• Title/Summary/Keyword: high-performance surfactant

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A Study on Heat and Mass Transfer Characteristics of LiBr-$H_2$O Solution with a Sufactant Flowing over a Cooled Horizontal Tube (계면활성제 첨가시 수평 냉각관 외부를 흘러내리는 LiBr수용액의 열 및 물질전달 특성에 관한 연구)

  • 김경희;설신수;이상용
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.4
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    • pp.341-349
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    • 2002
  • Heat and mass transfer characteristics of a surfactant-added LiBr-$H_2O$ solution flowing over a single horizontal tube were examined experimentally. The parameters considered were surfactant (2-ethyl-1-hexanol) concentration, solution temperature at the top of the tube and absorber pressure. Even with an amount of the surfactant below the solubility limit, heat and mass transfer performances were enhanced tremendously. The Nusselt and Sherwood numbers increased by about 70% and 340%, respectively, when 10 ppm of the surfactant was added. However, an excess amount of the surfactant in the solution did not bring a further enhancement. The absorption performance deteriorated when the non-condensable gases were extracted from the system (by a vacuum pump) since the vaporized surfactant was also extracted during the process. Therefore, it is desirable to add a sufficient amount of the surfactant (more than 10 ppm) to maintain high performance of absorption.

The Effect of Chemical Admixtures on Removal of Scattered Dust

  • Son, Ho Jeong;An, Jung Min;Chung, Chul-Woo;Lee, Jae-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.6
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    • pp.594-601
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    • 2013
  • One of the important problems associated with building demolition is the dust generated during the work. The only way to reduce the demolition dust is to use a dust net during water spraying. However, it is difficult to supply the necessary amount of water to remove demolition dust, thus making it difficult to apply this method on a demolition site. This work attempted to find an alternative approach to dust removal by incorporating surfactant and high range AE water reducer in the water being sprayed. Through the experiment, it was found that the addition of surfactant did not contribute to the removal of demolition dust. However, the use of high range AE water reducer showed better performance than spraying plain water, indicating that some amount of demolition dust had been adsorbed on the high range AE water reducer.

Trend on Development and Application of High Performance Surfactants for Detergents (세제용 고기능성 계면활성제의 개발 및 응용 동향)

  • Rang, Moon-Jeong
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.126-133
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    • 2009
  • The surfactants applied in household detergents and industrial cleansers should satisfy the requirement of not just the basic function such as emulsification, solubilisation, dispersion, detergency, wetting and foaming, but also the economical efficiency and the safety to human and environment. In the viewpoint of the sustainable development, the surfactants, moreover, have to reduce raw materials and energy consumption and waste disposal when they are being manufactured and also consumed for their purposes. New high-performance surfactants have been extensively studied and developed in order to respond the change in social and economical environment. Noticeable progresses have been achieved so far, which are the significant increase in solubility and surface activity through the minor modification of existing surfactant molecular structure and the synergistic increase in a surface activity shown in the mixed surfactant system of anionic and cationic surfactants. In this review, the important and meaningful progresses achieved recently in technological advance and practical application will be summarized and discussed.

Dispersion of Li[Ni0.2Li0.2Mn0.6]O2 Powder by Surfactant for High-power Li-ion Cell

  • Yun, Su-Hyun;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1598-1602
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    • 2009
  • The particle size of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode powder was controlled effectively by dispersion using lauric acid as a surfactant. The samples treated by lauric acid showed smaller particles of approximately half the original size compared to the particles of a pristine sample. A structural change due to the dispersion of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ powder was not detected. The rate performance of the Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode was improved by dispersion using lauric acid, which was likely due to the decrease of the particle size. In particular, a sample dispersed pristine powder using lauric acid (L2) presented a greatly enhanced discharge capacity and capacity retention at a high C rate. The discharge capacity of a pristine sample was only 133 m$Ahg^{-1}$ (3C rate) and 96 m$Ahg^{-1}$ (12C rate) at the tenth cycle. In contrast, the L2 electrode delivered higher discharge capacities of 160 m$Ahg^{-1}$ (3C rate) and 129 m$Ahg^{-1}$ (12C rate) at the tenth cycle. The capacity retention at a rate of 12C/2C was also enhanced from ~ 45% (pristine sample) to 57% (L2) by treatment with lauric acid.

A Surfactant-based Method for Carbon Coating of LiNi0.8Co0.15Al0.05O2 Cathode in Li Ion Batteries

  • Chung, Young-Min;Ryu, Seong-Hyeon;Ju, Jeong-Hun;Bak, Yu-Rim;Hwang, Moon-Jin;Kim, Ki-Won;Cho, Kwon-Koo;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2304-2308
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    • 2010
  • A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

Development of Perfluoroalkyl Derivative for $Cr^{3+}$ Adsorbent Promotion Process (3가 크롬 흡착 증진용 과불소 알킬유도체 제조 및 적용공정 개발)

  • Shin, Jong-Sub;Kum, Chang-Hun;Yun, Jong-Kuk;Park, Il-Kyu
    • Clean Technology
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    • v.14 no.3
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    • pp.193-203
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    • 2008
  • A surfactant is used to assist the effect of cleaning, dispersibility and adhesion during leather manufacturing process. Existing surfactant for that process includes many hydrophilic groups that may cause problem such as stain, bad water resistance and poor durability, etc. It is potential problem to make high-performance property for future leather market. In this study, we have synthesized the fluorinated surfactant of which property decreases surface tension, increases dispersion, cleaning effect and the better chrome absorption by the high bond energy of C-F to complement weakness that the present alkyl derivative surfactants have. Using fluorinated surfactant, we can confirm that dispersion is increased, chrome absorption ratio is augmented with high osmosis and coherence, chrome content in the tanning waste water is reduced, BOD and COD contents are diminished and physical characteristics are improved.

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A Study on Fire-proof Characteristics of Ultra High Strength Concrete Using Polyamide Fiber (폴리아미드섬유를 사용한 초고강도 콘크리트의 내화성능에 관한 연구)

  • Lee, Soo-Choul;Jeon, Joong-Kyu;Jeon, Chan-Ki
    • Journal of the Society of Disaster Information
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    • v.7 no.4
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    • pp.286-293
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    • 2011
  • Accordingly architectural structure is getting high-rise and bigger, a use of high strength and high performance concrete has been increased. High performance concrete has cons of explosion in a fire. This explosion in the fire can cause the loss of the sheath on a concrete surface, therefore it effects that increasing a rate of heat transmission between the steel bar and inner concrete. Preventing this explosion of high performance concrete in the fire, many kinds of researches are now in progressing. Typically, researches with using polypropylene-fiber and steel-fiber can prove controling the explosion, but the reduction of mobility was posed as a problem of workability. Consequently, to solve the problem as mentioned above, concrete cans secure fire resisting capacity through the using of coating liquid, including Ester-lubricant and non-ionic characteristic surfactant. This research has been drawn a ideal condition in compressive strength areas of concrete by an experiment. When applying 13mm of polyamide fiber, proper fiber mixing volume by compressive strength areas of concrete more than 2.5kg in 160MPa. These amount of a compound can control the explosion.

Effects of Non-ionic Surfactant Supplementation on Ruminal Fermentation, Nutrient Digestibility and Performance of Beef Steers Fed High-roughage Diets

  • Ahn, Gyu-chul;Kim, Jeong-hoon;Park, Eun-kyu;Oh, Young-Kyoon;Lee, Gang-yeon;Lee, Jung-il;Kim, Chong-min;Park, Keun-kyu
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.7
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    • pp.993-1004
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    • 2009
  • Three experiments were conducted to determine the effects of non-ionic surfactant (NIS) supplementation on ruminal fermentation, nutrient digestibility and performance of beef steers fed high-roughage diets. The objective of experiment 1 was to investigate the effects of NIS supplementation on in vitro ruminal fermentation of cultures administered with corn and barley as grain substrate and rice straw and timothy hay as roughage substrate. The in vivo ruminal fermentation, nitrogen balance and digestibility of nutrients were also examined with steers fed a high-roughage diet in experiment 2. The aim of experiment 3 was to determine the responses to NIS of growing steers fed a high-roughage diet. In experiment 1, ammonia nitrogen concentration for NIS supplementation was higher (p<0.05) than for the control with all substrates. However, concentrations of total volatile fatty acid (VFA), acetate, butyrate and valerate of the incubated roughage substrates, rice straw and timothy hay, were higher (p<0.05) for NIS supplementation than for the control whereas VFA concentrations in the cultures of corn and barley were unaffected. These results indicated that effects of NIS on ruminal fermentation are diet dependent, specifically on roughage sources. In experiment 2, ruminal pH of steers supplemented with NIS was lower (p<0.05) than the control. Ruminal concentrations of ammonia nitrogen, acetate, total VFA and urinary concentrations of purine derivatives were increased (p<0.05) by NIS supplementation. In experiment 3, supplementation of NIS increased (p<0.05) intakes of total feed and corn silage, average daily gain, and feed efficiency of growing steers although they varied depending on supplementation level. Due to the roughage-specific feature of NIS effects, NIS appears to enhance ruminal fermentation of fibrous parts of feeds and, consequently, performance of steers fed a high-roughage diet.

Effects of Surfactants on Dispersion Behavior of Vectran® in Water - Evaluation of Fibers Dispersion Behavior in Water with Quadrat Analysis - (Vectran®의 수중 분산 거동에 미치는 계면활성제의 영향(I) - 쿼드라트법을 결합한 수중 분산 거동 평가 -)

  • Kang, Yoo-Jung;Lee, Do-Hyun;Song, Sun-Hye;Bae, Jin-Seok
    • Textile Coloration and Finishing
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    • v.26 no.4
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    • pp.339-346
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    • 2014
  • To give a positive effect on dispersion behavior of high performance fibers $Vectran^{(R)}$ in water with reference to wet-laid nonwoven technology, 9 kinds of sulfonate type anionic surfactants were chosen to study. After dispersion experiment, the number and the area occupied by fibers in each sample were counted and figured to calculate the index of dispersion in conjunction with quadrat analysis. Similar tendency was observed in the results of two experiments. The sample without addition of any surfactant resulted in the most aggregated dispersion behavior. As the length of alkyl group attached to sulfonate increases, the sample shows more dispersed behavior. The sample with the surfactant having the aryl group and the longer alkyl group shows the most dispersed behavior and it can be seen with the naked eye as well.

A Study on Synthesis of Organic Plant Surfactant and Its Solubilizing Action on Bergamot Oil (유기농 식물성 계면활성제의 합성과 베르가못오일에 대한 가용화력에 관한 연구)

  • Kim, In-Young;Noh, Ji-Min
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1208-1218
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    • 2019
  • The study is on the cosmetic solubilizing power of organic plant surfactants. The blended high purity polyglyceryl-10 oleate and polyglyceryl-10 stearate mixtures were synthesized using organically certified raw materials to develop surfactants having excellent solubilizing power. The mixture is called "Solubil ORG-1300". The appearance of this material is a pale yellowish paste, with a specific odor. The specific gravity was 1.12 and it was high purity that acid value was 0.072±0.1. The HLB value of this natural surfactant was averaged = 15.1 and calculated through the Griffin equation. Mechanically it is explained how organic surfactant are available with fragrance and oils. The solubilizing test was determined by eye evaluation method through the dissolving performance test for the two oils and measured the transmittance at 890 nm using a UV spectrophotometer to measure the transparency. The results showed that the concentration of surfactant needed to make Bergamot oil available requires approximately more 2 times. It was also found that the concentration of surfactant needed to make the tocoperyl acetate available was about 8 times higher. Experiments on the solubility resulting from pH changes showed stabilized usable solubilizing power even in acidic areas of pH=3.5, neutral areas of pH=7.2, and alkaline areas of pH=1.5. Experiments on the solubility according to pH variation showed good solubility stabilized in acidic areas of pH=3.5, neutral areas of pH=7.2, and alkaline areas of pH=11.5. As an application of cosmetics, the company successfully developed a prescription for moisturizing activity based on these results, it is expected that a wide range of applications will be available for skin care, baby lotion, sensitivity or atopic skin cosmetics.