• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.148.2-148.2
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• 2011

천연의 메탄 하이드레이트를 생산하기 위한 방법으로는 크게 다음의 세 가지가 알려져 있다; 감압법, 열 자극법, 저해제 주입법. 갑압법이 가장 경제성이 높은 방법으로 보고 있으며, 이를 활용한 개발생산 시에는 해리 이후의 잔류 물에서 하이드레이트 전구체라고 알려진 하이드레이트 구조가 남아 있으며 이는 생산된 메탄 가스의 이송 과정에서 하이드레이트 재생성의 위험을 높이게 된다. 하이드레이트 재생성을 방지할 수 있는 한 가지 수단으로는 억제제를 주입하는 방법이 가능한데, 적절한 양을 주입함으로써 생산의 경제성을 높일 수 있다. 최근 들어 kinetic 억제제의 적용이 인기를 얻고 있는 바, 수용성 고분자인 이들 억제제를 적용하여 초기 하이드레이트 핵 생성을 지연시킬 수 있다. 이들 kinetic 억제제를 메탄 하이드레이트 생산 과정에서 투여하는 방법을 실험적으로 측정해 보았고, 잔류의 하이드레이트 구조에 대한 존재여부에 대하여 간접적으로 증명해보고자 하였다. kinetic 억제제로는 Poly Vinyl Caprolactam (PVCap)을 선택하였다. 해리압력, PVCap 주입 농도에 변화를 주면서 메탄 하이드레이트 생산, 수송과정에서 발생할 수 있는 하이드레이트 재생성 억제에 대한 효과를 실험적으로 측정하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.47-49
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• 2006

The Sea of Okhotsk is the unique area providing the highest methane production rate of the northern hemisphere. The area of focused fluid venting offshore the NE Sakhalin continental slope was investigated during the CHAOS (Hydro-Carbon Hydrate Accumulations in the Okhotsk Sea) expeditions onboard of RV "Akademik Lavrentyev" In 2003, 2005 and 2006. The International Research Project CHAOS (Russia-Korea-Japan) aimed at the study of gas hydrate formation processes associated with the fluid venting in the Sea of Okhotsk. Several new gas hydrate accumulations were discovered during the cruise. Hydrate-associated structures have been named as KOPRI, VNIIOKeangeologia, POI and KIT (the names of cruise participant institutes) Some of hydrate-bearing cores contain big amount of gas hydrates: massive gas hydrate layers (up to 35cm thick) were recovered. The shallowest submarine gas hydrate accumulations in the world (at the depth less then 400m) were discovered during the cruise.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2003.10a
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• pp.391-394
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• 2003

Effects of the polymer-binder ratio and slag content on the properties of combined wet/dry-cured polymer-modified mortars using granulated blast-furnace slag are examined. Results shows that the flexural, compressive, tensile and adhesion in tension strengths of polymer-modified mortar using the slag tend to increase with increasing slag content, and is inclined to increase with increasing polymer-binder ratio. In particular, the polymer-modified mortars with slag content of 40% provide about 20% higher tensile strength than unmodified mortars. Such high strength development is attributed to the high tensile strength of polymer and the improved bond between cement hydrates and aggregates because of the addition of polymer.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.399-404
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• 2008

The influence of gas hydrate dissociation on submarine slope stability was studied in this paper. Gas hydrates are stable under high pressure and low temperature conditions. Once gas hydrate dissociates due to natural or human activities, it generates large amount of gas and water. During gas hydrate dissociation, a pore pressure between soil particles increases and results in the loss of an effective stress and degradation of soil stiffness. A pore pressures model was proposed to calculated excess pore pressures generated by gas hydrate dissociation at the Storegga Slide. A slope stability analysis for the Storegga Slide using a two dimensional finite difference method was carried out by considering excess pore pressures due to gas hydrate dissociation. Since the excess pore pressure calculated by the proposed method resulted in the considerable loss of stiffness and strength in slope, a submarine slope failure occurred at the Storegga slide was well simulated.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.727-730
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• 2005

The purpose of this study evaluates possibilities of waste phosphogypsum into concerts by steam curing admixture. The waste phosphogypsum is made use of 4 forms(Dehydrate, $\beta$-Hemihydrate, III-Anhydrite and II-Anhydrite) which were changed to in low temperature of calcination. The penetration depth and compressive strength of cement mortar are investigated to evaluate the chloride ion and carbonation resistance. As a result, chloride ion and carbonation resistance of cement mortar admixed with waste phosphogypsum are more excellent than cement mortar contained OPC alone. The internal pores of cement mortar are decreased by using waste phosphogypsum, because the hydrates of ettringite which is denesified in structure is much formed in early ages at steam curing. These densified effect is concluded with improving the resistance to attack of cement mortar including waste phospogypsum.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.773-776
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• 2005

MSWI ash is the residue from waste combustion processes at temperature between $850^{\circ}C\;and\;1000^{\circ}C$. And the main components of MSWI ash are $SiO_2,\;CaO\;and\;Al_2O_3$. The aim of this study is to find a way to useful application of MSWI ash(after treatment) as a structural material and to investigates the hydraulic activity, compressive strength development, composition variation of such chemicallyi-activated MSWI ashes concrete. And it was found that early cement hydration, followed by the breakdown and dissolving of the MSWI-ashes, enhanced the formation of calcium silicate hydrates(C-S-H), The XRD and SEM-EDS results indicate that, both the hydration degree and strength development are closely connected with a curing condition and a chemically-activator. Compressive strengths with values in the 40.5MFa were obtained after curing the activated MSWI ashes with NaOH+water glass at $90^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.31 no.11
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• pp.1387-1395
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• 1994

Re-hydration properties of heated and ground CaO-SiO2-H2O system were studied under hydrothermal condition in order to examine the possibility of recycling ALC waste as raw materials of ALC. Powder of calcium silicate hydrates and ALC waste without heat treatment did not show further hydration while those of heat-treated at proper temperature showed re-hydration properties under hydrothermal condition. The lath-like shape of initially synthesized tobermorite was gradually turned into small debris during heating and plate-like tobermorite was crystallized during re-hydration of the heated powders. Heated and ground ALC waste could be added to natural raw mix for ALC at the ammount up to 20% with increased compressive strength and up to 30% with slightly decreased compressive strength. The optimum heating temperature of ALC for recycling was about 50$0^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.31 no.2
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• pp.194-200
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• 1994

Pitchstone(Volcanic ejecta) reacts with CaO in hot water and increases its sedimentary volume by forming Ca(OH)2 and calcium silicate hydrates. ALC was prepared from the various gelling and curing conditions using the ratio of pitchstone/CaO was 2(CaO/SiO2 mol ratio=0.81), and then the products, crystalline phases and physical properties of ALC with experimental conditions was investigated. The crystalline phase of tobermorite with laths and plate type and the porosity were increased, the thermal conductivity was decreased with increasing gelling temperature and time. But modulus of rupture has maximum value when gelling time was 2 hrs. Othwrwise the bulk density nearly unchanged with increasing curing temperature, but the modulus of rupture was increased.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.74-77
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• 2003

This paper investigated the apparent chloride diffusivity of various concretes. Ten mixtures of concrete were initially prepared and tested to estimate diffusion property. The penetration depth and concentration of chloride ion were examined at the same water-binder ration. The binders were composed of normal portland cement, fly ash, ground granulated blast-furnace slag, and silica fume. From the results, it was concluded that using the mineral admixtures had a filling effect on the pore structure of cements matrix due to those pozzoanic reaction with the hydrates of cement, which increases the tortuosity of pore and makes large pore finer. And diffusivity of chloride is following: NPC100 > F10N90 > F30N70 > F20N80 > F20S05 > G30N70 > F10S05 > G30S05 > G30F15 > G50N50.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.399-402
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• 2005

In ultra-high strength SFRCC(Steel Fiber Reinforced Cementious Composites), much silica fume are used to improve strength, flowability and durability. Silica fume have merits of filling the voids, enhancement of reheological chracteristics, production of secondary hydrates by pozzolanic reaction in reactive powder concretes. However silica fume has been imported in high-cost in domestic industry, we need to investigate replaceable material in stead of silica fume in a view of economy Therefore, in this paper, in order to investigate replacement of silica fume in ultra-high strength SFRCC we used the granulate blast-furnce slag with finess 4000, 6000, 8000. As a results, we have evaluated that the bigger the finess the more increase compressive strength of ultra-high strength SFRCC using the blast-furnce slag and there was no problem from the viewpoint of flowability and compressive strength when we use blast-furnce $50\%$ with replacement ratio of silica fume