• Title/Summary/Keyword: higher order solution

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The Compressive Strength Development of Briquette Ash by Alkali Activated Reaction (알칼리 활성반응에 의한 Briquette ash의 강도 발현 특성)

  • Seo, Myeong-Deok;Lee, Su-Jeong;Park, Hyun-Hye;Kim, Yun-Jong;Lee, Su-Ok;Kim, Taik-Nam;Cho, Sung-Baek
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.463-469
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    • 2008
  • Non-sintering cement was manufactured with briquette ash. Alkali activator for compression bodies used a NaOH solution. In order to apply alkali-activated briquette ash and the non-sintering cement to concrete, several experimental studies were performed. It was necessary to study the binder obtained by means of a substitute for the cement. This study concentrated on strength development according to the concentration of NaOH solution, the curing temperature, and the curing time. The highest compressive strength of compression bodies appeared as $353kgf/cm^2$ cured at $80^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is needed to get a higher strength body. Also, geopolymerization was examined by SEM and XRD analysis after the curing of compression bodies. According to SEM and XRD, the main reaction product in the alkali activated briquette ash is aluminosilicate crystal.

Surfactant-enhanced Soil Washing using Tween and Tergitol Series Surfactants for Kuwait Soil Heavily Contaminated with Crude Oil

  • Heo, Hyojin;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.20 no.5
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    • pp.26-33
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    • 2015
  • Batch experiments were performed to investigate the feasibility of a surfactant-enhanced soil washing process for soils heavily contaminated with crude oil in Kuwait. TPH concentration of the contaminated soil was 223,754 mg/kg, sampled from the bottom of a vaporized oil extraction pond in the Burgan reservoir field. Commercialized eight nonionic surfactants (Tween and Tergitol series) were used to measure the aqueous solubility for the crude oil. Among them, two Tergitol surfactants were used to evaluate the TPH removal efficiency of the surfactant-enhanced soil washing for heavily contaminated Kuwait soil. The solubility of the crude oil in surfactant solution was in the order Tergitol 15-S-7 > Tergitol 15-S-9 > Tergitol 15-S-12 > Tween-80 > Tween-20 > Tween-60, which showed that the crude oil solubilities of the Tergitol series were higher than those of the Tween series. The TPH removal efficiencies of 2% and 5% Tergitol 15-S-9 solution were 59% and 65%, respectively. Because the residual TPH concentration in the washed soil was still higher than the clean-up level (10,000 mg/kg), the soil washing process was repeated five times. After the fifth washing, the residual TPH concentration in the soil went down to 7,680 mg/kg and its removal efficiency was 97%.

Effect of Cr Addition on the High Temperature Deformation Behavior of Fe-Al Intermetallics (Fe-Al 금속간 화합물의 고온변형거동에 미치는 Cr 첨가의 효과)

  • Bang W.;Lim H. T.;Ha T. K.;Song J. H.;Chang Y. W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.05a
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    • pp.167-171
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    • 2001
  • High temperature deformation behavior of Fe-28Al-5Cr alloy has been investigated known to show anomalous temperature dependence of yield strength. Specifically, the effect of Cr addition has been examined. A series of tensile and load relaxation tests have been carried out to obtain the flow behavior of Fe-28Al-5Cr alloy at the elevated temperatures. The flow curves have then been analyzed using the inelastic deformation theory recently proposed. Firstly, high temperature flow stress of iron aluminides can be resolved into internal stress and frictional stress. Secondly, the temperature corresponding to peak strength gets higher level at faster strain rate, which presumably due to the increased contribution of internal stress in observed flow stress. And thirdly, the alloying of Cr seems to cause solid-solution strengthening of frictional stress level and the elevation of 2nd order transition temperature. In this analogy, Fe-28Al-5Cr exhibits better strength especially at relatively higher temperature and lower strain rate than Fe-28Al.

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Removal of Toxic Pollutants from Aqueous Solutions by Adsorption onto Organo-kaolin

  • Sayed Ahmed, S.A.
    • Carbon letters
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    • v.10 no.4
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    • pp.305-313
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    • 2009
  • In this study, the adsorption of toxic pollutants onto cetyltrimethylammonium kaolin (CTAB-Kaolin) is investigated. The organo-kaolin is synthesized by exchanging cetyltrimethylammonium cations (CTAB) with inorganic ions on the surface of kaolin. The chemical analysis, the structural and textural properties of kaolin and CTAB-kaolin were investigated using elemental analysis, FTIR, SEM and adsorption of nitrogen at $-196^{\circ}C$. The kinetic adsorption and adsorption capacity of the organo-kaolin towards o-xylene, phenol and Cu(II) ion from aqueous solution was investigated. The kinetic adsorption data of o-xylene, phenol and Cu(II) are in agreement with a second order model. The equilibrium adsorption data were found to fit Langmuir equation. The uptake of o-xylene and phenol from their aqueous solution by kaolin, CTAB-kaolin and activated carbon proceed via physisorption. The removal of Cu(II) ion from water depends on the surface properties of the adsorbent. Onto kaolin, the Cu(II) ions are adsorbed through cation exchange with $Na^+$. For CTAB-kaolin, Cu(II) ions are mainly adsorbed via electrostatic attraction with the counter ions in the electric double layer ($Br^-$), via ion pairing, Cu(II) ions removal by the activated carbon is probably related to the carbon-oxygen groups particularly those of acid type. The adsorption capacities of CTAB-kaolin for the investigated adsorbates are considerably higher compared with those of unmodified kaolin. However, the adsorption capacities of the activated carbons are by far higher than those determined for CTAB-kaolin.

Hierarchical theories for a linearised stability analysis of thin-walled beams with open and closed cross-section

  • Giunta, Gaetano;Belouettar, Salim;Biscani, Fabio;Carrera, Erasmo
    • Advances in aircraft and spacecraft science
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    • v.1 no.3
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    • pp.253-271
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    • 2014
  • A linearised buckling analysis of thin-walled beams is addressed in this paper. Beam theories formulated according to a unified approach are presented. The displacement unknown variables on the cross-section of the beam are approximated via Mac Laurin's polynomials. The governing differential equations and the boundary conditions are derived in terms of a fundamental nucleo that does not depend upon the expansion order. Classical beam theories such as Euler-Bernoulli's and Timoshenko's can be retrieved as particular cases. Slender and deep beams are investigated. Flexural, torsional and mixed buckling modes are considered. Results are assessed toward three-dimensional finite element solutions. The numerical investigations show that classical and lower-order theories are accurate for flexural buckling modes of slender beams only. When deep beams or torsional buckling modes are considered, higher-order theories are required.

A Hybrid ARQ Scheme with Changing the Modulation Order (변조 차수 변경을 통한 하이브리드 자동 재전송 기법)

  • Park, Bum-Soo
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.3
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    • pp.336-341
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    • 2014
  • When using a higher-order modulation scheme, there are variations in bit-reliability depending on the bit position in a modulation symbol. Variations of bit-reliability in the codeword block lower the decoding performance. Also, the decoding performance increases as the sum of the bit-reliabilities in the codeword block increases. This paper presents a novel hybrid automatic repeat request scheme that increases the sum of the reliabilities of the transmitted bits by lowering the modulation order, and decreases the variations of bit-reliability in the codeword block by preferentially retransmitting bits with low reliability. The proposed scheme outperforms the constellation rearrangement scheme. Furthermore, the proposed scheme also provides a good solution in cases where the size of the retransmission block is smaller than the size of the initial transmission block.

A Study on an Effective Higher-Order Taylor-Galerkin Method for the Analysis of Structural Dynamics (동적 해석을 위한 효과적 고차 Taylor Galerkin법에 관한 연구)

  • 윤성기;박상훈
    • Journal of KSNVE
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    • v.3 no.4
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    • pp.353-359
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    • 1993
  • In this study, the Taylor-Galerkin method is modified to take into consideration the third order term in the Taylor series of the fundamental variable. In the Taylor-Galerkin method, after expressing the governing equation of motion in conservation form, the temporal discretization is done first and then spatial discretization follows in contrast to the conventional approaches. A predictor-corrector type algorithm has been developed previously by the same author. A new computationally efficient direct algorithm is proposed in this study. A study on convergency and accuracy of the solution is carried out. Numerical examples show that this new algorithm exhibits the same order of accuracy with less computational effort.

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Comparions of Removal Performances of Divalent Heavy Metals by Natural and Pretreated Zeolites (천연 및 전처리 제올라이트에 의한 2가 중금속 이온 제거능의 비교.검토)

  • 감상규;김덕수;이민규
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.399-409
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    • 1999
  • The three domestic natural zeolites(Yong dong-ri (Y), Daesin-ri (D), Seogdong-ri (S)) harvested in Kyeongju-shi and Pohang-shi, Kyungsangbug-Do, were pretreatd with each of the NaOH, $Ca(OH)_2$ and NaOH following HCl solutions, and the removal performances of divalent haevy metals(Cu, Mn, Pb, and Sr) for natural and pretreated zeolites were investigated and compared in the single and mixed solutions. The natural zeolite-heavy metal system attained the final equilibrium plateau within 20 min, irrespective of initial heavy metal concentration. The heavy metal uptakes increased with increasing initial heavy metal concentration and pH. The heavy metal uptakes for natural zeolites decreased in the following sequences : D>Y>S among the natural zeolites; Pb>Cu>Sr>Mn among the heavy metals. The pretreated zeolites showed higher heavy metal removal performances than natural zeolites and decreased in the order of NaOH, NaOH following HCl, $Ca(OH)_2$ treatment among the pretreatment methods. The heavy metal ion exchange capacity by natural and pretreated zeolites was described either by Freundlich equation or Langmuir equation, but it followed the former better than the latter. The heavy metal uptakes for natural zeolites decreased in the mixed solution, in comparing with those in the single solution and especially, the manganese uptake decreased greatly in the mixed solution. The pretreated zeolites showed the improved removal performances of heavy metals in the mixed solution than in the single solution and the heavy metal uptakes by those in the mixed solution showed the same trends in the single solution among the chemical treatment methods and heavy metals.

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Adsorption Characteristics of Alkaline Copper Quat Preservative Components in Wood (구리⋅알킬암모늄화합물계 목재방부제 (ACQ) 유효성분의 목재 흡착 특성)

  • Lee, Jong-Shin;Choi, Gwang-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.491-498
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    • 2014
  • In order to obtain basic data for concentration control of alkaline copper quat (ACQ) solution in wood preservative treatment, this study investigates the change of concentration and adsorption of treating solution and active ingredient, copper oxide (CuO) and didecyldimethyl ammonium chloride (DDAC), in the process of recycling of ACQ solution. Japanese larch (Larix leptolepis), Douglas-fir (Psedotsuga menziesii) and Radiata pine (Pinus radiata) were treated with ACQ solution. The active ingredient concentration of ACQ solution was decreased continuously with increase of recycling. There are differences between extent of concentration decrease of Cu (as CuO) and DDAC. DDAC was decreased more quickly and to a higher degree than Cu for all recycling. The extent of DDAC concentration decrease was remarkable than that of Cu for wood species. The amount of DDAC adsorbed into wood decreased with the increase of ACQ solution recycling, but adsorption of Cu was little difference regardless of recycling. The adsorption of Cu into wood increased as DDAC concentration decrease by recycling of ACQ solution. This is likely due to decrease of DDAC competition with Cu for the same reaction site in wood.

Characteristics of Phosphate Adsorption using Prepared Magnetic Iron Oxide (MIO) by Co-precipitation Method in Water (공침법에 의해 제조된 Magnetic Iron Oxide (MIO)를 이용한 수중 인 흡착 특성)

  • Lee, Won-Hee;Chung, Jinwook;Kim, Jong-Oh
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.6
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    • pp.609-615
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    • 2015
  • This study was carried out for characterization of MIO synthesized in our laboratory by co-precipitation method and applied isotherm and kinetic models for adsorption properties. XRD analysis were conducted to find crystal structure of synthesized MIO. Further SEM and XPS analysis was performed before and after phosphate adsorption, and BET analysis for surface characterization. Phosphate stock solution was prepared by KH2PO4 for characterization of phosphate adsorption, and batch experiment was conducted using 50 ml conical tube. Langmuir and Freundlich models were applied based on adsorption equilibrium test of MIO by initial phosphate solution. Pseudo first order and pseudo second order models were applied for interpretation of kinetic model by temperature. Surface area and pore size of MIO were found $89.6m^2/g$ and 16 nm respectively. And, the determination coefficient ($R^2$) value of Langmuir model was 0.9779, which was comparatively higher than that of Freundlich isotherm model 0.9340.