• Journal of Adhesion and Interface
• /
• v.5 no.1
• /
• pp.21-28
• /
• 2004

In this work, glass fiber/nylon 6 and woven glass fiber/nylon 6 composites have been fabricated using glass fiber reinforcements sized with 3-chloropropyltrimethoxysilane(CTMS) having a chloropropyl organo-functional group in the molecular chain end. The interfacial shear strength of glass fiber/nylon 6 composite was measured using a single fiber microbonding test and the interlaminar shear strength and the storage modulus of woven glass fabric/nylon 6 composites were measured using a short-warn shear test and a dynamic mechanical analysis, respectively, informing the effect of the concentration of CTMS on the properties. With increasing CTMS concentration, the interfacial properties of the composites were improved. The results on the interfacial shear strength, interlaminar shear strength, interlaminar failure pattern, and storage modulus with varying the CTMS concentration agree with each other.

• Macromolecular Research
• /
• v.12 no.1
• /
• pp.119-126
• /
• 2004

In this study, the influence of silane coupling agents, featuring different organo-functional groups on the interlaminar and thermal properties of woven glass fabric-reinforced nylon 6 composites, has been by means of short-beam shear tests, dynamic mechanical analysis, scanning electron microscopy, and thermogravimetric analysis. The results indicate that the fiber-matrix interfacial characteristics obtained using the different analytical methods agree well with each other. The interlaminar shear strengths (ILSS) of glass fabric/nylon 6 composites sized with various silane coupling agents are significantly improved in comparison with that of the composite sized commercially. ILSS of the composites increases in the order: Z-6076 with chloropropyl groups in the silanes > Z-6030 with methacrylate groups> Z-6020 with diamine groups; this trend is similar to that of results found in an earlier study of interfacial shear strength. The dynamic mechanical properties, the fracture surface observations, and the thermal stability also support the interfacial results. The improvement of the interfacial properties may be ascribed to the different chemical reactivities of the reactive amino end groups of nylon 6 and the organo-functional groups located at the ends of the silane chains, which results from the increased chemical reactivity in order chloropropyl > methacrylate > diamine.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.23 no.1
• /
• pp.171-178
• /
• 2019

Fiber-reinforced polymer (FRP) composites have proved to be reliable as strengthening materials. Most of existing studies used single types of FRP composites. Therefore, in this experimental study, carbon FRP sheet, aramid FRP sheet, and hybrid FRP plate including glass fibers were fabricated, and the effect of pre-stressed FRP composites on flexural strengthening of reinforced concrete (RC) beams was investigated. In total, eight RC beam specimens were fabricated, including one control beam (specimen N) without FRP composites and seven FRP-strengthened beams. The main parameters were type of FRP composite, the number of anchors used for pre-stressing, and thickness of FRP plates. As a result, the beam strengthened with pre-stressed FRP plate showed superior performance to the non-strengthened one in terms of initial strength, strength and stiffness at yielding, and ultimate strength. As the number of anchors and thickness of FRP plate (i.e., amount of FRP plates) increased, the strengthening effect increased as well. When hybrid FRP plates were pre-stressed, the strengthening effect was higher in comparison with pre-stressed single type FRP plate.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.37 no.4
• /
• pp.497-502
• /
• 2013

In this study, the interlaminar fracture toughness in mode I of a hybrid composite inserted with different types of non-woven tissues was determined. The interlaminar fracture toughness in mode I is obtained by a double cantilever beam test. The experiment is performed using three types of non-woven tissues: 8 $g/m^2$ of carbon tissue, 10 $g/m^2$ of glass tissue, and 8 $g/m^2$ of polyester tissue. Considering a specimen with no non-woven tissue as a reference, the interlaminar fracture toughness in mode I of specimens inserted with non-woven carbon and glass tissues decreases by as much as 6.3% and 11.4%, respectively. However, the fracture toughness of a hybrid composite specimen inserted with non-woven polyester tissue increases by as much as 69.4%. It is considered that the specimen inserted with non-woven polyester tissue becomes cheaper, and lighter, and the value of the fracture toughness becomes much greater than that of the non-woven carbon tissue.

• Steel and Composite Structures
• /
• v.24 no.3
• /
• pp.287-296
• /
• 2017

The buckling capacity of a radially retractable hybrid grid shell in the closed position was investigated in this paper. The geometrically non-linear elastic buckling and elasto-plastic buckling analyses of the hybrid structure were carried out. A parametric study was done to investigate the effects rise-to-span ratio, beam section, area and pre-stress of cables, on the failure load. Also, the influence of the shape and scale of imperfections on the elasto-plastic buckling loads was discussed. The results show that the critical buckling load is reduced by taking account of material non-linearity. Furthermore, increasing the rise-to-span ratio or the cross-section area of steel beams notably improves the stability of the structure. However, the cross section area and pre-stress of cables pose negligible effect on the structural stability. It can also be found that the hybrid structure is highly sensitive to geometric imperfection which will considerably reduce the failure load. The proper shape and scale of the imperfection are also important.

• Journal of the Korean Society for Aviation and Aeronautics
• /
• v.9 no.1
• /
• pp.59-69
• /
• 2001

The rotor blade is modeled using a composite box beam with arbitrary wall. The active constrained damping layers are bonded to the upper and lower surfaces of the box beam to provide active and passive damping. A finite element model, based on a hybrid displacement theory, is used in the structural analysis. The theory is capable of accurately capturing the transverse shear effects in the composite primary structure, the viscoelastic and the piezoelectric layers within the ACLs. A reduced order model is derived based on the Hankel singular value. A linear quadratic Gaussian (LQG) controller is designed based on the reduced order model and the available measurement output. However, the LQG control system fails to stabilize the perturbed system although it shows good control performance at the nominal operating condition. To improve the robust stability of LQG controller, the loop transfer recovery (LTR) method is applied. Numerical results show that the proposed controller significantly improves rotor aeromechanical stability and suppresses rotor response over large variations in rotating speed by increasing lead-lag modal damping in the coupled rotor-body system.

• Steel and Composite Structures
• /
• v.23 no.4
• /
• pp.409-420
• /
• 2017

This paper theoretically studies the cyclic behavior of hybrid connections between steel coupling beams and concrete shear walls with embedded steel columns. Finite element models of connections with long and short embedded steel columns are built in ABAQUS and validated against the test results in the companion paper. Parametric studies are carried out using the validated FE model to determine the key influencing factors on the load-bearing capacity of connections. A close-form solution of the load-bearing capacity of connections is proposed by considering the contributions from the compressive strength of concrete at the interface between the embedded beam and concrete, shear yielding of column web in the tensile region, and shear capacity of column web and concrete in joint zone. The results show that the bond slip between embedded steel members and concrete should be considered which can be simulated by defining contact boundary conditions. It is found that the loadbearing capacity of connections strongly depends on the section height, flange width and web thickness of the embedded column. The accuracy of the proposed calculation method is validated against test results and also verified against FE results (with differences within 10%). It is recommended that embedded steel columns should be placed along the entire height of shear walls to facilitate construction and enhance the ductility. The thickness and section height of embedded columns should be increased to enhance the load-bearing capacity of connections. The stirrups in the joint zone should be strengthened and embedded columns with very small section height should be avoided.

• Journal of the Korea Concrete Institute
• /
• v.26 no.2
• /
• pp.189-199
• /
• 2014

Currently, in the precast concrete construction, Precast Concrete (PC) and Cast-In-Place (CIP) concrete with different concrete strengths are frequently used. However, current design codes do not specifically provide shear design methods for PC-CIP hybrid members using dual concrete strengths. In the present study, simply supported composite beams with shear reinforcement were tested. The test variables were the area ratio of the two concretes, spacing of shear reinforcement, and shear span-to-depth ratio. The shear strengths of the test specimens were evaluated by current design codes on the basis of the test results. The results showed that the shear strength of the composite beams was affected by the concrete strength of the compressive zone and also proportional to the flexural rigidity of un-cracked sections. Furthermore, the contribution of shear reinforcements varied according to the concrete strength of the compressive zone.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2011.05a
• /
• pp.5-5
• /
• 2011

The research and development of hybrid electric vehicle (HEV), plug-in hybrid electric vehicle (PHEV) and electric vehicle (EV) are intensified due to the energy crisis and environmental concerns. In order to meet the challenging requirements of powering HEV, PHEV and EV, the current lithium battery technology needs to be significantly improved in terms of the cost, safety, power and energy density, as well as the calendar and cycle life. One new technology being developed is the utilization of composite cathode by mixing two different types of insertion compounds [e.g., spinel $LiMn_2O_4$ and layered $LiMO_2$ (M=Ni, Co, and Mn)]. Recently, some studies on mixing two different types of cathode materials to make a composite cathode have been reported, which were aimed at reducing cost and improving self-discharge. Numata et al. reported that when stored in a sealed can together with electrolyte at $80^{\circ}C$ for 10 days, the concentrations of both HF and $Mn^{2+}$ were lower in the can containing $LiMn_2O_4$ blended with $LiNi_{0.8}Co_{0.2}O_2$ than that containing $LiMn_2O_4$ only. That reports clearly showed that this blending technique can prevent the decline in capacity caused by cycling or storage at elevated temperatures. However, not much work has been reported on the charge-discharge characteristics and related structural phase transitions for these composite cathodes. In this presentation, we will report our in situ x-ray diffraction studies on this mixed composite cathode material during charge-discharge cycling. The mixed cathodes were incorporated into in situ XRD cells with a Li foil anode, a Celgard separator, and a 1M $LiPF_6$ electrolyte in a 1 : 1 EC : DMC solvent (LP 30 from EM Industries, Inc.). For in situ XRD cell, Mylar windows were used as has been described in detail elsewhere. All of these in situ XRD spectra were collected on beam line X18A at National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory using two different detectors. One is a conventional scintillation detector with data collection at 0.02 degree in two theta angle for each step. The other is a wide angle position sensitive detector (PSD). The wavelengths used were 1.1950 ${\AA}$ for the scintillation detector and 0.9999 A for the PSD. The newly installed PSD at beam line X18A of NSLS can collect XRD patterns as short as a few minutes covering $90^{\circ}$ of two theta angles simultaneously with good signal to noise ratio. It significantly reduced the data collection time for each scan, giving us a great advantage in studying the phase transition in real time. The two theta angles of all the XRD spectra presented in this paper have been recalculated and converted to corresponding angles for ${\lambda}=1.54\;{\AA}$, which is the wavelength of conventional x-ray tube source with Cu-$k{\alpha}$ radiation, for easy comparison with data in other literatures. The structural changes of the composite cathode made by mixing spinel $LiMn_2O_4$ and layered $Li-Ni_{1/3}Co_{1/3}Mn_{1/3}O_2$ in 1 : 1 wt% in both Li-half and Li-ion cells during charge/discharge are studied by in situ XRD. During the first charge up to ~5.2 V vs. $Li/Li^+$, the in situ XRD spectra for the composite cathode in the Li-half cell track the structural changes of each component. At the early stage of charge, the lithium extraction takes place in the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component only. When the cell voltage reaches at ~4.0 V vs. $Li/Li^+$, lithium extraction from the spinel $LiMn_2O_4$ component starts and becomes the major contributor for the cell capacity due to the higher rate capability of $LiMn_2O_4$. When the voltage passed 4.3 V, the major structural changes are from the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, while the $LiMn_2O_4$ component is almost unchanged. In the Li-ion cell using a MCMB anode and a composite cathode cycled between 2.5 V and 4.2 V, the structural changes are dominated by the spinel $LiMn_2O_4$ component, with much less changes in the layered $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, comparing with the Li-half cell results. These results give us valuable information about the structural changes relating to the contributions of each individual component to the cell capacity at certain charge/discharge state, which are helpful in designing and optimizing the composite cathode using spinel- and layered-type materials for Li-ion battery research. More detailed discussion will be presented at the meeting.

• Journal of the Korean earth science society
• /
• v.38 no.7
• /
• pp.496-510
• /
• 2017

This study presents a new nationwide quantitative precipitation estimation (QPE) based on the hybrid surface rainfall (HSR) technique using the weather radar network of Korea Meteorological Administration (KMA). This new nationwide HSR is characterized by the synthesis of reflectivity at the hybrid surface that is not affected by ground clutter, beam blockage, non-meteorological echoes, and bright band. The nationwide HSR is classified into static (STATIC) and dynamic HSR (DYNAMIC) mosaic depending on employing a quality control process, which is based on the fuzzy logic approach for single-polarization radar and the spatial texture technique for dual-polarization radar. The STATIC and DYNAMIC were evaluated by comparing with official and operational radar rainfall mosaic (MOSAIC) of KMA for 10 rainfall events from May to October 2014. The correlation coefficients within the block region of STATIC, DYNAMIC and MOSAIC are 0.52, 0.78, and 0.69, respectively, and their mean relative errors are 34.08, 30.08, and 40.71%.