• Title/Summary/Keyword: hybrid solar cells

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Configuration and Ground Tests of Solar Cell and Fuel Cell Powered System for Long Endurance UAV (장기체공 무인기용 태양전지-연료전지를 활용한 동력원 구성 및 지상시험)

  • Park, Byeongseob;Kim, Hyuntak;Baek, Seungkwan;Kwon, Sejin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.4
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    • pp.94-101
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    • 2015
  • Each of power systems of solar cell and fuel cell were configured and validated for long endurance UAV, as the preliminary research for the integration of power systems. Solar power system consisted of solar modules fabricated by solar cells of Sunpower's C60, commercial solar MPPT controller and Li-po battery, and then was validated. The re-start characteristics of hydrogen production from $NaBH_4$ hydrolysis was validated for operating the commercial fuel cell. The average voltage drop of Li-po battery in solar power system was -2.9 V/hour. The performance of re-start characteristics of $NaBH_4$ hydrolysis was stable in sequence mode of mission profile. Each of single systems were satisfied for the proposed mission profile.

Synthesis of Amorphous Er3+-Yb3+ Co-doped TiO2 and Its Application as a Scattering Layer for Dye-sensitized Solar Cells

  • Han, Chi-Hwan;Lee, Hak-Soo;Lee, Kyung-Won;Han, Sang-Do;Singh, Ishwar
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.219-223
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    • 2009
  • $TiO_2$ doped with $Er^{3+\;and\;Yb^{3+}$ was used for fabricating a scattering layer and a nano-crystalline $TiO_2$ electrode layer to be used in dye-sensitized solar cells. The material was prepared using a new sol-gel combustion hybrid method with acetylene black as fuel. The $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide powder synthesized at 700oC had embossed structure morphology with a size between 27 to 54 nm that agglomerated to produce micron size particles, as observed by the scanning electron micrographs. The XRD patterns showed that the $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide had an amorphous structure, while using the same method without doping $Er^{3+}\;or\;Yb^{3+},\;TiO_2$ was obtained in the crystallite form with thea dominance of rutile phase. Fabricating a bilayer structure consisting of nano-crystalline $TiO_2$ and the synthesized $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide showed better scattering property, with an overall increase of 15.6% in efficiency of the solar cell with respect to a single nano-crystalline $TiO_2$ layer.

Improvement of Dye-Hydrogel Based Photovoltaics via Hydroquinone Electrolyte Mediators (하이드로퀴논 전해질 중간체에 의한 염료-수화젤 기반 태양전지 효율 향상)

  • KOO, HYUNG-JUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.540-546
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    • 2016
  • Besides high-efficient photovoltaics based on silicon, polymers, dye-sensitization and hybrid perovskite materials, biomimetic solar cells inspired by a leaf in nature has also been actively studied. As one example, a hydrogel based photovoltaics (HGPV) is a low-cost, environmentally friendly device and requires easy fabrication process. In this paper, the effect of hydroquinone additive on the performance of the HGPV is discussed. The photocurrent increases ~14 times upon the addition of hydroquinone into the agarose hydrogel medium. The photocurrent increase is maximum at the optimum dye concentration, while the photovoltage is barely affected by the dye concentration. The effect of the agarose content in the hydrogel and the types of dyes on the photocurrent is also investigated. Finally, it is shown that the photovoltaic performance of HGPV with hydroquinone can be drastically improved when $TiO_2$ film is deposited on the anode electrode.

Analysis of Roof Integrated Photovoltaic Module's Performance with Insulation Hybrid Structure Layer (단열복합 구조에 따른 지붕일체형 태양전지모듈의 성능 분석)

  • Kang, Gi-Hwan;Kim, Hyun-Il;Park, Kyung-Eun;Yu, Gwon-Jong;Yi, So-Mi
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1220-1221
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    • 2007
  • Building-integrated photovoltaic(BIPV) perform traditional architectural function of walls and roof while also generating electricity. But most of the absorbed solar energy appears passively as heat, raising the temperature of cells and reducing the efficiency with which the active part is converted into electricity. Therefore this paper presents the comparison of electrical, architectural and thermal performance of roof integrated photovoltaic(PV) modules, which is composed of different hybrid structure layer such as urethane form, waffle stud etc.

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Slot-die Coating Method for Manufacturing Large-area Perovskite Solar Cell (대면적 페로브스카이트 태양전지 제작을 위한 슬롯-다이코팅 방법)

  • Oh, Ju-young;Ha, Jae-jun;Lee, Dong-geun
    • The Journal of the Korea Contents Association
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    • v.21 no.12
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    • pp.918-925
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    • 2021
  • The perovskite solar cell is a next-generation solar cell that replaces the existing silicon solar cell. It is a solar cell device using an organic-inorganic hybrid material having a perovskite structure as a photoactive layer. It has advantages for the process and has shown rapid efficiency improvement over the past decade. In the process of commercialization of such perovskite solar cells, research and development for a large-area coating method should be carried out. As one of the large-area perovskite solar cell large-area coating methods, the slot-die coating method was studied. By using a meniscus to pass over the substrate and coating the solution, the 3D printer was equipped with a meniscus so that it could be coated. Variables that act during coating include bed temperature, coating speed, N2 blowing interval, N2 blowing height, N2 blowing intensity, etc. By controlling these, the perovskite absorption layer was manufactured and the coating conditions for manufacturing large-area devices were optimized.

Synthesis and Characterization of Thiophene-Based Copolymers Containing Urethane and Alkyl Functional Side Chains for Hybrid Bulk Heterojunction Photovoltaic Cell Applications

  • Im, Min-Joung;Kim, Chul-Hyun;Song, Myung-Kwan;Park, Jin-Su;Lee, Jae-Wook;Gal, Yeong-Soon;Lee, Jun-Hee;Jin, Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.559-565
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    • 2011
  • The following noble series of statistical copolymers, poly[(2-(3-thienyl)ethanol n-butoxycarbonylmethylurethane)-co-3-hexylthiophene] (PURET-co-P3HT), were synthesized by the chemical dehydrogenation method using anhydrous $FeCl_3$. The structure and electro-optical properties of these copolymers were characterized using $^1H$-NMR, UV-visible spectroscopy, elemental analysis, GPC, DSC, TGA, photoluminescence (PL), and cyclic voltammetry (CV). The statistical copolymers, PURET-co-P3HT (1:0, 2:1, 1:1, 1:2, 1:3), were soluble in common organic solvents and easily spin coated onto indium-tin oxide (ITO) coated glass substrates. Hybrid bulk heterojunction photovoltaic cells with an ITO/G-PEDOT/PURET-co-P3HT:PCBM:Ag nanowires/$TiO_x$/Al configuration were fabricated, and the photovoltaic cells using PURET-co-P3HT (1:2) showed the best photovoltaic performance compared with those using PURET-co-P3HT (1:0, 2:1, 1:1, 1:3). The optimal hybrid bulk heterojunction photovoltaic cell exhibits a power conversion efficiency (PCE) of 1.58% ($V_{oc}$ = 0.82 V, $J_{sc}$ = 5.58, FF = 0.35) with PURET-co-P3HT (1:2) measured by using an AM 1.5 G irradiation (100 mW/$cm^2$) on an Oriel Xenon solar simulator (Oriel 300 W).

Improved performance in flexible organic solar cells via optimization of highly transparent silver grid/graphene electrodes

  • Cha, Myoung Joo;Kim, Sung Man;Kang, Ju Hwan;Kang, Seong Jun;Seo, Jung Hwa;Walker, Bright
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.152-152
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    • 2016
  • We studied the effect of the silver grid size on graphene transparent conducting films for flexible organic solar cells (OSCs). The silver grid was used an assistant layer of the graphene to reduce the sheet resistance of substrates. Silver grid with various graphene sizes for optimizing transmittance and sheet resistance of substrates were fabricated on polyethylene terephthalate (PET) substrates to form the hybrid films. The optimized grid geometry on the single layer graphene (SLG) was the grid dimension $200{\mu}m{\times}200{\mu}m{\times}50nm{\times}2{\mu}m$ (length ${\times}$ width ${\times}$ height ${\times}$ linewidth), where the sheet resistance was $55.73{\Omega}/square$ with the average transmittance of ~ 92.83 % at 550 nm. The properties of the OSCs fabricated using SLG with optimized silver grids on PET substrates show a short circuit current of $10.9mA/cm^2$, an open circuit voltage of 0.58 V, a fill factor of 60.8 %, and a power conversion efficiency (PCE) of 3.9 %. The PCE was improved about 91% than that of the OSCs using the SLG without the silver grid. These results demonstrate that the optimized grid geometry to the based on the graphene transparent electrodes contribute to improving the performance of OSCs.

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A Study on Optimization of Perovskite Solar Cell Light Absorption Layer Thin Film Based on Machine Learning (머신러닝 기반 페로브스카이트 태양전지 광흡수층 박막 최적화를 위한 연구)

  • Ha, Jae-jun;Lee, Jun-hyuk;Oh, Ju-young;Lee, Dong-geun
    • The Journal of the Korea Contents Association
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    • v.22 no.7
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    • pp.55-62
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    • 2022
  • The perovskite solar cell is an active part of research in renewable energy fields such as solar energy, wind, hydroelectric power, marine energy, bioenergy, and hydrogen energy to replace fossil fuels such as oil, coal, and natural gas, which will gradually disappear as power demand increases due to the increase in use of the Internet of Things and Virtual environments due to the 4th industrial revolution. The perovskite solar cell is a solar cell device using an organic-inorganic hybrid material having a perovskite structure, and has advantages of replacing existing silicon solar cells with high efficiency, low cost solutions, and low temperature processes. In order to optimize the light absorption layer thin film predicted by the existing empirical method, reliability must be verified through device characteristics evaluation. However, since it costs a lot to evaluate the characteristics of the light-absorbing layer thin film device, the number of tests is limited. In order to solve this problem, the development and applicability of a clear and valid model using machine learning or artificial intelligence model as an auxiliary means for optimizing the light absorption layer thin film are considered infinite. In this study, to estimate the light absorption layer thin-film optimization of perovskite solar cells, the regression models of the support vector machine's linear kernel, R.B.F kernel, polynomial kernel, and sigmoid kernel were compared to verify the accuracy difference for each kernel function.

Power Enhance Effect on the Hybrid Cell Based on Direct Current Nanogenerator and an Organic Photovoltaic Device

  • Yun, Gyu-Cheol;Sin, Gyeong-Sik;Lee, Geun-Yeong;Lee, Ju-Hyeok;Kim, Sang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.298-298
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    • 2013
  • Finding renewable and clean energy resources is essential research to solve global warming and depletion of fossil fuels in modern society. Recently, complex harvesting of energy from multiple sources is available in our living environments using a single device has become highly desirable, representing a new trend in energy technologies. We report that when simultaneously driving the fusion and composite cells of two or more types, it is possible to make an affect the other cells to obtain a greater synergistic effect. To understand the coupling effect of photovoltaic and piezoelectric device, we fabricate the serially integrated hybrid cell (s-HC) based on organic solar cell (OSC) and piezoelectric nanogenerator (PNG). The size of increased voltage peaks when OSC and PNG are working on is larger than the case when only PNG is working. This voltage difference is the Voc change of OSC, not the voltage change of PNG and current density difference between these two cases is manifested more clearly. When the OSC and PNG are working in s-HC at the same time, piezoelectric potential (VPNG) is generated in ZnO and theoretical total voltage is sum of voltage of an OSC (VOSC) and VPNG. However, electrons from OSC are influenced by piezoelectric potential in ZnO and current loss of OSC in whole circuit decreases. As a result, VOSC increases temporarily. Current shows the similar behavior. PNG acts a resistance in the whole circuit and current loss occurs when the electrons from OSC pass through the PNG. But piezoelectric potential recover current loss and decrease the resistance of PNG. Our PNG can maintain piezoelectric potential when the strain is held owing to the LDH layer while general PNG cannot maintain piezoelectric potential. During the section that strain is held, voltage enhancement effect is maintained and same effect appeared even turn off the light. Actually at this time, electrons in ZnO nanosheets move to LDH and trapped by the positive charges in this layer. After this strain is held, piezoelectric potential of ZnO nanosheets is disappeared but potential difference which is developed by negative charge dominant LDH layer is remained. This potential acts similar role like piezoelectric potential in ZnO. Electrons from the OSC also are influenced by this potential and the more current flows.

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A Study on Optimum Takeoff Time of the Hybrid Electric Powered Systems for a Middle Size UAV (중형무인기용 하이브리드 전기동력시스템의 최적 이륙시간에 관한 연구)

  • Lee, Bohwa;Park, Poomin;Kim, Keunbae;Cha, Bongjun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.11
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    • pp.940-947
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    • 2012
  • The target system is a middle size UAV, which is a low-speed long-endurance UAV with a weight of 18 kg and wingspan of 6.4 m. Three electric power sources, i.e. solar cells, a fuel cell, and a battery, are considered. The optimal takeoff time is determined to maximize the endurance because the generated solar cell's energy is heavily dependent on it. Each power source is modeled in Matlab/Simulink, and the component models are verified with the component test data. The component models are integrated into a power system which is used for power simulations. When takeoff time is at 6 pm and 2 am, it can supply the power during 37.5 hrs and 27.6 hrs, respectively. In addition, the thermostat control simulation for fuel cell demonstrates that it yields more power supply and efficient power distribution.