• Bulletin of the Korean Chemical Society
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• v.9 no.5
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• pp.289-291
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• 1988

The ratio of trivalent to divalent copper has been determined by the redox titration for two superconducting phases of $YBa_2Cu^{3+}_{2x}Cu^{2+}_{3-2x}O_{6.5+x}$ with the onset temp. of 60K (x = 0.23 ${\pm}$ 0.01) and 90K (x = 0.35 ${\pm}$ 0.02), and for the insulating one (x ${\cong}$ 0) which was kept in an ambient atmosphere for 72 hrs. It is found that $T_c$, and the ratio of $Cu^{3+}/Cu^{2+}$ depend strongly on the annealing temperature and time. A typical orthorhombic phase can easily be obtained by a slow cooling or stepwise cooling at $PO_2$ = 1 atm, and shows a high Tc (ca. 90K) superconductivity.

• Progress in Superconductivity and Cryogenics
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• v.9 no.3
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• pp.32-36
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• 2007

On the contrary of a conventional motor with very narrow air-gap. it is difficult to calculate the accurate magnetic field distribution and the performance of an air-cored superconducting motor by 2 dimensional analysis. which does not use high permeability material except outer machine shield. This paper aims to do analysis of magnetic field and force distribution from the 3 dimensional modelling of a 1MW class superconducting synchronous motor. Especially. the field coil composed of Bi-2223 high-temperature superconductor and the outer machine shield are modelled by finite element analysis software according to their structures and the self-inductance and Lorentz force are calculated based on the 3 dimensional magnetic field calculation. Moreover. the influence of an important parameter, synchronous reactance, has been analyzed on the machine performances such as voltage variation and output power.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.7
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• pp.606-611
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• 2009

AC loss is one of the important factors for commercialization of a high temperature superconducting (HTS) cable from an economic point of view. But AC loss characteristics of the HTS-cable are not elucidated completely because of its complex structure. As an earlier stage of analyzing the AC loss in the 22.9 kV/50 MVA, 100m HTS-cable system of Korea Electric Power Corporation (KEPCO) which is now in collaboration with us, a two-dimensional (2D) numerical model, which takes into account the nonlinear conductivity properties of a high temperature superconductor, has been developed. In order to examine our 2D model, we have prepared several single-layer cable samples whose AC losses are sufficiently reliable due to their simple structure. The AC losses of the samples were experimentally investigated and then compared with our 2D model. The results show that the numerically calculated AC losses are not in good agreement with the measured ones for the cylindrical cable and deca-cable samples with low critical current density. However, the numerically calculated and measured AC losses are relatively in good agreement for the deca-cable and hex-cable samples with high critical current density, although the difference between these two loss data in the deca-cable sample tends to increase in the low current region.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.9 no.4
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• pp.552-560
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• 1997

Analysis is performed to determine the optimal lengths or cross-sectional areas of refrigerator-cooled current leads that can be applied to the conduction-cooled superconducting systems. The binary current lead is composed of the series combination of a normal metal at the upper(warm) part and a high $T_c$ superconductor(HTS) at the lower(cold) part. The heat conduction toward the cold end of HTS part constitutes a major refrigeration load. In addition, the joint between the parts should be cooled by a refrigerator in order to reduce the load at the low end and maintain the HTS part in a superconducting state. The sum of the work inputs required for the two refrigeration loads needs to be minimized for an optimal operation. In this design, three simple models that depict the refrigeration performance as functions of cooling temperature are developed based on some of the existing refrigerators. By solving one-dimensional conduction equation that take into account the temperature-dependent properties of the materials, the refrigeration works are numerically calculated for various values of the joint temperature and the sizes of two parts. The results show that for given size of HTS, there exist the optimal values for the joint temperature and the size of the normal metal. It is also found that the refrigeration work decreases as the length of HTS increases and that the optimal size of normal metal is quite independent of the size of HTS. For a given length of HTS, there is an optimal cross-sectional area and it increases as the length increases. The dependence of the optimal sizes on the refrigerator models employed are presented for 1kA leads.

• Progress in Superconductivity and Cryogenics
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• v.13 no.1
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• pp.6-11
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• 2011

The $BaHfO_3$ (BHO) buffer layer on the IBAD MgO template was turned to be effective for a successful fabrication of $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) films with high critical current density ($J_c$). Both the BHO buffer layers and GdBCO films were prepared by pulsed laser deposition (PLD). The effects of the PLD conditions, including substrate temperature ($T_s$), oxygen partial pressure ($PO_2$), and deposition time on the in-plane texture, surface roughness, and microstructures of the BHO buffer layers on the IBAD MgO template were systematically studied for processing optimization. The c-axis oriented growth of BHO layers was insensitive to the deposition temperature and the film thickness, while the in-plane texture and surface roughness of those were improved with increasing $T_s$ from 700 to $800^{\circ}C$. On the optimally processed BHO buffer layer, the highest $J_c$ value (77 K, self-field) of 3.68 $MA/cm^2$ could be obtained from GdBCO film deposited at $780^{\circ}C$, representing that BHO is a strong candidate for the buffer layer on the IBAD MgO template.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.55 no.12
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• pp.633-639
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• 2006

High temperature superconductor (HTS) winding coil is one of the key component in superconducting device fabrication. Double-pancake style coils are widely used for such application. High resistance between pancake coils greatly affects the machine design, operating condition and thus the stability. In order to reduce such resistance, experimentalists are looking for efficient and damage free coil connecting methods. In this respect, here we proposed parallel joining method to connect the coils. This is to do crossly joining with HTS tapes on two parallel HTS tapes. Joint samples between two parallel HTS tapes were prepared by using HTS tapes and current-voltage (I-V) characteristic curves were investigated at liquid nitrogen temperature i.e., 77.3 K. A 20 cm length joint connected between two parallel HTS tapes shows $32.5n{\Omega}$, for currents up to 250 A. A small HTS magnet, having two double pancake sub-coils connected together through new parallel joint method was fabricated and their current-voltage (I-V) characteristic curve was investigated. At 77.3K, critical current(Ic) of 97 A and resistance of $55n{\Omega}$ for currents upto 130 A were measured. At operating current 86 A lower than Ic, Joule heats generated in whole magnet and at joint region between sub-coils were 226 mW and 0.4 mW, respectively. Low Joule heat generation suggests that this joining method may be used to fabricate HTS magnet or windings.

• Progress in Superconductivity
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• v.3 no.1
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• pp.23-27
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• 2001

We have investigated the mixed-state magnetoresistance of high quality c-axis-oriented MgB2 thin film for magnetic field from 0.5 T to 5.0 T, applied normal to ab-plane. The temperature dependence of magnetoresistance was well described by vortex glass and fluctuation theories for different temperature regimes. We observed glassy exponent of v(z-1)~3 and upper critical field of $H_{c2}$(0)~35 T, which is consistent with previous data obtained from direct $H_{c2}$(0) measurements. Interestingly, the thermally activated flux flow region was observed to be very narrow, suggesting that the pinning strength of this compound is very strong. This finding is closely related to the recent reports that the bulk pinning is dominant in $MgB_2$and the critical current density of $MgB_2$ thin film is very high, comparable to that of cuprate superconductor. The present results further suggest that $MgB_2$is beneficial to technical applications.ons.

• KEPCO Journal on Electric Power and Energy
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• v.1 no.1
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• pp.157-162
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• 2015

Large scale superconducting magnetic energy storage (SMES) system requires very high magnetic energy density in its superconducting coils to enhance the energy capacity and efficiency of the system. The recent high temperature superconducting (HTS) conductors, so called 2G conductors, show very good performance under very high magnetic field so that they seem to be perfect materials for the large scale SMES coils. A general shape of the coil system with the 2G HTS conductor has been a tor oid, because the magnetic field applied perpendicularly to the surface of the 2G HTS conductor could be minimized in this shape of coil. However, a toroid coil requires a 3-dimensional computation to acquire the characteristics of its critical current density - magnetic field relations which needs very complicated numerical calculation, very high computer specification, and long calculation time. In this paper, we suggested an analytic and statistical calculation method to acquire the maximum magnetic flux density applied perpendicularly to the surface of the 2G HTS conductor and the stored energy in the toroid coil system. Although the result with this method includes some errors but we could reduce these errors within 5 percent to get a reasonable estimation of the important parameters for design process of the HTS toroid coil system. As a result, the calculation time by the suggested method could be reduced to 0.1 percent of that by the 3-dimensional numerical calculation.

• Journal of Powder Materials
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• v.15 no.1
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• pp.6-12
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• 2008

[ $YBa_2Cu_3O_{7-y}$ ](123) powders were synthesized by the solid state reaction method using two different purity $BaCO_3$ powders (99.75% and 99.7% purity) and $Y_2O_3$ (99.9%) and CuO (99.9%) powders. The effect of $BaCO_3$ purity on the formation of a 123 phase and the superconducting properties were investigated. The mixtures of raw powders were calcined at temperature ranges of $800^{\circ}C-880^{\circ}C$ in air and finally made into a single grain samples by a melt processing with top seeding. It was found that a 123 phase was well formed at temperature above $870^{\circ}C$, but the purity effect on the 123 formation was negligible. The single-grain 123 samples prepared from the different $BaCO_3$ powders showed the same $T_c$ value of 90.5 K and similar $J_c$ values about $10^4\;A/cm^2$ at 0 T and 77 K, and $10^3\;A/cm^2$ at 2 T and 77 K. This result indicates that the low purity, cheap price $BaCO_3$ powder can be used as a raw material for the fabrication of single-grain, high-$J_c$ superconducting levitator.

• 한국초전도학회:학술대회논문집
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• v.9
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• pp.210-213
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• 1999

Magnetoresistance and magnetization of Sr$_{l-x}K_xBiO_3$ were both measured as functions of temperature and magnetic field. Resistivity goes to zero at T=10.1K and the overall superconducting transition behavior under applied magnetic fields is similar to that of other BiO based superconductors. Also, below T<5K we have observed the reappearance of finite resistivity with a power law temperature dependence( ${\rho}$ ${\sim}$T$^1$); the reentrant superconducting transition of resistivity. Contrary to the Josephson weak link effect in polycrystalline samples, which gives the depression of the superconducting state with increasing electrical current or magnetic field, the superconducting state for T<5K is resumed by applying a higher current or magnetic field. Magnetic susceptibility( ${\chi}$ ) of Sr$_{l-x}K_xBiO_3$ for T<5K also shows similar trends to that observed in transport measurements: increase of ${\chi}$ (paramagnetic-like behavior) at a low magnetic fields(B=50 Oe) and, the resumption of perfect diamagnetism at high fields.