• Title/Summary/Keyword: hydrates

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Distribution of gas hydrates off northern Antarctic Peninsula (남극반도 북부해역의 가스하이드레이트 분포)

  • Hong, Jong-Kuk;Jin, Young-Keun;Lee, Joo-Han;Park, Min-Kyu;Nam, Sang-Heon;Goo, Kyoung-Mo
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.524-527
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    • 2007
  • 남극 반도 북부해역은 남극대륙 주변부에 존재하는 가스하이드레이트 매장 유망지역중의 하나이다. 남극반도 북부해역내에서 BSR이 가장 뚜렷이 나타나는 남셰틀랜드 군도의 대륙주변부에서 가스하이드레이트 특성 및 분포를 연구하기 위한 탄성파 탐사가 1992년, 2005년도 수행되었다. 이 지역에 나타나는 BSR은 대륙사면에서 광범위하게 발달되어있다. 이 지역 BSR에 대한 AVO 분석결과에 의하면 BSR상부지층은 높은 탄성파 속도를 갖으며 하부지층은 가스를 포함하는 것으로 밝혀졌다. 탄성파 단면에 나타난 BSR의 발견지역을 대상으로 분포도를 작성하였으며, 이 지역에 대한 추가적인 탄성파 탐사 완료 후에는 정확한 매장량과 분포가 밝혀질 것이다.

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A multiscale creep model as basis for simulation of early-age concrete behavior

  • Pichler, Ch.;Lackner, R.
    • Computers and Concrete
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    • v.5 no.4
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    • pp.295-328
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    • 2008
  • A previously published multiscale model for early-age cement-based materials [Pichler, et al.2007. "A multiscale micromechanics model for the autogenous-shrinkage deformation of early-age cement-based materials." Engineering Fracture Mechanics, 74, 34-58] is extended towards upscaling of viscoelastic properties. The obtained model links macroscopic behavior, i.e., creep compliance of concrete samples, to the composition of concrete at finer scales and the (supposedly) intrinsic material properties of distinct phases at these scales. Whereas finer-scale composition (and its history) is accessible through recently developed hydration models for the main clinker phases in ordinary Portland cement (OPC), viscous properties of the creep active constituent at finer scales, i.e., calcium-silicate-hydrates (CSH) are identified from macroscopic creep tests using the proposed multiscale model. The proposed multiscale model is assessed by different concrete creep tests reported in the open literature. Moreover, the model prediction is compared to a commonly used macroscopic creep model, the so-called B3 model.

The Microstructure and Mechanical Properties of Fiber Reinforced Calcium Silicate Hydrates (섬유보강 규산칼슘수화물 경화체의 미세조직과 기계적 특성)

  • 엄태선;최상흘
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.491-499
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    • 1997
  • High flexible lightweight composites containing tobermorite as a main mineral is produced using various amorphous silicates, lime, cement and fibers. Here, Mechanical properties of the composites were studied by observing microstructures of hydrates and fibers. Amorphous silicates having better hydraulicity retarded the crystallization of tobermorite due to better formation of C-S-H gel in water bath curing, but, difficult conversion from C-S-H gel to tobermorite in hydrothermal reaction. In the low molar ratio of CaO/SiO2 (0.67), faster crystalization was observed dued to more impurities such as Al2O3 alkali, resulting in improving mechanical properties due to small crystal size and many contact points. It was identified that a lot of calcium silicate hydates formed at surface of pulps increase bonding strength and the crack-resistance of matrix in the composites, but decrease hardness and compressive strength. The choice of amorpous silicates having better hydraulicity, low CaO/SiO2 adding each fibers bellow about 5% in the raw mixs and lower molding pressure should be needed at improve mechanical properties of composites.

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General Idea of NGH and NGH Carrier (NGH 특성 및 NGH 수송선 개요)

  • Kang, Gon;Lee, Sang-Su;Kim, Jung-Hoon
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2011.06a
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    • pp.13-14
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    • 2011
  • Methane Hydrates or Natural Gas Hydrates (hereinafter NGH) are solid-state energy source formed by the clathration of methane gas in water molecules at low temperature and high pressure. NGH is also known as "burning ice" because of its burning property and appearance similar to that of dry ice. Today, concerns about the NGH are rising as an environment-friendly energy source that can replace fossil fuels. In this paper, to keep pace with the research and development of the NGH, the properties of the NGH and the general features of NGH carriers are introduced.

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Phytochemical Compounds from the Underground Parts of Gardenia jasminoides var. radicans Makino (꽃치자 지하부의 식물화학적 성분)

  • Moon, Hyung-In;Oh, Joa-Sub;Kim, Jong-Sik;Chen, Pei-Chun;Zee, Ok-Pyo
    • Korean Journal of Pharmacognosy
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    • v.33 no.1 s.128
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    • pp.1-4
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    • 2002
  • The phytochemical study of the underground parts of Gardenia jasminoides var. radicans Makino (Rubiaceae) led to the isolation of five coumarins. On the basis of spectroscopic evidences, the structures of these compounds were charaterized as ferulic acid(l), 5,8-di-(3-methyl-2,3-dihydroxybutyloxylpsoralen)(2), skimmin(3), uracil(4), $3-0-{\alpha}-D-glucopyranosyl-(1{\rightarrow}4)-{\beta}-D-glucopyranosyloxypeucedanin$ hydrates(5), respectively.

Early Strength and Properties of EVA Powder Modified High Strength Concrete (EVA Powder 개질 고강도 콘크리트의 초기강도 및 수밀특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.123-127
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    • 2005
  • EVA Powder modified high strength concretes were prepared by varying polymer/binder mass ratio with a constant water/binder mass ratio of 0.3. The effect of EVA powder on the slump, hydration heat, compressive and flexural strength, toughness and water absorption ratio was studied. In hydration heat test, temperature of hydration reaction displayed almost fixed level regardless of containing rate of EVA powder, but peak time of hydration reaction displayed late inclination as containing rate of powder increases. With the same water/binder mass ratio, the compressive strength and water absorption of EVA powder modified concretes decreased slightly when EVA powder was added and the flexural strength of EVA powder modified concretes rised slightly when EVA powder was added. Also, the toughness of the modified concretes can be improved markedly. The interpenetrating structure between the polymeric phase and cement hydrates formed at a $2{\sim}6%$(containing rate of EVA powder). The properties of the polymer modified concretes were influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases.

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Characteristics of Internal Hydrate Change in High Temperature Heated Concrete through Micro Analysis (미시 분석을 통한 고온 가열된 콘크리트의 내부 수화물 변화 특성)

  • Ji, Woo-Ram;Shin, Ki-Don;Cho, Hyeon-Seo;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.132-133
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    • 2018
  • The In this study, the change of composition of the hydrates according to the recovery age of concrete in the case of fire damage was confirmed through microscopic analysis. In 28 days of age, the production of ettringite was higher than that of day 1, and the calcium hydroxide was increased in the 91 day. It has been recovered through the generation of major hydrates which affect the strength.

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The Thermal Transformation of Tobermorite-Studies on The Thermal Transformation of Calcium Silicate Hydrates(II)- (Tobermorite의 가열변화 -규산칼슘 수화물의 가열성상에 관한 연구(II)-)

  • 이종근;최상흘;한상목
    • Journal of the Korean Ceramic Society
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    • v.11 no.4
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    • pp.25-30
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    • 1974
  • The mixture of quartz powder and slaked lime with plenty water was oscillated in an autoclave and treated hydrothermally under the pressure of 10 kg/$\textrm{cm}^2$ for 8 hours. The main mineral synthesized was confirmed 11$\AA$ tobermorite by the method of X-ray diffraction and selected area electron diffraction. Tobermorite was heat-treated at 40$0^{\circ}C$, 80$0^{\circ}C$ and 100$0^{\circ}C$ for investigation of transformation of morphology and structure. Electron micrographs showed the thin platy structure of synthetic tobermorite with a little of crumpled foil or fibrous semi-crystalline calcium silicate hydrates. No difference in structure was appeared under the temperature of 80$0^{\circ}C$ but tobermorite converted gradually into wollastonite at 800$^{\circ}$~85$0^{\circ}C$. On heating, moulded material from tobermorite hardly shrinks under 80$0^{\circ}C$.

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Equilibrium Conditions of Methane Hydrate added Help Gases (보조가스가 첨가된 메탄 하이드레이트 상평형 조건에 대한 연구)

  • Kim, Nam-Jin;Lim, Sang-Hoon;Chun, Won-Gee
    • Journal of the Korean Solar Energy Society
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    • v.27 no.4
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    • pp.51-58
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    • 2007
  • Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. When referred to standard conditions, $1m^3$ solid hydrates contain up to $172Nm^3$ of methane gas, depending on the pressure and temperature of production. Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming methane hydrate were theoretically obtained in aqueous single electrolyte solution containing 3wt% NaCl. The results show that the predictions match the previous experimental values very well, and it was found that NaCl acts as an inhibitor.

Synthesis of a Series of Long Chain Lamellar Inorganic/Organic Iron(II) Alkylsulfonate Hydrates

  • Park, Seong-Hun
    • Journal of Integrative Natural Science
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    • v.1 no.2
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    • pp.76-78
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    • 2008
  • A series of the long-chain iron(II) alkylsulfonate hydrates were synthesized via self-assembly of surfactant alkyl chains in aqueous medium. Reaction of iron(II) salts with n-alkylsulfonate yields lamellar $Fe(CnH2n+1SO3)2{\cdot}4H_2O$. These compounds show a layered structure, as determined by XRD, consisting of alternating organic alkylsulfonate layers and inorganic iron(II) hydrate layers, with interlayer distances of upto 3.2 nm. This lamellar structure may be attributed to the amphiphilic nature of the surfactants, mediating the coordination and H-bionding interactions, and the hydrophobic alkyl chains. An alkyl chain packing of present system are differ from those of similar Cu(II) series, which are attributed from the size of hydrated metal(II) ions.

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