 2015

In marine and coastal environments, penetration of chloride ions is one of the main mechanisms causing concrete reinforcement corrosion. Currently, most of experimental investigations about submerged penetration of chloride ions are started after the four weeks standard curing of concrete. The further hydration of cement and reduction of chloride diffusivity during submerged penetration period are ignored. To overcome this weak point, this paper presents a numerical procedure to analyze simultaneously cement hydration reaction and chloride ion penetration process. First, using a cement hydration model, degree of hydration and phase volume fractions of hardening concrete are determined. Second, the dependences of chloride diffusivity and chloride binding capacity on age of concrete are clarified. Third, chloride profiles in hardening concrete are calculated. The proposed numerical procedure is verified by using chloride penetration test results of concrete with different mixing proportions.