• 제목/요약/키워드: homogenous

검색결과 492건 처리시간 0.033초

Development of Titanium Dioxide (TiO2)-immobilized Buoyant Photocatalyst Balls Using Expanded Polystyrene (EPS)

  • Joo, Jin Chul;Lee, Saeromi;Ahn, Chang Hyuk;Lee, Inju;Liu, Zihan;Park, Jae-Roh
    • Ecology and Resilient Infrastructure
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    • 제3권4호
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    • pp.215-220
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    • 2016
  • A new immobilization technique of nanoscale $TiO_2$ powder to expanded polystyrene (EPS) balls with temperature-controlled melting method was developed, and the photocatalytic activity of $TiO_2$ powder-embedded EPS balls were evaluated using methylene blue (MB) solution under ultraviolet irradiation (${\lambda}=254nm$). Based on the scanning electron microscope (SEM) images and associated energy-dispersive X-ray spectroscopy (EDX) analysis, the components of the intact EPS balls were mainly carbon and oxygen, whereas those of $TiO_2$-immobilized EPS balls were carbon, oxygen, and titanium, indicating that relatively homogenous patches of $TiO_2$ and glycerin film were coated on the surface of EPS balls. Based on the comparison of degradation efficiencies of MB between intact and $TiO_2$-immobilized EPS balls under UVC illumination, the degradation efficiencies of MB can be significantly improved using $TiO_2$-immobilized EPS balls, and surface reactions in heterogeneous photocatalysis were more dominant than photo-induced radical reactions in aqueous solutions. Thus, $TiO_2$-immobilized EPS balls were found to be an effective photocatalyst for photodegradation of organic compounds in aqueous solutions without further processes (i.e., separation, recycling, and regeneration of $TiO_2$ powder). Further study is in progress to evaluate the feasibility for usage of buoyant $TiO_2$-immobilized EPS to inhibit the excessive growth of algae in rivers and lakes.

Comparative Ultrastructure of Secretory Granules of the Submandibular Gland in the Korean Spider Shrew, Sorex caecutiens, the Lesser White-toothed Shrew, Crocidura suaveolens and the Big White-toothed Shrew, Crocidura lasiura

  • Jeong, Soon-Jeong;Bae, Chun Sik;Lee, Hye-Yon;Choi, Baik-Dong;Yoon, Myung-Hee;Jeong, Moon-Jin
    • Applied Microscopy
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    • 제42권4호
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    • pp.186-193
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    • 2012
  • The ultrastructure of the secretory granules of the submandibular gland was examined in the Korean spider shrew, Sorex caecutiens, lesser white-toothed shrew, Crocidura suaveolens and big white-toothed shrew, C. lasiura. The mucous and serous acinar granules of S. caecutiens with a border of the lucid corona differed from those of C. suaveolens and C. lasiurar with a dense lateral border. The mucous acinar granules of C. lasiura with several bands producing a variety of patterns in the matrix were similar to those of C. suaveolens. The serous acinar granules of C. lasiura had a homogenous pale center surrounded by minute dense specks or had an unusual substructure showing a geometric pattern according to the inclusions in the pale matrix of the granules. This is the first report of an unusual substructure showing a geometric pattern of the serous acinar granules of C. lasiura. The myelin-like body was observed in the granular duct cell of the three species of shrew. The myelin-like body of S. caecutiens with layers of unit membranes was different from that of C. suaveolens and C. lasiura with paired membranes. Therefore, the layers composing of the paired membranes of the myelin-like body might be one of the characteristics of Crocidura.

한반도 서해 태안반도 연근해 부유퇴적물의 기초 해양환경적 특성 (Basic Marine Environmental Characteristics of Suspended Sediments in the Inner Shelf Zone off Tae-An Peninsula, West Coast of Korea)

  • 최진용;박용안
    • 한국해양학회지:바다
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    • 제1권1호
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    • pp.46-54
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    • 1996
  • 한반도 서해 태안반도 연근 해역에서 춘계동안 부유물 함량분포경향을 분석 하여, 부유물질의 운반 양상을 해석하였다. 특히 비파괴 방식의 SPECTREX 분석 기기를 이용하여 부유물의 입도분포를 정밀 분석하였다. 연구해역의 수괴 특성은 강한 조석전선이 형성되어, 수직적으로 균질한 수괴의 연안역과 수온약층이 뚜렷한 외양역으로 구분되었다. 부유물 함량은 대체로 10 mg/l 이하로 낮지만, 연안역의 저층수와 외양역의 중층수에서는 혼탁한 수괴가 관측되었다. 부유물은 평균입도가 각각 5-6$\mu\textrm{m}$와 8-10$\mu\textrm{m}$에 해당하는 세립질 부유물과 조립질 부유물로 구분되며, 주로 쇄설성 성분이 우세한 것으로 해석되었다. 전반적으로 태안반도 연근해역에서는 강 한 조류에 의해 해저 퇴적물의 재부유작용이 우세하며, 세립 퇴적물의 집적이 제한 되는 것으로 해석된다. 또한 경기만의 초입에 해당하는 북부역으로부터 공급되는 쇄설성 부유 퇴적물이 수온약층의 중층수역을 따라 남쪽 또는 남서쪽 방향으로 우 세하게 운반되는 것으로 해석된다.

비정상적 위치에서 발생한 외엽형 및 내엽형 폐 격절증 - 2예 보고 - (Pulmonary Sequestration of Unusual Location, Extralobar and intralobar Type -Report of two cases -)

  • 박해문
    • Journal of Chest Surgery
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    • 제22권2호
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    • pp.308-314
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    • 1989
  • Pulmonary sequestration is a congenital malformation characterized by an area of embryonic lung tissue that derives its blood supply from an anomalous systemic artery. Two forms recognized: extralobar and intralobar. Extralobar form is a very rare congenital malformation, usually located in the lower chest, and may be found in newborn infants at the time a congenital diaphragmatic hernia is repaired. Large sequestrated segments may be cause acute respiratory distress in the neonate. The condition is asymptomatic in 15 per cent of patients. This report presents two cases of pulmonary sequestration which misdiagnosed a superior mediastinal tumor and a benign lung tumor. First case was 30-year-old male patient and chief complaints were dyspnea, dry cough and right chest pain. Chest X-ray showed a homogenous increased density of smooth margin at the right superior mediastinal area and suggested a benign mediastinal tumor. And so explothoracotomy was made without other special studies. Second case was 28-year-old male patient. One month ago, he had tracheostomy and right closed thoracostomy due to massive hemoptysis and spontaneous hemothorax. Chest X-ray showed a benign cystic lesion at RLL area. At the time of operation, in first case, a mass of adult fist size was placed medial to the right upper lobe and densely adhesive to trachea, SVC and esophagus. Blood supply of the mass was bronchial arteries of trachea and RUL bronchus and drained to SVC and azygos vein through anomalous systemic veins. There was no bronchial communication on Frozen biopsy. In 2nd case, large cystic lesion contained old blood hematoma was located in RLL and anomalous blood vessel from thoracic aorta was drained to posterior segment of RLL. In operation field, intralobar pulmonary sequestration was diagnosed, and RLL lobectomy was carried out.

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Chiral Mesoporous Silica for Asymmetric Metal-free Catalysis: Enhancement of Chirality thorough Confinement Space by Plug Effect

  • 정은영;임청래;박상언
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.199-199
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    • 2011
  • The addition of a carbanion to ${\yen}{\acute{a}}{\yen}{\hat{a}}$-unsaturated carbonyl compounds is of importance in the C-C bond formation reactions for modern pharmaceuticals and organic synthesis. Recently, heterogeneous asymmetric catalysis became more attractive area of research because of the easy recovery and separation of the catalyst from the reaction system. Most of synthetic methods for heterogeneous catalysts were grafting or immobilization of homogeneous catalyst onto the solid supports. Trans-1,2-Diaminocyclohexane(DACH) and L-proline ligands have been enormously used as chiral ligands in several catalytic transformation under homogenous conditions. Our group prepared l-proline functionalized mesoporous silica was synthesized under acidic condition using a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer template (EO20PO70EO20, Pluronic P-123, BASF). Furthermore, we successfully directly synthesized trans-1,2 diaminocyclohexane functionalized mesoporous silica by using microwave method. The direct functionalization of chiral ligand into the framework of mesoporous materials is expected to be useful for the heterogeneous asymmetric catalysis. So, we adopt the direct synthesis of chiral ligand functionalized mesoporous silica by using thermal and microwave irradiation. Then, chiral ligand functionalized mesoporous silicas were applied to enantioselective asymmetric catalytic reactions.

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Cats Cloned from Fetal Fibroblast Cells by Nuclear Transfer

  • Yin, X.J.;Lee, H.S.;Lee, Y.H.;Hwang, W.S.;Kong, I.K.
    • 한국수정란이식학회:학술대회논문집
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    • 한국수정란이식학회 2004년도 제4회 발생공학 국제심포지움 및 학술대회
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    • pp.26-31
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    • 2004
  • This work was undertaken in order to study the developmental competence of nuclear transfer cat embryo with fetal fibroblast and adult skin fibroblast as donor nuclei. Oocytes wererecovered by mincing the ovaries in Hepes-buffered TCM199 and selected the cumulus oocyte complexes (COCs) with compact cumulus cell mass and dark. Homogenous ooplasm were cultured for maturation in TCM199 + 10% fetal bovine serum (FBS) for 12 hours and used as a source of recipient cytoplast for exogenous somatic nuclei. In Experiment 1, we evaluated the effect donor cell types on the reconstruction and development of cloned embryos. Fusion, first cleavage and blastocyst developmental rate was not different between fetal fibroblast and adult skin cell (71.2 vs. 66.8; 71.0 vs. 57.6; 4.0 vs. 6.1 %, P<0.05). In Experiment 2, cloned embryos were surgically transferred into the oviducts of recipient queens. One of seven recipient queens was delivered naturally 2healthy cloned cats and 1 stillborn from fetal fibroblast cell of male origin after 65 days embryo transfer. One of three recipient queens was delivered naturally 1 healthy cloned cat from adult skin cell of female after 65 days embryo transfer. The cloned cats showed genotypes identical to the donor cell lines, indicating that adult somatic cells can be used for feline cloning.

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치성상피종양으로부터 상악에 발생한 치성유령세포암종의 치험례 (ODONTOGENIC GHOST CELL CARCINOMA ARISING FROM ODONTOGENIC EPITHELIAL TUMOR IN MAXILLA - A CASE REPORT)

  • 김진학;김문기;차인호;김진;김현실;최희수;김형준
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제30권3호
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    • pp.218-222
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    • 2004
  • 치성유령세포암종은 석회화치성낭종의 악성 부분으로 치성낭종, 치성종양 모두에서 기인할 수 있다. 다형성 상피 세포와 유령세포가 nucleated cell들과 혼재된 침윤성 종양의 형태로 나타나는 것이 특징이고, 국소 재발 및 원격 전이된 증례도 보고된 바있다. 저자들은 드문 치성종양인 치성유령세포암종을 상악골에서 경험하였기에 문헌 고찰과 함께 보고하였으며, 본 증례의 경우 향후 재발 및 전이 여부 파악을 위해 주기적인 경과 관찰이 필요하리라 사료된다. 또한 악성 변화의 요인으로 이종골 이식의 영향에 대한 연구도 필요하리라 사료된다.

옴개구리 Rana rugosa 위점막의 위장관 내분비세포에 관한 전자현미경적 연구 (The Ultrastructure of the Gastro-endocrine Cells in the Gastric Mucosa of the Frog, Rana rugosa)

  • 이형식;이재현
    • 한국동물학회지
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    • 제33권1호
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    • pp.22-27
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    • 1990
  • 본 연구는 옴개구리의 위저부 점막을 전자현미경으로 관찰한 결과, 내분비세포의 분비 과립의 크기, 형태, 전자밀도 및 세포의 형태에 따라서 다음과 같이 3종류의 세포를 분류하였다. 제 I 형 : 전자밀도가 높고 원형 또는 난원혀으이 과립을 가지며, 과립내용물과 한계막 사이의 편제하거나 공포상으로 출현하였다. 과립의 크기는 직경이 300-500nm였다. 제 II 형 : 구형 또는 난원형의 과립을 가지며, 전자밀도는 낮거나 높게 나타나며, 한계막과 과립내용물 사이에는 좁은 halo를 나타내었다. 과립의 크리는 직경이 110-230nm였다. 제 III 형 : 신장된 난원형 또는 다형태성의 과립을 가지며, 전자밀도는 낮거나 중등도이며 과림가 내용물 사이에는 명확한 halo를 형성하고 세포질내에는 미세섬유들이 풍부하게 출현하였다. 과립의 크기는 직경이 50-200nm였다.

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Diethylnitrosamine을 투여한 rat 간장의 tumorigenesis에 관하여 3. 간장조직의 전자현미경적 관찰 (Diethylnitrosamine-induced hepatic tumorigenesis in rats 3. Electron microscopic observation of liver tissue)

  • 곽수동;김종섭;고필옥;양재훈;서득록
    • 대한수의학회지
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    • 제39권6호
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    • pp.1057-1065
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    • 1999
  • The study was designated to investigate the electron microscopic findings following diethylnitrosamine (DEN) treatment in rats. Forty four male (Srague Dawley) rats were continuously given water containing 0.01% DEN for 13 weeks and livers of five rats with more tumor lesions at 16 and 17 weeks after initial treatment were used as EM materials. In transmission electron microscopic findings, most small-sized hepatocytes were active cells containing large mount of organelles, but light (pale staining) hepatocytes among small-sized hepatocytes were injured cells containg disorganized organelles. Tumor cells among small-sized hepatocytes were irregularly arranged and have pleomorphic nuclei containing electron dense chromatin but the organelles in cytoplasm were swelled. Large-sized hepatocytes were active cells with condensed chromatin but the cytoplasm of these cells were pale due to be injured and dilated organelles. Dark hepatocytes were apoptotic cells with homogenous pyknotic nuclei and cytoplasm, and the cytoplasm of these cells contained dilated smooth endoplasmic reticulum (sER) but these sER were non-vesiculated. Cholangiocarninoma cells were crowded and were pale by far less number of organelles in cytoplasm and nuclei. In scanning electron microscopic findings, the lumens of portal veins, bile canaliculi, bile ductules, bile ducts and sinusoids were dilated and have irregular folded inner surface by protruded parenchyma.

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반응고법에 의한 금속복합재료의 제조 및 성형 시스템의 개발 (Fabrication of Metal Matrix Composites and Development of Forming System in Mashy State)

  • 강충길;김현우;김영도
    • 대한기계학회논문집
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    • 제14권3호
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    • pp.581-593
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    • 1990
  • 본 연구에서는 교반기술에 의하여 얻어진 반응고상태의 금속에 단섬유를 첨가 하여 복합재료를 제조하였다. 그리고 제조되어진 복합재료에 있어서 섬유의 분산상 태및 기지재와의 접합관계를 조사하여 압연가공에 필요한 반응고상태인 금속복합재료 의 제조방법을 확립하였다. 균일하게 분실되어진 반용융상태의 단섬유강화형 금속복 합재료를 직접 압연하여 박판을 제조할 수 있는 가능성을 검토하였으며, 또한 제조되 어진 박판의 인장시험에 의하여 기계적 성질을 조사하였다.