• 제목/요약/키워드: high-energy density science

검색결과 664건 처리시간 0.023초

Nanocomposite Electrode Materials Prepared from Pinus roxburghii and Hematite for Application in Supercapacitors

  • SHRESTHA, Dibyashree
    • Journal of the Korean Wood Science and Technology
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    • 제50권4호
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    • pp.219-236
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    • 2022
  • Wood-based nanocomposite electrode materials were synthesized for application in supercapacitors by mixing nanostructured hematite (Fe2O3) with highly porous activated carbon (AC) produced from the wood-waste of Pinus roxburghii. The AC was characterized using various instrumental techniques and the results showed admirable electrochemical properties, such as high surface area and reasonable porosity. Firstly, AC was tested as an electrode material for supercapacitors and it showed a specific capacitance of 59.02 Fg-1 at a current density of 1 Ag-1, cycle life of 84.2% after 1,000 cycles (at a current density of 3 Ag-1), and energy density of 5.1 Wh/kg at a power density of 135 Wkg-1. However, when the AC was composited with different ratios of Fe2O3 (1:1, 2:1, and 1:2), there was an overall improvement in its electrochemical performance. Among the 3 ratios, 2:1 (AC:Fe2O3) had the best specific capacitance of 102.42 Fg-1 at 1 Ag-1, cycle life of 94.4% capacitance after 1,000 cycles (at a current density of 3 Ag-1), and energy density of 8.34 Wh/kg at a power density of 395.15 Wkg-1 in 6 M KOH electrolyte in a 3-electrode experimental setup with a high working voltage of 1.55 V. Furthermore, when Fe2O3 was doubled, 1:2 (AC:Fe2O3), the electrochemical capacitive performance of the electrode twisted and deteriorated due to either the accumulation of Fe2O3 particles within the composite or higher bulk resistance value of pure Fe2O3.

리튬금속과 고체전해질의 계면 반응 (Interfacial Reaction between Li Metal and Solid Electrolyte in All-Solid-State Batteries)

  • 김재헌
    • Corrosion Science and Technology
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    • 제22권4호
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    • pp.287-296
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    • 2023
  • Li-ion batteries have been gaining increasing importance, driven by the growing utilization of renewable energy and the expansion of electric vehicles. To meet market demands, it is essential to ensure high energy density and battery safety. All-solid-state batteries (ASSBs) have attracted significant attention as a potential solution. Among the advantages, they operate with an ion-conductive solid electrolyte instead of a liquid electrolyte therefore significantly reducing the risk of fire. In addition, by using high-capacity alternative electrode materials, ASSBs offer a promising opportunity to enhance energy density, making them highly desirable in the automotive and secondary battery industries. In ASSBs, Li metal can be used as the anode, providing a high theoretical capacity (3860 mAh/g). However, challenges related to the high interfacial resistance between Li metal and solid electrolytes and those concerning material degradation during charge-discharge cycles need to be addressed for the successful commercialization of ASSBs. This review introduces and discusses the interfacial reactions between Li metal and solid electrolytes, along with research cases aiming to improve these interactions. Additionally, future development directions in this field are explored.

아연-이온 배터리의 에너지 저장 성능 향상을 위한 망간산화물이 코팅된 흑연시트의 제조 (Synthesis of Manganese Oxide Coated Graphite Sheet for Zinc-Ion Batteries with Improved Energy Storage Performance)

  • 이영근;안건형
    • 한국재료학회지
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    • 제31권2호
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    • pp.68-74
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    • 2021
  • Zinc-ion Batteris (ZIBs) are recently being considered as energy storage devices due to their high specific capacity and high safety, and the abundance of zinc sources. Especially, ZIBs can overcome the drawbacks of conventional lithium ion batteris (LIBs), such as cost and safety issues. However, in spite of their advantages, the cathode materials under development are required to improve performance of ZIBs, because the capacity and cycling stability of ZIBs are mainly influenced by the cathode materials. To design optimized cathode materials for high performance ZIBs, a novel manganese oxide (MnO2) coated graphite sheet is suggested herein with improved zinc-ion diffusion capability thanks to the uniformly decorated MnO2 on the graphite sheet surface. Especially, to optimize MnO2 on the graphite sheet surface, amounts of percursors are regulated. The optimized MnO2 coated graphite sheet shows a superior zinc-ion diffusion ability and good electrochemical performance, including high specific capacity of 330.8 mAh g-1 at current density of 0.1 A g-1, high-rate performance with 109.4 mAh g-1 at a current density of 2.0 A g-1, and remarkable cycling stability (82.2 % after 200 cycles at a current density of 1.0 A g-1). The excellent electrochemical performance is due to the uniformly decorated MnO2 on the graphite sheet surface, which leads to excellent zinc-ion diffusion ability. Thus, our study can provide a promising strategy for high performance next-generation ZIBs in the near future.

Isoquinoline alkaloids supplementation on performance and carcass traits of feedlot bulls

  • Michels, Alex;Neumann, Mikael;Leao, Guilherme Fernando Mattos;Reck, Angela Maria;Bertagnon, Heloisa Godoi;Lopes, Leandro Samia;de Souza, Andre Martins;dos Santos, Leslei Caroline;Stadler, Edelmir Silvio Junior
    • Asian-Australasian Journal of Animal Sciences
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    • 제31권9호
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    • pp.1474-1480
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    • 2018
  • Objective: Isoquinoline Alkaloids, derived from one plant (Macleaya cordata) can be an alternative when it is desired to increase performance in feedlot cattle. However, results on these nutritional additives in high energy diets in ruminants are still incipient in literature. In this context, the objective of this study was to evaluate performance and carcass traits of feedlot bulls supplemented with sanguinarine, the main alkaloid presents in Macleaya cordata in high energy density diets. Methods: Thirty-two crossbred Angus-Nelore bulls with mean initial body weight of $365{\pm}10kg$ and mean initial age of $11{\pm}3$ months were used. The experiment lasted 119 days, with 14 days of adaptation and 105 experimental days. Experimental diet consisted of 85% whole corn grains and 15% protein-vitamin-mineral nucleus and supplied ad libitum. Treatments consisted of a control diet (CON) and a diet with sanguinarine supplementation (SAN) at a dosage of 4 g of product sufficient to provide 6 mg of sanguinarine/d. Experimental design was completely randomized. Results: Dry matter intake, average daily gain and feed conversion were similar (p>0.05) between treatments. However, SAN group animals had higher carcass yield (p = 0.045) and were more efficient in the transformation of dry matter consumed in carcass gain (p = 0.046) than CON. In addition, haptoglobin, increased throughout feedlot duration meaning high challenge for the animals due to the diet, but this behavior was similar (p>0.05) between treatments. Conclusion: Sanguinarine produced positive results in relation to carcass yield and could be used as an additive for bulls fed diets receiving high energy density diet.

고강력 PET Interlace Yarn 밀도변화가 Pack Style Shock Energy Absorber의 물성에 미치는 영향 (Effect of Density Variation of High Tenacity PET Interlace Yarn on the Physical Properties of Pack Style Shock Energy Absorber)

  • 조진원;권상준;최종덕;김상태;지병철;양성백;염정현
    • 한국염색가공학회지
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    • 제27권2호
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    • pp.132-141
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    • 2015
  • Fall-arrest systems(maximum arrest force and allowable free-fall) have been widely applied to provide a safe stop during fall incidents for various industrial activities. Fabric structure affects on the mechanical properties of shock energy absorber. The object of this study is to perform the basic research for the evaluation of the capacity of fall arrest energy absorber in relation to the different interlace yarn density. In this work, pack style energy absorber was prepared by weaving 10 types(Interlace yarn density used high tenacity PET 1000D : 60, 59, 58, 57, 56, 55, 54, 53, 52, 51). The paper presents the results of theoretical investigations of the performance of adjustable absorber during fall arrest. Dynamic load tests based on the EU fall protection equipment standard(CE : EN355:2002) were conducted. Results showed that the maximum arrest force by dynamic load test of energy absorber was satisfied with global standard(below 6,000N). Also, Maximum allowable free-fall of energy absorber showed below 1.75m.

Optimization of Barium Titanate Slip for Tape Casting Using Design of Experiments

  • Kwon, Sung-Wook;Darsono, Nono;Yoon, Dang-Hyok
    • 한국세라믹학회지
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    • 제43권9호
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    • pp.519-526
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    • 2006
  • A full-factorial design of experiments with three input factors and two levels for each factor including center points was utilized for the preparation and characterization of twelve types of $BaTiO_3$ slips for tape casting. Ceramic powders with different particle sizes, different milling methods such as high energy milling and conventional ball milling, and two types of dispersant with different polymeric species were chosen as input factors in order to investigate their effects on slip and on green tape properties. Tape casting, a small rectangular-shaped K-square preparation, characterization and quantitative data analysis using statistical software were followed. Ceramic powder was the most significant among three input factors for the output responses of slip viscosity and green tape density, showing more favorable results with large particles than with very fine ones. In addition, high energy milling for only 30 min was more efficient than 24h of conventional ball milling in terms of powder dispersion and milling. The optimum condition based on the experimental results was a slip exposed to high energy milling with large ceramic particles along with a methylethyl acetate dispersant.

이중에너지 엑스선 흡광분석법을 이용한 골밀도검사의 관리법 (Management Methods of Bone Mineral Density Examination Using Dual Energy X-ray Absorptiometry)

  • 김호성;김태형;김상현
    • 대한방사선기술학회지:방사선기술과학
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    • 제41권4호
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    • pp.351-360
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    • 2018
  • In recent years, demand for examination of bone mineral density (BMD) is increasing in Korea according aging society. Therefore, it is required to develop an efficient management program that can increase the safety and reliability of Dual Energy X-ray Absorptiometry (DXA) that can be applied to the criteria of the World Health Organization. It is necessary to develop a management program that can design a program to improve the accuracy and precision of the results of the analysis and to improve the accuracy of diagnosis of osteoporosis by development a high quality DXA report. It is recommended to prepare the examination manuals and to establish procedures of standard operating including the program to prevent the pitfalls during the examination, the compatibility evaluation of the examination data, and the contents of the radiation safety. In addition, relevant regulations on the production of high-quality DXA reports are required and government and related agencies should introduce individual and facility recognition programs through DXA measurement and education programs and training. It is considered that efforts should be made to prepare high quality DXA report by guidelines on all aspects of BMD for preparation about aging society.

IN718 초내열 합금의 고속 적층 제조 속도 확보를 위한 최적 VED 활용 공정 변수 제어 방안 연구 (Study for the Process Parameter Control to Achieve High Build Rate of Laser Powder Bed Fused IN718 Super Alloy Using Optimal VED)

  • 김상욱;김규식;손용호;이기안
    • 한국분말재료학회지
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    • 제29권5호
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    • pp.390-398
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    • 2022
  • Recently, considerable attention has been given to nickel-based superalloys used in additive manufacturing. However, additive manufacturing is limited by a slow build rate in obtaining optimal densities. In this study, optimal volumetric energy density (VED) was calculated using optimal process parameters of IN718 provided by additive manufacturing of laser powder-bed fusion. The laser power and scan speed were controlled using the same ratio to maintain the optimal VED and achieve a fast build rate. Cube samples were manufactured using seven process parameters, including an optimal process parameter. Analysis was conducted based on changes in density and melt-pool morphology. At a low laser power and scan speed, the energy applied to the powder bed was proportional to ${\frac{P}{\sqrt{V}}}$ and not ${\frac{P}{V}}$. At a high laser power and scan speed, a curved track was formed due to Plateau-Rayleigh instability. However, a wide melt-pool shape and continuous track were formed, which did not significantly affect the density. We were able to verify the validity of the VED formula and succeeded in achieving a 75% higher build rate than that of the optimal parameter, with a slight decrease in density and hardness.

Challenges and Design Strategies for Conversion-Based Anode Materials for Lithium- and Sodium-Ion Batteries

  • Kim, Hyunwoo;Kim, Dong In;Yoon, Won-Sub
    • Journal of Electrochemical Science and Technology
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    • 제13권1호
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    • pp.32-53
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    • 2022
  • Although lithium-ion batteries are currently the most reliable power supply system for various mobile applications, further improvement in energy density is still required as the need for batteries in large energy-consuming devices is rapidly growing. However, in the anode, the most widely commercialized graphite-based anode materials almost face theoretical limitations. In addition, sodium-ion batteries have been actively studied to replace expensive charge carriers with cheaper ones. Accordingly, conversion-based materials have been extensively studied as high-capacity anode materials in both lithiumion batteries and sodium-ion batteries because their theoretical capacity is twice or thrice higher than that of insertion-based materials. This review will provide a comprehensive understanding of conversion-based materials, including basic charge storage behaviors, critical drawbacks that should be overcome, and practical material design for high-performance.

Joule열이 Sn-3.5Ag 플립칩 솔더범프의 Electromigration 거동에 미치는 영향 (Effect of Joule Heating on Electromigration Characteristics of Sn-3.5Ag Flip Chip Solder Bump)

  • 이장희;양승택;서민석;정관호;변광유;박영배
    • 한국재료학회지
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    • 제17권2호
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    • pp.91-95
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    • 2007
  • Electromigration characteristics of Sn-3.5Ag flip chip solder bump were analyzed using flip chip packages which consisted of Si chip substrate and electroplated Cu under bump metallurgy. Electromigration test temperatures and current densities peformed were $140{\sim}175^{\circ}C\;and\;6{\sim}9{\times}10^4A/cm^2$ respectively. Mean time to failure of solder bump decreased as the temperature and current density increased. The activation energy and current density exponent were found to be 1.63 eV and 4.6, respectively. The activation energy and current density exponent have very high value because of high Joule heating. Evolution of Cu-Sn intermetallic compound was also investigated with respect to current density conditions.