Removal of High Concentration Manganese in 2-stage Manganese Sand Filtration

2단 망간모래여과에 의한 고농도 망간 처리

  • 김충환 (한국수자원공사 수자원연구원 상하수도연구소) ;
  • 윤종섭 (한국수자원공사 수자원연구원 상하수도연구소) ;
  • 임재림 (한국수자원공사 수자원연구원 상하수도연구소) ;
  • 김성수 (한국수자원공사 수자원연구원 상하수도연구소)
  • Received : 2007.08.01
  • Accepted : 2007.08.13
  • Published : 2007.08.15

Abstract

Small scale D-water treatment plant(WTP) where has slow sand filtration was using raw water containing high concentration of manganese (> 2mg/l). The raw water was pre-chlorinated for oxidation of manganese and resulted in difficulty for filtration. Thus, sometimes manganese concentration and turbidity were over the water quality standard. Two stage rapid manganese sand filtration pilot plant which can treat $200m^3/d$ was operated to solve manganese problem in D-WTP. The removal rate of manganese and turbidity were about 38% and 84%, respectively without pH control of raw water. However, when pH of raw water was controlled to average 7.9 with NaOH solution, the removal rate of manganese and turbidity increased to 95.0% and 95.5%, respectively and the water quality of filtrate satisfied the water quality standard. Manganese content in sand was over 0.3mg/g which is Japan Water Association Guideline. The content in upper filter was 5~10 times more than that of middle and lower during an early operation but the content in middle and lower filter was increased more and more with increase of operation time. This result means that the oxidized manganese was adsorbed well in sand. Rapid manganese sand filter was backwashed periodically. The water quality of backwash wastewater was improved by sedimentation. Thus, turbidity and manganese concentration decreased from 29.4NTU to 3.09NTU and from 1.7mg/L to 0.26mg/L, respectively for one day. In Jar test of backwash wastewater with PAC(Poly-aluminum chloride), optimum dosage was 30mg/L. Because the turbidity of filtrate was high as 0.76NTU for early 5 minute after backwash, filter-to-waste should be used after backwash to prevent poor quality water.

Keywords

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