• Title/Summary/Keyword: higher order solution

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Evaluation of Thermal Diffusivity and Electrochemical Properties of LiAlH4-PVDF Electrolyte Composites (LiAlH4-PVDF 전해질 복합체의 열확산 및 전기화학적 특성평가)

  • HWANG, JUNE-HYEON;HONG, TAE-WHAN
    • Journal of Hydrogen and New Energy
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    • v.33 no.5
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    • pp.574-582
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    • 2022
  • A lithium-ion battery exhibits high energy density but has many limitations due to safety issues. Currently, as a solution for this, research on solid state batteries is attracting attention and is actively being conducted. Among the solid electrolytes, sulfide-based solid electrolytes are receiving much attention with high ion conductivity, but there is a limit to commercialization due to the relatively high price of lithium sulfide, which is a precursor material. This study focused on the possibility of relatively inexpensive and light lithium hydride and conducted an experiment on it. In order to analyze the characteristics of LiAlH4, ion conductivity and thermal stability were measured, and a composites mixed with PVDF, a representative polymer electrolyte, was synthesized to confirm a change in characteristics. And metallurgical changes in the material were performed through XRD, SEM, and BET analysis, and ion conductivity and thermal stability were measured by EIS and LFA methods. As a result, Li3AlH6 having ion conductivity higher than LiAlH4 is formed by the synthesis of composite materials, and thus ion conductivity is slightly improved, but thermal stability is rapidly degraded due to structural irregularity.

A High-efficiency Single-phase Photovoltaic Inverter for High-voltage Photovoltaic Panels (고전압 태양광 패널용 고효율 단상 태양광 인버터)

  • Hyung-Min, Ryu
    • Journal of IKEEE
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    • v.26 no.4
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    • pp.584-589
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    • 2022
  • For DC-AC power conversion from a high-voltage photovoltaic panel to a single-phase grid, the two-stage transformerless inverter with a buck-boost converter followed by a full-bridge inverter is widely used. To avoid an excessive leakage current due to the large parasitic capacitance of the photovoltaic panel, the full-bridge inverter can only adopt the bipolar PWM which results in much higher power loss compared to the unipolar PWM. In order to overcome such a poor efficiency, this paper proposes a new topology in which an IGBT and a diode for circuit isolation are added to the buck-boost converter. The proposed circuit isolation method allows the unipolar PWM in the full-bridge inverter without any increase in the leakage current so that the overall efficiency can be improved. The validity of the proposed solution is verified by computer simulation and power loss calculation.

Large cylindrical deflection analysis of FG carbon nanotube-reinforced plates in thermal environment using a simple integral HSDT

  • Djilali, Nassira;Bousahla, Abdelmoumen Anis;Kaci, Abdelhakim;Selim, Mahmoud M.;Bourada, Fouad;Tounsi, Abdeldjebbar;Tounsi, Abdelouahed;Benrahou, Kouider Halim;Mahmoud, S.R.
    • Steel and Composite Structures
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    • v.42 no.6
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    • pp.779-789
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    • 2022
  • This work presents a non-linear cylindrical bending analysis of functionally graded plate reinforced by single-walled carbon nanotubes (SWCNTs) in thermal environment using a simple integral higher-order shear deformation theory (HSDT). This theory does not require shear correction factors and the transverse shear stresses vary parabolically through the thickness. The material properties of SWCNTs are assumed to be temperature-dependent and are obtained from molecular dynamics simulations. The material properties of functionally graded carbon nanotube-reinforced composites (FG-CNTCRs) are considered to be graded in the thickness direction, and are estimated through a micromechanical model. The non-linear strain-displacement relations in the Von Karman sense are used to study the effect of geometric non-linearity and the solution is obtained by minimization of the total potential energy. The numerical illustrations concern the nonlinear bending response of FG-CNTRC plates under different sets of thermal environmental conditions, from which results for uniformly distributed CNTRC plates are obtained as benchmarks.

Vibration behavior of partially bio-sourced sandwich panel with orthogonally stiffened core: Analytical and experiment study

  • Boussoufi, Aicha;Errouane, Lahouaria;Sereir, Zouaoui;Antunes, Jose V.;Debut, Vincent
    • Advances in aircraft and spacecraft science
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    • v.9 no.3
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    • pp.169-193
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    • 2022
  • By the present paper, both experimental and analytical models have been proposed to study the vibration behavior of partially bio-sourced sandwich panel with orthogonally stiffened core. For a variable mass fraction of Alfa fibers from 5% to 15%, impregnated in a Medapoxy STR resin, this panel were manufactured by molding the orthogonally stiffened core then attached it with both skins. Using simply supported boundary conditions, a free vibration test was carried out using an impact hammer for predicting the natural frequencies, the mode shapes and the damping coefficient versus the fibers content. In addition, an analytical model based on the Higher order Shear Deformation Theory (HSDT) was developed to predict natural frequencies and the mode shapes according to Navier's solution. From the experimental test, we have found that the frequency increases with the increase in the mass fraction of the fibers until 10%. Beyond this fraction, the frequencies give relatively lower values. For the analytical model, variation of the natural frequencies increased considerably with side-to-thickness ratio (a/H) and equivalent thickness of the core to thickness of the face (hs/h). We concluded that, the vibration behavior was significantly influenced by geometrical and mechanical properties of the partially bio-sourced sandwich panel.

Cost-Effective Soft Lithography of Organic Semiconductors in OFETs with Compact Discs as Master Molds (Compact Disc를 마스터 몰드로 사용하는 저비용의 OFET용 유기반도체 소프트 리소그래피)

  • Sejin Park;Hyukjin Kim;Tae Kyu An
    • Journal of Adhesion and Interface
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    • v.23 no.4
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    • pp.116-121
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    • 2022
  • OFET have require fine patterning technology for organic semiconductor solution process to be used in actual electronics. In this study, we compared and analyzed the soft lithography method which can form fine patterns more than the conventional spin coating method in order to confirm that it can have better electrical characteristics. The soft lithography method produced a flexible master mold using nano patterns on compact disc surfaces and obtained a 650 nm wide 2,7-Dioctyl [1] benzothieno [3,2-b] [1] benzo thiophene (C8-BTBT) nanowires. As a result, the field-effect mobility of devices fabricated by the spin coating method was 0.0036 cm2/Vs and mobility of devices produced by soft lithography method was 0.086 cm2/Vs, which was about 20 times higher than spin-coated devices and has better electrical performance.

Efficient Elimination of Tetracycline by Ferrate (VI): Real Water Implications

  • Levia Lalthazuala;Lalhmunsiama Lalhmunsiama;Ngainunsiami Ngainunsiami;Diwakar Tiwari;Seung Mok Lee;Suk Soon Choi
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.318-325
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    • 2023
  • The detection of antibiotics in treated wastewater is a global concern as it enters water bodies and causes the development of antibiotic resistance genes in humans and marine life. The study specifically aims to explore the potential of ferrate (VI) in eliminating tetracycline (TCL). The degradation of TCL is optimized with parametric studies, viz., the effect of pH and concentration, which provide insights into TCL elimination. The increase in pH (from 7.0 to 10.0) favors the percentage removal of TCL; however, the increase in TCL concentrations from 0.02 to 0.3 mmol/L caused a decrease in percentage TCL removal from 97.4 to 29.1%, respectively, at pH 10.0. The time-dependent elimination of TCL using ferrate (VI) followed pseudosecond-order rate kinetics, and an apparent rate constant (kapp) was found at 1978.8 L2 /mol2 /min. Coexisting ions, i.e., NaNO3, Na2HPO4, NaCl, and oxalic acid, negligibly affect the oxidation of TCL by ferrate (VI). However, EDTA and glycine significantly inhibited the elimination of TCL using ferrate (VI). The mineralization of TCL using ferrate (VI) was favored at higher pH, and it increased from 18.57 to 32.52% when the solution pH increased from pH 7.0 to 10.0. Additionally, the real water samples containing a relatively high level of inorganic carbon spiked with TCL revealed that ferrate (VI) performance in the removal of TCL was unaffected, which further inferred the potential of ferrate (VI) in real implications.

Study on the Shear Characteristics by using the Hot Mechanical Piercing during the Hot Stamping Process (열간 기계적 피어싱을 이용한 핫스탬핑 전단특성 연구)

  • K. J. Park;J. M. Park;J. Y. Kong;J. Y. Kim;S. C. Yoon;J. S. Hyun;Y. D. Jung
    • Transactions of Materials Processing
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    • v.32 no.2
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    • pp.81-86
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    • 2023
  • The hot stamping process is widely used for high strength of vehicle parts, with heating 900 ℃ or higher in a furnace and in-die quenching to achieve strength above 1.5 GPa of the quenchable boron alloyed steel 22MnB5. First of all, the hot stamping process consisted of heating, forming, quenching and trimming. In the trimming process case, the laser method has been conventionally adopted. For laser trimming process, it has the problems pertaining to low productivity and high cost while the hot stamping process, accordingly the trimming process need to investigate the research for alternative method. In order to overcome these issues, many research groups have studied the mechanical trim solution on the hot stamped parts at high temperature. In this study, the mechanical piercing was performed during the hot stamping process at the high temperature for overcome the disadvantages of laser cutting. Also, the process parameters such as piercing time after die closing, clearances of between die and punch were controlled for obtaining the reasonable shear characteristics.

Using a Stretch Sensor About of Squat Ankle Range of Motion Check Socks -Focusing on Men in Their Late 20s- (스트레치 센서를 이용한 스쿼트 시 발목 가동범위 체크 센서 양말에 관하여 -20대 후반 남성을 중심으로-)

  • Song, Kwanwoo;Park, Jinhee;Kim, Jooyong
    • Journal of Fashion Business
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    • v.26 no.2
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    • pp.129-142
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    • 2022
  • The purpose of this study is to develop socks to check the range of ankle movement during squats for men in their late 20s. Sensors of 6, 8, and 12 mm were selected, and each sample was impregnated 1 to 3 times. It was prepared using a CNT dispersion, and the GF value was measured using UTM. Among them, the sample with 2 impregnation showed the best GF value. As a result of applying each sample to the socks, the 12 mm sensor was wider than the area of the Achilles tendon, resulting in noise, and the 8 mm sensor was higher than the tensile strength of the socks, resulting in a decrease in the graph. Therefore, testing was performed using a 6 mm sensor. In order to determine the effectiveness of the sensor, the normal operating range was checked through squats, and significant changes were confirmed when the operating range was checked again through squats by performing operations that can increase the operating range through Gastrocnemius, Soleus stretching, and low lunge. Using the results of this study, it is expected that the average value of the ankle movement range of the user is checked prevent injury, to be provided as basic data for the production of shoe products and the promotion of physical health.

A review on the application of plastic waste in the reinforced concrete structures

  • K. Senthil;Suresh Jakhar;Manish Khanna;Kavita Rani
    • Advances in materials Research
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    • v.13 no.2
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    • pp.115-128
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    • 2024
  • Concrete is the most significant material in the construction industry which is required to construct several facilities like roads, buildings, and bridges etc. which leads to the economic development of a country. But now days, in view of sustainable development and environmental problems, plastic waste management is one of the major environmental issues due to its non-biodegradable nature which allows it to stay in the landfills until they are cleaned up. To overcome all these concerns, plastic waste may be used as a substitute of natural fine and coarse aggregate in concrete and a valuable solution to utilize the plastic items which causes several problems. In order to, present study is focused on the affecting properties of concrete as workability, compressive strength, and tensile strength of concrete with using plastic waste and without using plastic waste. Based on the detailed literature, it was observed that the plastic waste is not affecting the quality and consistency of concrete. However, as the number of PVC particles in the mixture increased, the drying shrinkage values decreased and the inclusion of plastic flakes can mitigate drying shrinkage cracking which leads the higher durability of concrete. Based on the comprehensive literature, it was also observed that the plastic aggregate found to be suitable for low and medium strength concrete. However, the investigation on the application of plastic aggregate in the high strength concrete is found limited. It was concluded that the optimum percentage of the plastic aggregate was found about 20%.

Enhancement of phosphate removal using stabilized Fe-Mn particle (Fe-Mn 입자의 안정화를 통한 인산염 효율 향상)

  • Seoyeon Kang;Jeongwoo Shin;Byugnryul An
    • Journal of Korean Society of Water and Wastewater
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    • v.37 no.6
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    • pp.375-382
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    • 2023
  • The binary oxide adsorbent using Fe and Mn (Fe-Mn) has been prepared by precipitation method to enhance the removal of phosphate. Different amounts of chitosan, a natural organic polymer, were used during preparation of Fe-Mn as a stabilizer to protect an aggregation of Fe-Mn particles. The optimal amount of chitosan has been determined considering the separation of the Fe-Mn particles by gravity from solution and highest removal efficiency of phosphate (Fe-Mn10). The application of Fe-Mn10 increased removal efficiency at least 15% compared to bare Fe-Mn. According to the Langmuir isotherm model, the maximum uptake (qm) and affinity coefficient (b) were calculated to be 184 and 240 mg/g, and 4.28 and 7.30 L/mg for Fe-Mn and Fe-Mn10, respectively, indicating 30% and 70% increase. The effect of pH showed that the removal efficiency of phosphate was decrease with increase of pH regardless of type of adsorbent. The enhanced removal efficiency for Fe-Mn10 was maintained in entire range of pH. In the kinetics, both adsorbents obtained 70% removal efficiency within 5 min and 90% removal efficiency was achieved at 1 h. Pseudo second order (PSO) kinetic model showed higher correlation of determination (R2), suggesting chemisorption was the primary phosphate adsorption for both Fe-Mn and Fe-Mn10.