• Title/Summary/Keyword: high-temperature state

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High field HTS insert coils : Status and key technical issue

  • Schwartz, Justin
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.22-22
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    • 2000
  • The discoveries of high temperature superconductors received great attention due to their high critical temperatures. These materials also exhibit extremely high critical magnetic fields and high critical current density at low temperature, high magnetic field. Thus, they are the most promising materials for superconducting magnets above 20 T. In this talk, progress in the development of HTS materials and insert coils at the National High Magnetic Field Laboratory will be reviewed. In 1999, a Bi-2212 stack of double pancakes generated 3 T in a 19 T background field. These results will be reviewed in terms of implications for future systems. Individual double pancakes of Bi-2223 have also been tested and their performance will also be discused. The present goal of a 57 system will be presented and the key technical requirements for larger, higher field systems will be addressed. It will be shown that in addition to increased critical current density, improved mechanical performance (stain resistanced) is necessary for high field systems. Furthemore, improvements in the conductor n-value will improve prospects for operational systems.

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The steady-state creep rate and creep-rupture life of 2024 Al alloy at high temperature (2024 Al 合金의 高溫正常 크리이프 變形速度와 크리이프 破斷壽命에 관한 硏究)

  • 오세욱;박경동;박인석
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.3
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    • pp.513-519
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    • 1988
  • Constant load creep tests have been carried out over a range of stresses at high temperatures. The experimental equations of the steady-state creep rate and creep-rupture life were respectively found to be related to the normalized applied-stress and temperature as ln.epsilon.$_{s}$ =6.10 on.sigma./ $E_{T}$-12.81*10$^{3}$ 1/T+15.98 (h $r^{-1}$) ln $t_{R}$=-6.24ln.sigma./ $E_{T}$+15.08*10$^{3}$1/T-23.66 (hr) and the equation of creep-rupture life had a good agreement with the expression of the Minimum-Commitment Method (MCM). However, the relationship between the steady-state creep rate and the creep-rupture life, noted by Monkman and Grant, lnt/snb R/ = mln.epsilon.$_{S}$+b made a considerable deviation against the present creep-rupture data. It is believed that this problem is to be discussed and investigated continually.lly.lly..

Microstructure and Sintering Behavior of W-15 wt%Cu Nanocomposite Powder Prepared from W-CuO Mixture (W-CuO 혼합물을 이용하여 제조된 W-Cu나노복합분말의 미세구조와 소결거동에 관한 연구)

  • 김길수;김대건;김영도
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.270-274
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    • 2003
  • Recently, the fabrication process of W-Cu nanocomposite powders has been researched to improve the sinterability by mechanochemical process (MCP), which consists of ball milling and hydrogen-reduction with W- and Cu-oxide mixture. However, there are many control variables in this process because the W oxides are hydrogen-reduced via several reduction stages at high temperature over 80$0^{\circ}C$ with susceptive reduction conditions. In this experiment, the W-15 wt%Cu nanocomposite powder was fabricated with the ball-milling and hydrogen-reduction process using W and CuO powder. The microstructure of the fabricated W-Cu nanocomposite powder was homogeneously composed of the fine W particles embedded in the Cu matrix. In the sintering process, the solid state sintering was certainly observed around 85$0^{\circ}C$ at the heating rate of 1$0^{\circ}C$/min. It is considered that the solid state sintering at low temperature range should occur as a result of the sintering of Cu phase between aggregates. The specimen was fully densified over 98% for theoretical density at 120$0^{\circ}C$ for 1 h with the heating rate of 1$0^{\circ}C$/min.

Theoretical Researches of Kinetics and Anharmonic Effect for the Reactions Related to NO in the Ozone Denitration Process

  • Yu, Hongjing;Xia, Wenwen;Liu, Yancheng;Yao, Li
    • Journal of the Korean Chemical Society
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    • v.65 no.3
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    • pp.185-196
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    • 2021
  • For studying the reaction mechanism of the reactions related to NO in the ozone denitration reactions, the harmonic and anharmonic rate constants were calculated by the transition state (TS) theory and Yao and Lin (YL) method. According to above calculations, the reactions of NO with O3 and NO3 play an essential role, and the kinetic parameters considering anharmonic effect were fitted. Furthermore, the rate constants were up as temperature increasing, and the tendencies of high temperature were more gradual than the low temperature. The research will provide theoretical basis for the ozone denitration reactions.

Chemical Reactions in Solid State Complexes of 1,2-Polybutadiene and Palladium Chloride : High Temperature Infrared Study

  • Lee, Joon Y.;Laurence A. Belfiore
    • Bulletin of the Korean Chemical Society
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    • v.17 no.9
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    • pp.826-830
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    • 1996
  • Fourier transform infrared (FTIR) temperature studies were performed to examine the microstructural changes that occur in annealing process of the thin films of 1,2-polybutadiene (1,2-PBu)/palladium chloride (PdCl2) complex. The disappearance of the infrared absorption intensities at 1640, 1418, 994 and 910 cm-1 signifies the consumption of 1,2-vinyl groups of 1,2-PBu. The progressive loss of unsaturation and production of methyl groups as a function of temperature were identified by the enhanced infrared absorption intensities at 1447 and 1375 cm-1. The loss of pendent carbon-carbon double bond is considered to involve both palladium-catalyzed addition reaction and thermally induced cyclization.

Characteristics of Precise Temperature Control of Industrial Cooler on Thermal Load (산업용 냉각기의 열부하 변화에 대응한 정밀온도제어 특성)

  • Baek, S.M.;Choi, J.H.;Byun, J.Y.;Moon, C.G.;Jeong, S.K.;Yoon, J.I.
    • Journal of Power System Engineering
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    • v.14 no.2
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    • pp.34-39
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    • 2010
  • Recently, technical trend for machine tools is focused on enhancement of speed and accuracy. High speedy processing causes thermal and structural deformation of objects from the machine tools. Water cooler has to be applied to machine tools to reduce the thermal negative influence with accurate temperature controlling system. Existing On-Off control type can't control temperature accurately because compressor is operated and stopped repeatedly and causes increment of power consumption and decrement of the expected life of compressor. The goal of this study is to minimize temperature error in steady state. In addition, control period of an electronic expansion valve were considered to increment of lifetime of the machine tools and quality of product with a water cooler. PI controller is designed using type of hot-gas bypass for precise control of temperature. Gain of PI is decided easily by method of critical oscillation response, excellent performance of control is shown with 4.24% overshoot and ${\pm}0.2^{\circ}C$error of steady state. Also, error range of temperature is controlled within $0.2^{\circ}C$although disturbance occurs.

Temperature-dependent DC Characteristics of Homojunction InGaAs vertical Fin TFETs (동종 접합 InGaAs 수직형 Fin TFET의 온도 의존 DC 특성에 대한 연구)

  • Baek, Ji-Min;Kim, Dae-Hyun
    • Journal of Sensor Science and Technology
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    • v.29 no.4
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    • pp.275-278
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    • 2020
  • In this study, we evaluated the temperature-dependent characteristics of homojunction InGaAs vertical Fin-shaped Tunnel Field-Effect Transistors (Fin TFETs), which were fabricated using a novel nano-fin patterning technique in which the Au electroplating and the high-temperature InGaAs dry-etching processes were combined. The fabricated homojunction InGaAs vertical Fin TFETs, with a fin width and gate length of 60 nm and 100 nm, respectively, exhibited excellent device characteristics, such as a minimum subthreshold swing of 80 mV/decade for drain voltage (VDS) = 0.3 V at 300 K. We also analyzed the temperature-dependent characteristics of the fabricated TFETs and confirmed that the on-state characteristics were insensitive to temperature variations. From 77 K to 300 K, the subthreshold swing at gate voltage (VGS) = threshold voltage (VT), and it was constant at 115 mV/decade, thereby indicating that the conduction mechanism through band-to-band tunneling influenced the on-state characteristics of the devices.

Effects of morphology and structure of electrolytic tin coating layers on the flow melting behaviors during reflow treatment (리플로우과정의 용융 거동에 미치는 전기주석 도금층의 결정 형상 및 구조의 영향)

  • 김태엽;조준형;이재륭;배대철;홍기정
    • Journal of the Korean institute of surface engineering
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    • v.33 no.5
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    • pp.373-380
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    • 2000
  • The flow melting behavior of the electrolytic tinplate during reflow treatment was investigated in terms of morphology and structure of coating layers which were electrodeposited with variation of electrolyte temperature. It was commonly found that the nucleation density of the electrodeposits showed little difference with the electrolyte temperature, and the growth of electrodeposited tin occurred along <100> direction of (002) plane. At low electrolyte temperature, the (002) plane of tin nucleated paralleling to the substrate and grew perpendicularly to the substrate, which rendered porous rod-like deposits. With increasing the temperature, the (002) plane nucleated declining $15^{\circ}$ to the substrate and also grew to the normal <100> direction, which enabled lateral growth of the tin crystals and rendered compact deposits. During reflow treatment, the matte deposit transformed to the reflowed state via transition regions consisted of contraction, island formation, and wetting . The matte deposits formed at low temperature exhibited wide transition regions because of poor thermal transfer between crystals due to their porous nature. While that formed at high temperature transformed very rapidly to the reflowed state by enhanced thermal transfer between the compact crystals.

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Effect of Cr/Ti/Al Elements on High Temperature Oxidation Behavior of a Ni-Based Superalloy with Thermal Exposure (고온 노출 니켈기 초내열합금 터빈 블레이드의 Cr/Ti/Al 성분이 고온 산화에 미치는 영향)

  • Byung Hak Choe;Sung Hee Han;Dae Hyun Kim;Jong Kee Ahn;Jae Hyun Lee;Kwang Soo Choi
    • Korean Journal of Materials Research
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    • v.33 no.2
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    • pp.77-86
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    • 2023
  • High-temperature oxidation of a Ni-based superalloy was analyzed with samples taken from gas turbine blades, where the samples were heat-treated and thermally exposed. The effect of Cr/Ti/Al elements in the alloy on high temperature oxidation was investigated using an optical microscope, SEM/EDS, and TEM. A high-Cr/high-Ti oxide layer was formed on the blade surface under the heat-treated state considered to be the initial stage of high-temperature oxidation. In addition, a PFZ (γ' precipitate free zone) accompanied by Cr carbide of Cr23C6 and high Cr-Co phase as a kind of TCP precipitation was formed under the surface layer. Pits of several ㎛ depth containing high-Al content oxide was observed at the boundary between the oxide layer and PFZ. However, high temperature oxidation formed on the thermally exposed blade surface consisted of the following steps: ① Ti-oxide formation in the center of the oxide layer, ② Cr-oxide formation surrounding the inner oxide layer, and ③ Al-oxide formation in the pits directly under the Cr oxide layer. It is estimated that the Cr content of Ni-based superalloys improves the oxidation resistance of the alloy by forming dense oxide layer, but produced the σ or µ phase of TCP precipitation with the high-Cr component resulting in material brittleness.

Numerical Study of Lightweight FRP Bridge Deck System induced by Thermal Stress by Fire (화재 발생시 열응력에 의한 복합재료 과량 시스템의 거동에 관한 연구)

  • Jung Woo-Young;Lee Hyung-Kil;Park Hui-Kwang;Shim In-Seob;Song Young-Jin
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2006.04a
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    • pp.928-931
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    • 2006
  • Due to their light weight, high stiffness-to-weight and strength-to-weight ratios, and potentially high resistance to environmental degradation, resulting in lower life-cycle costs, polymer composites, are increasingly being considered for use in civil infrastructure applications. Recently, an FRP deck has been installed on a state highway, located in New York State. In this study, a thermal stress analysis was conducted using finite element method to study failure mechanisms of the superstructure. This analysis evaluated small and large temperature gradient effects on the FRP deck considering lightweight of FRP deck and ply orientations at the interface between steel girders and FRP deck Finite element model was verified using the load tests of the bridge deck. Finally, the analytical results shows the possible failure mechanism of FRP deck under various temperature changes and its corresponding index is suddenly varied depending on the rapid change of temperature on the deck plate.

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