• Corrosion Science and Technology
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• 제9권2호
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• pp.98-103
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• 2010

In order to further reduce the cost without reducing the corrosion resistance, a high-manganese austenitic alloy for sink roll or stabilizer roll in continuous hot-dip coating lines was developed. A systematic study of corrosion behavior of the high-manganese austenitic alloy in pure zinc bath at $490^{\circ}C$ was carried out. The results shows that, the high-manganese austenitic alloy shows better corrosion resistance than 316L steel. The corrosion rate of the high-manganese austenitic alloy in pure zinc bath is calculated to be approximately $6.42{\times}10^{-4}g{\cdot}cm^{-2}{\cdot}h^{-1}$, while the 316L is $1.54{\times}10^{-3}g{\cdot}cm^{-2}{\cdot}h^{-1}$. The high-manganese austenitic alloy forms a three-phase intermetallic compound layer morphology containing ${\Gamma$}, ${\delta}$ and ${\zeta}$ phases, while the 316L is almost ${\zeta}$ phase. The ${\Gamma}$ and ${\delta}$ phases of the high-manganese austenitic alloy contain about 8.5 wt% Cr, the existence of Cr improve the stabilization of phases, which slow down the reaction of Fe and Zn, improve the corrosion resistance of the high-manganese austenitic alloy. So substitute the nickel with the manganese to manufacture the high-manganese austenitic alloy of low cost is feasible.

• 상하수도학회지
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• 제21권4호
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• pp.503-508
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• 2007

Small scale D-water treatment plant(WTP) where has slow sand filtration was using raw water containing high concentration of manganese (> 2mg/l). The raw water was pre-chlorinated for oxidation of manganese and resulted in difficulty for filtration. Thus, sometimes manganese concentration and turbidity were over the water quality standard. Two stage rapid manganese sand filtration pilot plant which can treat $200m^3/d$ was operated to solve manganese problem in D-WTP. The removal rate of manganese and turbidity were about 38% and 84%, respectively without pH control of raw water. However, when pH of raw water was controlled to average 7.9 with NaOH solution, the removal rate of manganese and turbidity increased to 95.0% and 95.5%, respectively and the water quality of filtrate satisfied the water quality standard. Manganese content in sand was over 0.3mg/g which is Japan Water Association Guideline. The content in upper filter was 5~10 times more than that of middle and lower during an early operation but the content in middle and lower filter was increased more and more with increase of operation time. This result means that the oxidized manganese was adsorbed well in sand. Rapid manganese sand filter was backwashed periodically. The water quality of backwash wastewater was improved by sedimentation. Thus, turbidity and manganese concentration decreased from 29.4NTU to 3.09NTU and from 1.7mg/L to 0.26mg/L, respectively for one day. In Jar test of backwash wastewater with PAC(Poly-aluminum chloride), optimum dosage was 30mg/L. Because the turbidity of filtrate was high as 0.76NTU for early 5 minute after backwash, filter-to-waste should be used after backwash to prevent poor quality water.

• 동아시아식생활학회지
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• 제7권2호
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• pp.143-151
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• 1997

The purpose of this study was to investigate the effect of iron and selenium intakes on utilization of manganese in rats fed adequate, 2-fold, 4-fold iron and adequate, high selenium for 6 weeks. There was no difference feed intake across iron and selenium containing diet groups. Body weight gain in 2-fold iron and high selenium group(MFeHSe) was significantly higher than those in other groups. Serum iron level was increased with iron increment, and liver iron content was decreased with selenium supplementation. Selenium and manganese contents in tissues were decreased with iron increment. In the case of manganese balance, manganese excretion through feces was significantly increased as iron intake was increased. However, retention and apparent absorption of manganese were not significantly affected by dietary iron. From these results, it could be suggested that the supplementations of iron and selenium affected the manganese utilization. Therefore, it must be considered interaction with various minerals in micro-nutrient supplementations.

• 한국재료학회지
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• 제29권3호
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• pp.189-195
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• 2019

The effect of C, Mn, and Al additions on the tensile and Charpy impact properties of austenitic high-manganese steels for cryogenic applications is investigated in terms of the deformation mechanism dependent on stacking fault energy and austenite stability. The addition of the alloying elements usually increases the stacking fault energy, which is calculated using a modified thermodynamic model. Although the yield strength of austenitic high-manganese steels is increased by the addition of the alloying elements, the tensile strength is significantly affected by the deformation mechanism associated with stacking fault energy because of grain size refinement caused by deformation twinning and mobile dislocations generated during deformation-induced martensite transformation. None of the austenitic high-manganese steels exhibit clear ductile-brittle transition behavior, but their absorbed energy gradually decreases with lowering test temperature, regardless of the alloying elements. However, the combined addition of Mn and Al to the austenitic high-manganese steels suppresses the decrease in absorbed energy with a decreasing temperature by enhancing austenite stability.

• 한국재료학회지
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• 제26권7호
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• pp.353-358
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• 2016

The hydrogen embrittlement of two austenitic high-manganese steels was investigated using tensile testing under high-pressure gaseous hydrogen. The test results were compared with those of different kinds of austenitic alloys containing Ni, Mn, and N in terms of stress and ductility. It was found that the ultimate tensile stress and ductility were more remarkably decreased under high-pressure gaseous hydrogen than under high-pressure gaseous argon, unlike the yield stress. In the specimens tested under high-pressure gaseous hydrogen, transgranular fractures were usually observed together with intergranular cracking near the fracture surface, whereas in those samples tested under high-pressure gaseous argon, ductile fractures mostly occurred. The austenitic high-manganese steels showed a relatively lower resistance to hydrogen embrittlement than did those with larger amounts of Ni because the formation of deformation twins or microbands in austenitic high-manganese steels probably promoted planar slip, which is associated with localized deformation due to gaseous hydrogen.

• Tribology and Lubricants
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• 제36권2호
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• pp.88-95
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• 2020

In this study, we investigate the mechanical properties of high manganese steel, and the friction and wear characteristics of brake friction material containing this steel, for passenger car application, with the aim of replacing copper and copper alloys whose usage is expected to be restricted in the future. These steels are prepared using a vacuum induction melting furnace to produce binary and ternary alloys. The hardness and tensile strength of the high manganese steel decrease and the elongation increases with increase in manganese content. This material exhibits high values of hardness, tensile strength, and elongation; these properties are similar to those of 7-3 brass used in conventional friction materials. We fabricate high manganese steel fibers to prepare test pad specimens, and evaluate the friction and wear characteristics by simulating various braking conditions using a 1/5 scale dynamometer. The brake pad material is found to have excellent friction stability in comparison with conventional friction materials that use 7-3 brass fibers; particularly, the friction stability at high temperature is significantly improved. Additionally, we evaluate the wear using a wear test method that simulates the braking conditions in Europe. It is found that the amount of wear of the brake pad is the same as that in the case of the conventional friction material, and that the amount of wear of the cast iron disc is reduced by approximately 10. The high manganese steel is expected to be useful in the development of eco-friendly, copper-free friction material.

• 한국재료학회지
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• 제27권6호
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• pp.318-324
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• 2017

In this study, two Fe-30Mn-0.2C-(1.5Al) high-manganese steels with different surface conditions were hydrogen-charged under high temperature and pressure; then, tensile testing was performed at room temperature in air. The yield strength of the 30Mn-0.2C specimen increased with decreasing surface roughness(achieved via polishing), but that of the 30Mn-0.2C-1.5Al specimen was hardly affected by the surface conditions. On the other hand, the tendency of hydrogen embrittlement of the two high-manganese steels was not sensitive to hydrogen charging or surface conditions from the standpoints of elongation and fracture behavior. Based on the EBSD analysis results, the small decrease in elongation of the charged specimens for the Fe-30Mn-0.2C-(1.5Al) high-manganese steels was attributed to the enhanced dislocation pile-up around grain boundaries, caused by hydrogen.

• Korean Chemical Engineering Research
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• 제46권3호
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• pp.473-478
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• 2008

망간황화물이 NO의 선택적 촉매 환원에 미치는 영향을 반응성 및 속도론적평가와 TPR(Temperature Programmed Reduction), TGA분석을 통하여 고찰하였다. 망간산화물은 $200^{\circ}C$ 이하의 저온에서 우수한 질소산화물 전환을 보였으나, 망간황화물의 경우 황화정도에 따라 질소산화물 전환은 고온으로 전이하였다. 또한 질소산화물 전환율도 황화정도에 따라 감소하였다. TPR 실험결과 망간산화물들은 $160^{\circ}C$ 이하의 낮은 온도에서 환원이 시작되었으나 망간황화물은 $280^{\circ}C$ 이상의 온도에서 환원이 시작되었다. TPR 실험을 통한 환원 시작온도는 촉매의SCR 시작 온도와 관련이 있는 것으로 판단된다. 망간황화물의 활성화에너지는 다른 촉매에 비해 낮게 나타났으나 pre-exponential 상수 크기가 다른 촉매에 비해 1/1000배 만큼 작아 NO에 대한 활성이 낮게 나타났다. 천연망간광석은 함유된 다양한 금속산화물의 영향으로 순수한 망간산화물보다 낮은 온도에서 재생되었다.

• 한국물환경학회지
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• 제20권5호
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• pp.409-414
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• 2004

Pilot-scale experiments were performed for the treatment of bank filtrate contammg high manganese concentration around 2mg/L using rapid manganese sand filtration to investigate effects of oxidant dose and pH control on the removal efficiency of manganese. For theoretical dose ranges of oxidant (sodium hypochlorite) between 3 and 4mg/L, the manganese concentration of effluent was 0.57 mg/L, which corresponded to 72.5% removal and was higher than drinking water quality standards of 0.3mg/L. For excess dose ranges of oxidant between 4 and 8mg/L, the manganese concentration of effluent was reduced to 0.14mg/L, which corresponded to 94.5% removal, but the residual chlorine concentration was over 1.0mg/L. On the other hand, manganese removal efficiency drastically increased up to the value of 98.0%, which is equivalent to the effluent concentration of 0.03mg/L by controling pH to the range between 7 and 8 for the theoretical dose of oxidant. Consequently, these results indicated that appropriate dose of chemicals, such as oxidant and alkali, and continuous monitoring of manganese should be necessary to obtain efficient removal of manganese and to optimize the maintenance of treatment facilities for the treatment of bank filtrate with high concentration of manganese.

• 상하수도학회지
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• 제22권6호
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• pp.633-640
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• 2008

In this research, the $3.6m^3/day$ scale pilot plant consisting preozonation, coagulation, flocculation, and ceramic membrane processes was operated for long term period to evaluate the validity of ceramic membrane filtration process for treating lake water containing high concentration manganese. The higher concentration of dissolved manganese($Mn^{2+}$) was effectively oxidized to the bigger insoluble colloidal manganese ($MnO^2$) by 1~2 mg/L ozone. The colloidal manganese reacted with coagulant (poly aluminium chloride, PAC) and then formed the big floc. Ceramic membrane rejected effectively manganese floc during membrane filtration. Dissolved organic carbon(DOC) removal was dependent upon $Mn^{2+}$ concentration. While average $Mn^{2+}$ concentration was 0.43 and 0.85 mg/L in raw water, DOC removal rate in preozonation was 26.5 and 13.5%, respectively. The decrease rate of membrane permeability was faster without preozonation than with preozonation while membrane fouling decreased with NOM oxidation by ozone. In conclusion, raw water containing high concentration of manganese can be effectively treated in preozonation-coagulation-ceramic membrane filtration system.