• Membrane Journal
• /
• v.15 no.2
• /
• pp.147-156
• /
• 2005

It is well-known that polyethersulfone (PES) has high $CO_2$ selectivity over $N_2\;(or\;CH_4)$ and excellent pressure resistance of $CO_2$ plasticization among muy commercialized engineering plastics[1-4]. Asymmetric PES hollow fiber membranes for flue gas separation were developed by dry-wet spinning technique. The dope solution consists of PES, NMP and acetone. Water and water/NMP mixtures are used in outer and inner coagulants, respectively. Gas permeation rate (i.e., permeance) and $CO_2/N_2$ selectivity were measured with pure gas, respectively and the micro-structure of hollow fiber membranes was characterized by scanning electron microscopy. The effects of polymer concentration, ratio of NMP to acetone, length of air gap, evaporation condition and silicone coating were investigated on the $CO_2/N_2$ separation properties of the hollow fibers. Optimized PES hollow fiber membranes exhibited high permeance of $25\~50$ GPU and $CO_2/N_2$ selectivity of $30\~40$ at room temperature and have the apparent skin layer thickness of about $0.1\;{\mu}m$. The developed PES hollow fiber membranes, would be a good candidate suitable for the flue gas separation process.

• Membrane Journal
• /
• v.29 no.6
• /
• pp.362-376
• /
• 2019

In this study, hydrophilic coating characteristics of PVDF [poly(vinylidene fluoride)] hollow fiber membranes with flower type cross-section prepared by thermally induced phase separation were studied. The hollow fiber used in this study was provided from PureEnvitech Co. Ltd., and the hydrophilic coating experiment was performed with different concentration and number of coating of PEBAX 1657, 2533 and 3533 block copolymer solution using a dip coating method. The hydrophilic coated hollow fiber membrane was characterized to scanning microscope and contact angle measurements to determine the degree of hydrophilization. As a result of SEM characterization, it was confirmed that the thickness of the coating layer increased as the coating concentration increased and the number of coatings increased. Contact angle of surface of hollow fibers decreased as the concentration of the coating solution increased and the number of coatings increased. Gas permeance of oxygen gas was measured for the application of the hydrophilized hollow fiber to Membrane Areated Biofilm Reactor. As a result of gas permeation test, it was confirmed that gas permeance decreased with increasing coating concentration and number of coatings, and the more hydrophilized hollow fiber coated with PEBAX 1657 showed lower gas permeance than those coated with PEBAX 2533 and 3533.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.21 no.9
• /
• pp.850-857
• /
• 2011

Generally, sound-absorbing materials in vehicles are used for giving the comfort to passengers by reducing noise while driving. Materials of which targets are light weight, high performance, eco friendliness and recycling have been developed recently. In this study, sound-absorbing materials using PET(polyethylene terephthalate) hollow fibers to achieve the light weight and the high sound absorption performance are developed, and then evaluated to meet a requirement for the automotive components. The test results show that the acoustic performances of developed products having new fiber structure are better than those of the conventional product.

• Toxicological Research
• /
• v.26 no.3
• /
• pp.233-236
• /
• 2010

The analytical in vivo chromium ion was searched for using a voltammetric hollow-fiber dialysis sensor via square wave stripping voltammetry (SW), cyclic voltammetry (CV), and chronoamperometry. Under optimum parameters, the analytical results indicated linear working ranges of 50~400 mg/l CV and $10{\sim}80\;{\mu}g/l$ SW within a 30-sec accumulation time. The analytical detection limit (S/N) was $6.0\;{\mu}g/l$. The developed method can be applied to in vivo tissues and in ex vivo toxicity assay, as well as to other materials that require chromium analysis.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.11a
• /
• pp.471-473
• /
• 2006

An object of the present study is to provide a hollow fiber membrane humidifier capable of improving the humidification efficiency while lowering the pressure loss, and is suitably usable for PEMFC(Polymer Electrolyte Membrane Fuel Cell). The performance of PEMFC is decisively dependent on the humidity of the electrolyte membrane(fluorinated membrane) and a humidifier plays an important role in moisturizing electrolyte membrane. Especially this humidifier is adaptable for lower price to promote the commercialization of fuel cell vehicles and is passive type to be power free and to be volumetrically optimized. In this research, we propose the substitutes for the expensive fluorinated materials and the optimum dry-jet wet spinning conditions of hollow fiber membrane to get the fuel cell humidifier. In addition to that we established the standard method of evaluating the moisturizing performance of the humidifier of various materials.

• Macromolecular Research
• /
• v.10 no.2
• /
• pp.127-134
• /
• 2002

Microporous polypropylene hollow fiber membrane was fabricated from isotactic polypropylene-soybean oil system by melt spinning process. Addition of nucleating agent accelerated the crystallization rate and elevated the crystallization temperature. Nucleating agent increased the number of nuclei and spherulites, which offered more inter-spherulitic amorphous sites for stretching. Benzoic acid, adipic acid, and dibenzylidene sorbitol were selected as nucleating agents, and their characteristics and effects were investigated by thermal and optical analyses. Spherulite growth and micropore formation characteristics were correlated with the kind of nucleating agent. Benzoic acid and adipic acid showed the remarkable nucleating effect, while dibenzylidene sorbitol was less effective than those. Nucleating agents also helped the sample have uniform microporous structure. Increase of nucleating agent composition enhanced the nucleation effect to some extent. Nucleating agents played very important roles in enhancing the membrane porosity and water flux.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2004.11a
• /
• pp.142-145
• /
• 2004

Anion-exchange porous hollow-fiber membranes with a thickness of about 1.2 mm and a pore size of about $0.30{\mu}m$ were used as a supporting matrix to immobilize cycloisomaltooligosaccharide glucanotransferase (CITase). CITase was immobilized to the membrane via anion-exchange adsorption and by subsequent enzymatic cross-linking with transglutaminase, the amount of which ranged from 3 to 110 mg per g of the membrane. The degree of enzyme multilayer binding was equivalent to 0.3 to 9.8. Dextran, as the substrate, was converted into seven- to nine-glucose-membered cycloisomaltooligosaccharides (CI-7, -8, and -9) at a maxi mum yield of $28\%$ in weight at a space velocity of 10 per hour during the permeation of $2.0(w/w)\%$ dextran solution across the CITase-immobilized porous hollow-fiber membrane.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1995.09a
• /
• pp.73-85
• /
• 1995

The asymmetric hollow fiber membranes were prepared by the wet spining of polyetherimide dope solution and the effect of hollow fiber structures on the permeation characteristics of carbon dioxide and nitrogen gases through these membrane were investigated. As the concentration of the $\gamma$-butyrolactone (GBL) in dope solution, acting as a swelling agent was increased, the structure of hollow fiber was changed from the finger to sponge type. The permeabilities of gases (CO$_{2}$, N$_{2}$) through these membrane were measured over the wide range of pressure under different temperature. The effect of water vapor on the permeabilities of gases was also investigated. The measured permeabilities showed the different characteristics depending on the structure of membranes. It was found that the flow through the pores were dominant over the polymers matrix. Blocking effect by water vapor in the pores of skin layer greatly improved the ideal separation factor of carbon dioxide/nitrogen.

• 한국생물공학회:학술대회논문집
• /
• 2000.11a
• /
• pp.745-748
• /
• 2000

Anaerobic digester coupled with hollow fiber membrane unit. Treatment of starch waste with anaerobic digester-membrane system was studied. $0.17\;m^2$ area of hollow fiber membrane unit of known pore size was immersed into laboratory-scale anaerobic digestion system. The gas production was about $0.74\;m^3/kg$ COD treated. The COD removal efficient was about 80-95% depending on the hydraulic retention time. Crossflow ultrafiltration as Post treatment to anaerobic filter. The study conducted with different membrane pore size indicated that membrane with 1,000,000 molecular weight cut-off size gave a higher COD removal efficiency in the range of 83-87% while giving a study flux of $120-130\;L/m^2\;{\cdot}\;h$. A study was conducted to see the long term clogging effect of membrane also.

• Journal of Advanced Marine Engineering and Technology
• /
• v.32 no.6
• /
• pp.915-922
• /
• 2008

The gas separation technology using membrane is widely used to refine various gases in many industry fields and recently is being applying in $CO_2$ recovery technology. In the gas and chemical tanker. nitrogen generators for inerting, purging and padding are on board and most of them have membrane modules of hollow fiber type with long life and vibration resisting properties. Because a membrane module is a key component accounting for 50% of total manufacturing cost of nitrogen generator, adequate selection for it is an important problem. In this paper, the flow performance coefficient based on dimension and specification data of membrane module was relatively selected to compare nitrogen generating capacity of module and various performance tests about the selected PARKER ST6010 membrane module were conducted. As a result, the useful coefficient and basic data in selecting a membrane module were achieved.