• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.641-646
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• 2012

We used the hybrid density-functional (B3LYP/6-31G(d,p)) method to analyze the substitution patterns of $C_{20}H_{18}X_2$ derivatives (X = F, Cl, Br, or OH) obtained as disubstituted $C_{20}H_{20}$ cages. Our results suggest that the cis-1 regioisomers (1,2-dihalo derivatives) are less stable than the trans-1 regioisomers (1,20-dihalo derivatives), whereas in the case of the dihydroxy derivatives, the cis-1 regioisomer is more stable than the trans-1 regioisomer. This implies that in the dihalo-induced strain cages of $C_{20}H_{18}X_2$, the strain effect would affect the relative energies, while in the dihydroxide, the hydrogen bonds have a stronger effect on the relative energies in cis-1 regioisomer than the strain effect do. Thus this supports the experimental result in which the bisvicinal tetrol was of particular preparative-synthetic interest as a substitute for the lacking bisvicinal tetrabromide. Further, the topologies of the HOMO and LUMO characteristics of all $C_{20}H_{18}Cl_2$ and $C_{20}H_{18}Br_2$ regioisomers with the same symmetry are same, but they are different from those of $C_{20}H_{18}F_2$ and $C_{20}H_{18}(OH)_2$. This indicates that the five regioisomers of each $C_{20}H_{20}$ disubstituted derivative will have an entirely different set of characteristic chemical reactions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.11-19
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• 2015

We present the results of a multi-material numerical investigation of the propagation of a combustible gas mixture detonation in narrow metal tubes. We use an experimentally tuned one step Arrhenius chemical reaction and ideal gas equation of state (EOS) to describe stoichiometric $H_2-O_2$ and $C_2H_4-O_2$ detonations. The purely plastic deformations of copper and steel tubes are modeled using the Mie-Gruneisen EOS and Johnson-Cook strength model. To precisely track the interface motion between the detonating gas and the deforming wall, we use the hybrid particle level-sets within the ghost fluid framework. The calculated results are validated against the experimental data because the results explain the process of the generation and subsequent interaction of the expansion wave with the high-strain-rate deformation of the walls.

• Progress in Superconductivity and Cryogenics
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• v.13 no.1
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• pp.31-35
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• 2011

A Hybrid Fault Current Limiter(FCL) which has more advantages in fast response and thermal characteristics than a simple resistive FCL had been proposed by our group. The Hybrid FCL consists of a resistive FCL for the magnitude of the first peak of fault current, and a fast switch for detecting fault current and generating the repulsive force within a cycle in fault situation. In ideal case, the impedance of the fast switch wound with two other kinds of HTS tape is negligibly zero in normal operation. But, during the fault situation, each HTS tape has different quench characteristics because of asymmetric current distribution. And this phenomenon causes effective flux and this flux opens the switch through the repulsive force applied to a metal plate of the fast switch. The magnitude of the repulsive force affects the switching characteristics of the fast switch. It should be large enough to raise the metal plate up. Otherwise the arc re-out break which are caused by not enough repulsive force to raise the metal plate up can cause unintended operation of the fast switch. In this paper, the numerical calculation of the repulsive force applied to the metal plate of the fast switch in various combinations of HTS tapes was performed by using the short-circuit test and finite element method.

• Journal of KIISE
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• v.41 no.10
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• pp.838-846
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• 2014

Three-dimensional (3D) object retrieval from user-drawn sketch queries is one of the important research issues in the areas of pattern recognition and computer graphics for simulation, visualization, and Computer Aided Design. The performance of content-based 3D object retrieval system depends on the availability of effective descriptors and similarity measures for this kind of data. In this paper, we present a sketch-based 3D object retrieval system by extracting a hybrid edge descriptor which is robust against rotation and translation. The experimental results which are based on HTML5 and WebGL show that proposed sketch-based 3D object retrieval method is very efficient to search and order the 3D objects according to user's intention.

• Structural Monitoring and Maintenance
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• v.5 no.2
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• pp.205-229
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• 2018

Energy induced by minor earthquake and micro vibration cannot be dissipated by traditional buckling-restrained braces (BRBs). To solve this problem, a new type of hybrid passive control device, named as VE-BRB, which is configured by a BRB with high-damping viscoelastic (VE) layers, is developed and studied. Theoretical analysis, performance tests, numerical simulation and case analysis are conducted to study the seismic behavior of VE-BRBs. The results indicate that the combination of hysteretic and damping devices lead to a multi-phased nature and good performance. VE-BRB's working state can be divided into three phases: before yielding of the steel core, VE layers provide sufficient damping ratio to mitigate minor vibrations; after yielding of the steel core, the steel's hysteretic deformations provide supplemental dissipative capacity for structures; after rupture of the steel core, VE layers are still able to work normally and provide multiple security assurance for structures. The simulation results agreed well with the experimental results, validating the finite element analysis method, constitutive models and the identified parameters. The comparison of the time history analysis on a 6-story frame with VE-BRBs and BRBs verified the advantages of VE-BRB for seismic protection of structures compared with traditional BRB. In general, VE-BRB had the potential to provide better control effect on structural displacement and shear in all stages than BRB as expected.

• The KIPS Transactions:PartD
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• v.19D no.2
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• pp.151-160
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• 2012

Most of the distributed high-dimensional indexing structures provide a reasonable search performance especially when the dataset is uniformly distributed. However, in case when the dataset is clustered or skewed, the search performances gradually degrade as compared with the uniformly distributed dataset. We propose a method of improving the k-nearest neighbor search performance for the distributed vector approximation-tree based on the strongly clustered or skewed dataset. The basic idea is to compute volumes of the leaf nodes on the top-tree of a distributed vector approximation-tree and to assign different number of bits to them in order to assure an identification performance of vector approximation. In other words, it can be done by assigning more bits to the high-density clusters. We conducted experiments to compare the search performance with the distributed hybrid spill-tree and distributed vector approximation-tree by using the synthetic and real data sets. The experimental results show that our proposed scheme provides consistent results with significant performance improvements of the distributed vector approximation-tree for strongly clustered or skewed datasets.

• Journal of the Institute of Electronics Engineers of Korea SP
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• v.48 no.2
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• pp.125-133
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• 2011

For any pattern matching based algorithm in WLAN environment, the characteristics of signal to noise ratio(SNR) to multiple access points(APs) are utilized to establish database in the training phase, and in the estimation phase, the actual two dimensional coordinates of mobile unit(MU) are estimated based on the comparison between the new recorded SNR and fingerprints stored in database. As fingerprinting method, k-nearest neighbor(KNN) has been widely applied for indoor location in wireless location area networks(WLAN), but its performance is sensitive to number of neighbors k and positions of reference points(RPs). So intuitive fuzzy c-means(IFCM) clustering algorithm is applied to improve KNN, which is the KNN/IFCM hybrid algorithm presented in this paper. In the proposed algorithm, through KNN, k RPs are firstly chosen as the data samples of IFCM based on signal to noise ratio(SNR). Then, the k RPs are classified into different clusters through IFCM based on SNR. Experimental results indicate that the proposed KNN/IFCM hybrid algorithm generally outperforms KNN, KNN/FCM, KNN/PFCM algorithm when the locations error is less than 2m.

• Asian-Australasian Journal of Animal Sciences
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• v.19 no.2
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• pp.165-170
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• 2006

Using the somatic cell hybrid panel (SCHP) and radiation hybrid (IMpRH) panel, porcine SOCS2 gene was mapped at SSC5 (1/2) q21-q24 and closely linked with SW1383 marker (47 cR in distance), while SOCS3 gene was assigned to SSC12p11-(2/3p13) and closely linked with SW2490 (43 cR). The reverse transcriptase-polymerase chain reaction (RT-PCR) was performed to detect the expression of these two genes in the different tissues and the results showed that both SOCS2 and SOCS3 genes were widely expressed in tissues investigated (heart, liver, spleen, lung, kidney skeletal muscle, fat and brain), although some tissues showed lower gene expression. Moreover, SOCS2 and SOCS3 genes had different expression levels at different stages, in different tissues and in different breeds. A G/A substitution, which can be recognized by restriction enzyme of Cfr421, was observed in 5' untranslated region (5'-UTR) of SOCS2 gene. The allele frequencies was investigated by PCR-restriction fragment length polymorphism (PCR-RFLP) method and it showed that the allele frequency among Dahuabai, Erhualian, Yushan, Qingping, Large white and Landrace tested were different. Association analysis in a cross experimental populations revealed no significant association between the SOCS2 gene polymorphism and the economic traits investigated. The full-length coding regions (CDs) of porcine SOCS3 gene was obtained by RT-PCR.

• The Transactions of the Korean Institute of Power Electronics
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• v.15 no.5
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• pp.369-375
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• 2010

This paper presents a design and implementation of 3.3 kW on-board battery charger for electric vehicles or plug-in hybrid electric vehicles. Considering characteristics of the electric vehicles, a series-loaded resonant dc-dc converter and frequency control scheme are adopted to improve efficiency and reliability, and to reduce volume and cost. The developed on-board battery charger is designed and implemented by using high frequency of 80-130 kHz and zero voltage switching method. The experimental result indicates 92.5% of the maximum efficiency, 5.84 liters in volume, and 5.8kg in weight through optimal hardware design.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.158-158
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• 2012

A new kind of organic-inorganic hybrid polymer, poly(tetraphenyl)silole siloxane (PSS), was invented and synthesized for realization of its unique charge trap properties. The organic portions consisting of (tetraphenyl)silole rings are responsible for electron trapping owing to their low-lying LUMO, while the Si-O-Si inorganic linkages of high HOMO-LUMO gap provide the intrachain energy barrier for controlling electron transport. Such an alternation of the organic and inorganic moieties in a polymer may give an interesting quantum well electronic structure in a molecule. The PSS thin film was fabricated by spin-coating of the PSS solution in THF organic solvent onto Si-wafer substrates and curing. The electron trapping of the PSS thin films was confirmed by the capacitance-voltage (C-V) measurements performed within the metal-insulator-semiconductor (MIS) device structure. And the quantum well electronic structure of the PSS thin film, which was thought to be the origin of the electron trapping, was investigated by a combination of theoretical and experimental methods: density functional theory (DFT) calculations in Gaussian03 package and spectroscopic techniques such as near edge X-ray absorption fine structure spectroscopy (NEXAFS) and photoemission spectroscopy (PES). The electron trapping properties of the PSS thin film of quantum well structure are closely related to intra- and inter-polymer chain electron transports. Among them, the intra-chain electron transport was theoretically studied using the Atomistix Toolkit (ATK) software based on the non-equilibrium Green's function (NEGF) method in conjunction with the DFT.