• 제목/요약/키워드: high-temperature shift

검색결과 266건 처리시간 0.026초

펄스 레이저 증착법으로 증착된 $MgTiO_3$박막의 전기적 특성 분석 (Electrical Properties Of MgTiO$_3$ thin films grown by pulsedd laser deposition method)

  • 안순홍;노용한;이영훈;강신충;이재찬
    • 한국진공학회지
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    • 제9권3호
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    • pp.249-253
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    • 2000
  • 차세대 마이크로파 유전체 소자에 응용하기 위한 $MgTiO_3$ 박막을 펄스 레이저 증착법(PLD, pulsed laser deposition)을 이용하여 400-$500^{\circ}C$에서 비정질 상태로 실리콘 기판 위에 성장시킨 후 전기적 특성을 분석하였다. PLD로 증착된 $MgTiO_3$ 박막의 전기적 특성은 성장시 온도에 의존하였다. 즉, 증착 온도가 낮아짐에 따라 $MgTiO_3$ 박막 내부에 존재하는 이상정전하 결함 밀도가 증가하였으며, 이들 결함과 실리콘 기판과의 전하교환에 의하여 High Frequency(HF) C-V 곡선이 음의 방향으로 이동하는 현상이 관측된 것으로 사료된다. 또한, 증착 온도간 HF C-V 곡선 이동 폭 및 이상정전하 밀도는 ~l00$\AA$ 두께의 $SiO_2$ 중간층을 사용할 경우에 현저히 감소함을 확인하였다.

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고분자 전해질 연료전지용 플라즈마 개질 시스템에서 수소 생산 및 CO 산화반응에 관한 연구 (Study on Hydrogen Production and CO Oxidation Reaction using Plasma Reforming System with PEMFC)

  • 홍석주;임문섭;전영남
    • Korean Chemical Engineering Research
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    • 제45권6호
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    • pp.656-662
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    • 2007
  • 고분자 전해질 연료전지 운전에 필요한 수소 공급 장치로서 플라즈마 개질 방법을 이용한 개질기와 일산화탄소 산화반응을 위한 전이 반응기를 설계 및 제작하였다. GlidArc 방전을 이용한 저온플라즈마 개질기는 Ni 촉매를 동시에 사용하여 $CH_4$ 개질함으로서 $H_2$ 선택도를 증대하였다. 개질기의 변수별 연구로서 촉매 온도, 가스 조성비, 전체 가스유량, 전압변화 그리고 개질 특성 및 최적 수소 생산조건을 연구하였으며, 전이반응기의 변수별 연구로서 선택적 산화반응기(PrOx)에 주입되는 공기량, 전이 반응기에 주입되는 수증기량 그리고 온도에 대하여 연구하였다. 플라즈마 개질기에서 최대 수소 생산 조건은 $O_2/C$ 비가 0.64, 가스유량은 14.2 l/min, 촉매 반응기 온도 $672^{\circ}C$ 그리고 유입전력이 1.1 kJ/L일 때 41.1%로 최대 수소 농도를 나타냈다. 그리고 이때의 $CH_4$ 전환율, $H_2$ 수율 그리고 개질기 에너지 밀도는 각각 88.7%, 54%, 35.2%를 나타냈다. 전이 반응기에서 모사된 개질 가스로부터 최대 CO 전환율을 보이는 조건은 2단으로 구성된 PrOx에 주입되는 $O_2/C$ 비가 0.3, HTS에서 주입되는 수증기 주입량 비가 2.8 그리고 HTS, LTS, PrOx I, PrOx II 반응기 온도가 475, 314, 260, $235^{\circ}C$ 일때 가장 높은 CO 전환율을 나타냈다. 플라즈마를 이용한 반응기는 예열 시간은 30분이 소요되었으며, 전이 반응기에서 나오는 최종 개질 가스의 조성은 $H_2$ 38%, CO<10 ppm, $N_2$ 36%, $CO_2$ 21% 그리고 $CH_4$ 4%로 나타냈다.

저 에너지 이온빔 조사에 따른 비정질 $Se_{75}Ge_{25}$ 박막의 광학적 특성 (The optical characteristics of amorphous $Se_{75}Ge_{25}$ thin film by the low-energy lon beam exposure)

  • 이현용;오연한;정홍배
    • E2M - 전기 전자와 첨단 소재
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    • 제7권2호
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    • pp.100-106
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    • 1994
  • A bilayer film consisting of a layer of a-Se$_{75}$ Ge$_{25}$ with a surface layer of silver -100[.angs.] thick and a monolayer film of a-Se$_{75}$ Ge$_{25}$ are irradiated with 9[keV] Ga$^{+}$ ion beam. The Ga$^{+}$ ion (10$^{16}$ [ions/cm$^{2}$] exposed a-Se$_{75}$ Ge$_{25}$ and Ag/a-Se$_{75}$ Ge$_{25}$ thin films show an increase in optical absorption, and the absorption edge on irradiation with shifts toward longer wavelength. The shift toward longer wavelength called a "darkening effect" is observed also in film exposure to optical radiation(4.5*10$^{20}$ [photons/cm$^{2}$]). The 0.3[eV] edge shift for ion irradiation films is about twice to that obtained on irradiation with photons. These large changes are primarily due to structural changes, which lead to high etch selectivity and high sensitivity.

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XLPE에서 보이드 위치변화에 따른 부분방전특성 (Partial Discharge Characteristics due to shift of Void Position in XLPE)

  • 김탁용;양재훈;김원종;신현택;김왕곤;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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    • pp.86-89
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    • 2004
  • To estimate a electrical performance of the extra high voltage XLPE cable the discharge properties due to shift of void position were investigated. The ${\phi}-q-n$ properties have been measured at room temperature by rising voltage ratio of 0.5[kV]. An obtained data was stored to personal computer through A/D converter. The period of applied wave form and discharge values were divided into 64 parts and discharge values generated during 10 seconds were accumulated by phases. As a result, it was confirmed that the charge, phase angle and counts of discharge changed due to void position.

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XLPE 내부 보이드 위치변화에 따른 부분방전 특성 및 수명예측 (Life Time Diagnosis and Partial Discharge Characteristics due to shift of Void Position in XLPE)

  • 김탁용;조경순;신현택;김귀열;이강성;이충호;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.256-257
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    • 2005
  • To estimate a electrical performance of the extra high voltage XLPE cable the discharge properties due to shift of void position were investigated. The $\Phi-q-n$ properties have been measured at room temperature by rising voltage ratio of 0.5[kV]. An obtained data was stored to personal computer through A/D converter. The period of applied wave form and discharge values were divided into 64 parts and discharge values generated during 10 seconds were accumulated by phases. As a result, it was confirmed that the charge, phase angle and counts of discharge changed due to void position.

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시간 평균 ESPI를 이용한 진동 물체의 공진 주파수 검출 신뢰도 검증에 대한 연구 (A Study on Reliability Verification of Resonance Frequency Detection of Vibration Object using Time-average ESPI)

  • 홍경민;유원재;강영준;이동환
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.930-933
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    • 2005
  • Non-destructive inspection techniques using laser have been breading their application areas as well as growing their measurement skills together with the rapid development of circumferential technology like fiber optics. computer and image processing The ESPI technique is already on the stage of on-line testing with commercial products in developed country nations. Especially, this technique is expected to be applied to the nuclear industry, automobile and aerospace because it is proper for the vibration measurement and it can be applied to objects of a high temperature. This paper describes the use of the ESPI system for measuring vibration patterns on the reflecting objects. Using this system, high-quality Jo fringes for identifying mode shapes are displayed. A bias vibration is introduced into the reference beam to shift the Jo fringes so that fringe shift algorithms can be used to determine vibration amplitude. Using this method. amplitude fields for vibrating objects were obtained directly from the time-average interferometer recorded by the ESPI system.

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소방관의 근골격계 증상과 직무 스트레스에 관한 연구 (The study for musculoskeletal symptoms and job stress in firemen)

  • 김정만;서병성;정갑열;김동일;김원술;조한석;김진욱;권재;윤동영;김정일;노영만
    • 한국산업보건학회지
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    • 제17권2호
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    • pp.111-119
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    • 2007
  • Firemen are directly exposed to various harmful chemicals, physical factors and mental stress during rescue and fire-fighting. In fire extinguishing, unstable posture, poisonous gas, dust, high temperature and heavy equipments are possible hazardous factors. The alertness for emergency, shift work, job strain and stress are also possibly hazardous. Therefore, this study aimed to investigate the prevalence of musculo-skeletal symptoms and job stress and to determine risk factors in firemen. This study was carried out in a group of 226 firemen in Busan City, Korea. Standardized Nordic Questionnaire was used to investigate the prevalence of musculo-skeletal symptoms and Psycho-social Well-being Index (abbreviated PWI) was used to investigate the prevalence of job stress. General and occupational characteristics were included education, marital status, alcohol and smoking history, working duration, and work shift system. Body mass index (BMI) scores were calculated by physical examination including height and weight. Concerning musculo-skeletal complaints, the commonest site was neck, and shoulder, lower back, upper back were the next. Complaint site above one area of body was about 80%. From multiple logistic regression analysis, working duration was significant variable in musculo-skeletal symptoms. Odds ratio were 15.4 in working duration. About 16.8% was high risk stress group. From multiple logistic regression analysis, shift work and alcohol drinking were significant variables in PWI scores. Odds ratios were 2.25 in shift work. Accordingly, interventions are needed for health promotion of long term and shift worker.

어븀 첨가 광섬유형 링 레이저와 광섬유 격자 기반 센서를 이용한 원거리의 온도 및 전류 측정 (Remote Measurement of a Distant Temperature and Current using Fiber Bragg Grating Sensors and Erbium-doped Fiber Ring Laser)

  • 손경락;심준환;양규식
    • Journal of Advanced Marine Engineering and Technology
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    • 제32권8호
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    • pp.1257-1262
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    • 2008
  • A long-distance remote sensing of temperature and current based on a fiber Bragg grating (FBG) is proposed and demonstrated. The thermal expanding effect of the epoxy and the Er-doped fiber ring laser (EFRL) are applied to the sensor system to enhance the temperature and current sensitivity. An EFRL with a 5 km-single-mode fiber and a FBG shows a high extinction ratio of more than 60 dB and a low power fluctuation of less than 1 dB. The metal wires are used to supply the current to the sensors. When the NOA65 puts on the FBG as a thermal expanding material, the temperature and current sensitivity of the lasing wavelength shift are about $30\;pm/^{\circ}C$ and 3pm/mA, respectively. The proposed sensing scheme is useful for measurement of current or temperature at a distant object of more than several km.

In0.27Ga0.73N/GaN 다중 양자우물 구조에 대한 광전기적 특성 (Optoelectronics Properties of In0.27Ga0.73N/GaN Multi-Quantum-Well Structure)

  • 박헌보;배인호;김기홍
    • 한국재료학회지
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    • 제17권9호
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    • pp.489-492
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    • 2007
  • Temperature and injection current dependence of elctroluminescence(EL) spectral intensity of the $In_{0.27}Ga_{0.73}N/GaN$ multi-quantum-well(MQW) have been studied over a wide temperature and as a function of injection current level. EL peaks also show significant broadening into higher photon energy region with the increase of injection current. This is explained by the band-filling effect. When temperature is slightly increased to 300 from 15 K, the EL emission peak showed red-blue-red shift. It can be explained by the carrier localization by potential fluctuation of multiple quantum well and band-gap shrinkage as temperature increase. It is found that a temperature-dependent variation pattern of the EL efficiency under very low and high injection currents show a drastic difference. This unique EL efficiency variation pattern with temperature and current is explained field effects due to the driving forward bias in presence of internal(piezo and spontaneous polarization) fields.

$BaTiO_3$에서 $Cd_5(PO_4)_3Cl$의 첨가로 인한 Curie 온도변화 (Variation of the Curie Temperature in $BaTiO_3$ Doping $Cd_5(PO_4)_3Cl$)

  • 김광철
    • 반도체디스플레이기술학회지
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    • 제10권1호
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    • pp.95-99
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    • 2011
  • $(1-x)BaTiO_3+(x)Cd_5(PO_4)_3Cl$ ceramics were prepared by the conventional ceramic technique, i.e., solid state reaction at high temperature. The concentration of $Cd_5(PO_4)_3C$ was varied from 0.01 to 0.15 mole fraction. In order to study the phase transitions of our ceramics, the Raman scattering spectra were measured as functions of concentration x and temperature. It was found that the soluble limit of $Cd_5(PO_4)_3Cl$ in $BaTiO_3$ was the x=0.05 composition and $BaTiO_3$ phase disappeared above x=0.10. A new phase identified as $Ba_4Ti_3P_2O_{15}$ was detected in all samples of our compositions. The Curie temperature shifts up to $130^{\circ}C$ as the concentration x increases from zero to 0.05 and shift down to $95^{\circ}C$ as further increases to 0.08. For the increase of the Curie temperature, it is suggested that it can result from the inhibition of displacement of $Ti^{4+}$ in the distorted octahedron due to well dispersed $Ba_4Ti_3P_2O_{15}$ and $Cd_5(PO_4)_3Cl$ phase.