• 제목/요약/키워드: hot pressed

검색결과 260건 처리시간 0.029초

Skutterudite CoSb3의 합성 및 열전특성 (Synthesis and Thermoelectric Properties of Skutterudite CoSb3)

  • 김일호;유신욱;박종범;이정일;어순철;장경욱;최국선;김준수;김현주
    • 한국재료학회지
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    • 제15권10호
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    • pp.667-670
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    • 2005
  • Binary skutterudite $CoSb_3$ compounds were prepared by the arc melting and hot pressing processes and their thermoelectric properties were investigated in the range from 300 to 600 K. Annealing effect was correlated to phase transformation and homogenization. Thermoelectric properties of the arc-melted and hot-pressed $CoSb_3$ were discussed and compared. Undoped intrinsic $CoSb_3$ prepared by the arc melting showed p-type conduction, while it showed metallic behavior with increasing measuring temperature. However, hot pressed specimens showed n-type conduction, possibly due to Sb evaporation. Thermoelectric properties were remarkably improved by annealing In vacuum and they were closely related to phase transformation.

소결분위기 제어에 의한 Al2O3/Fe-Ni 나노복합재료의 제조 및 특성 (Fabrication of Al2O3/Fe-Ni Nanocomposites by Atmosphere-controlled Sintering and their Properties)

  • 이홍재;정영근;오승탁;이재성
    • 한국세라믹학회지
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    • 제39권2호
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    • pp.199-203
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    • 2002
  • 소결 분위기가 금속입자분산 세라믹스기 복합체의 미세 조직 및 물성에 미치는 영향에 대하여 조사하고자 화학적 방법으로 합성한 $Al_2O_3$/Fe-Ni 나노복합분말을 수소 및 아르곤 가스 분위기, 또한 소결온도 등으로 제어하여 열간가압 소결하였다. 수소분위기에서 소결한 복합체는 아르곤분위기의 경우보다 반응상 $FeAl_2O_4$의 형성이 억제되었으며, 증가된 파괴강도 및 인성 값을 나타내었다. 또한, 소결 온도를 낮추었을 경우 기지상 및 금속 분산상의 미세화와 향상된 기계적 성질을 얻을 수 있었다. 소결 조건에 따른 기계적 특성의 변화는 주로 반응상의 형성과 관련된 미세조직 특성에 의존하는 것으로 해석하였다.

TEOS와 카올린으로부터 제조한 $\beta$-Sialon의 기계적 성질 (Mechanical Properties of Beta-Sialon Ceramics Prepared from TEOS and Kaolin)

  • 임헌진;이홍림
    • 한국세라믹학회지
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    • 제26권5호
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    • pp.637-644
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    • 1989
  • Beta-sialon powder(Z=1) was synthesized by the simultaeous reduction and nitridation of the mixed powders of Hadong kaolin and silica. Silicon hydroxide was prepared from Si-alkoxide by a hydrolysis method and amorphous silica was obtained from the calcination of the prepared silicon hydroxide. Hadong kaolin was mixed with both the silicon hydroxide and amorphous silica, respectively. The average particle size was 4${\mu}{\textrm}{m}$ and the morphology of particle was rod-like and equiaxed in the case of beta-sialon powder prepared form Hadong kaolin and silicon hydroxide(COMPOSITION A), whereas the average particle size was 3${\mu}{\textrm}{m}$ and the morphology of particle was equiaxed in the case of beta-sialon powder prepared from Hadong kaolin and amorphous silica(COMPOSITION B). The synthesized beta-sialon powders were hot-pressed at 175$0^{\circ}C$ for 2 hours under 30 MPa in a nitrogen atmosphere after YAG composition(8wt%) was added to these powders as a sintering agent. The hot-pressed specimens were annealed a 140$0^{\circ}C$ for 4 hours in a nitrogen atmosphere. The mechanical properties of sintered bodies were investigated in terms of M.O.R., fracture toughness and hardness. The measured values are as follows. COMPOSITION A : M.O.R. 508MPa, KIC 3.5MN/m3/2, hardness 13.6GPa. COMPOSITION B : M.O.R. 653MPa, KIC 5.4MN/m3/2, hardness 13.5GPa.

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