• Title/Summary/Keyword: high-energy density science

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Effects of Sulfuric Acid Concentration and Alloying Elements on the Corrosion Resistance of Cu-bearing low Alloy Steels

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.17 no.4
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    • pp.154-165
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    • 2018
  • During the process of sulfur dioxide removal, flue gas desulfurization equipment provides a serious internal corrosion environment in creating sulfuric acid dew point corrosion. Therefore, the utilities must use the excellent corrosion resistance of steel desulfurization facilities in the atmosphere. Until now, the trend in developing anti-sulfuric acid steels was essentially the addition of Cu, in order to improve the corrosion resistance. The experimental alloy used in this study is Fe-0.03C-1.0Mn-0.3Si-0.15Ni-0.31Cu alloys to which Ru, Zn and Ta were added. In order to investigate the effect of $H_2SO_4$ concentration and the alloying elements, chemical and electrochemical corrosion tests were performed. In a low concentration of $H_2SO_4$ solution, the major factor affecting the corrosion rate of low alloy steels was the exchange current density for $H^+/H_2$ reaction, while in a high concentration of $H_2SO_4$ solution, the major factors were the thin and dense passive film and resulting passivation behavior. The alloying elements reducing the exchange current density in low concentration of $H_2SO_4$, and the alloying elements decreasing the passive current density in high concentration of $H_2SO_4$, together play an important role in determining the corrosion rate of Cu-bearing low alloy steels in a wide range of $H_2SO_4$ solution.

Utility AC Frequency to High Frequency ACPower Conversion Circuit with Soft Switching PWM Strategy

  • Sugimura Hisayuki;Ahmed Nabil A.;Ahmed Tarek;Lee Hyun-Woo;Nakaoka Mutsuo
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.5B no.2
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    • pp.181-188
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    • 2005
  • In this paper, a DC smoothing filterless soft switching pulse modulated high frequency AC power conversion circuit connected to utility. frequency AC power source is proposed for consumer induction heating hot water producer, steamer and super heated steamer. The operating principle of DC link filterless utility frequency AC-high frequency AC (HF AC) power conversion circuit defined as high frequency cycloinverter is described, which can operate under a principle of ZVS/AVT and power regulation based on alternate asymmetrical PWM in synchronization with the utility frequency single phase AC positive or negative half wave voltage. The dual mode modulation control scheme based on high frequency PWM and commercial frequency AC voltage PDM for the proposed high frequency cycloinverter are discussed to enlarge its soft switching commutation operating range for wide HF AC power regulation. This high frequency cycloinverter is developed for high frequency IH Dual Packs Heater (DPH) type boiler used in consumer and industrial fluid pipeline systems. Based on the experiment and simulation results, this high frequency cycloinverter is proved to be suitable for the consumer use IH-DPH boiler and hot water producers. The cycloinverter power regulation and power conversion efficiency characteristics are evaluated and discussed.

A comparison study of CORSIKA and COSMOS simulations for extensive air showers

  • Kim, Ji-Hee;Roh, Soon-Young;Ryu, Dong-Su;Kang, Hye-Sung
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.69.1-69.1
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    • 2012
  • Monte Carlo codes for extensive air shower (EAS) simulate the development of EASs initiated in the Earth's atmosphere by ultra-high energy cosmic rays (UHECRs) with energy exceeding - $10^{18}$ eV. Here, we compare EAS simulations with two different codes, CORSIKA and COSMOS, presenting quantities including the longitudinal distribution of particles, depth of shower maximum, kinetic energy distribution of particle at the ground, and calorimetric energy. In addition, the lateral distribution of local energy density far from the EAS core has been known as an important quantity to estimate the energy of UHECRs. We also present the lateral distribution function obtained from GEANT4 simulations for detector response.

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Li2S-Incorporated Separator for Achieving High-Energy-Density Li-S Batteries

  • Park, Jong Won;Kang, Jukyoung;Koh, Jeong Yoon;Caron, Arnaud;Kim, Seok;Jung, Yongju
    • Journal of Electrochemical Science and Technology
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    • v.11 no.1
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    • pp.33-40
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    • 2020
  • We present a new and facile design of a high-performance Li-S cell by integrating a Li2S-impregnated glass fiber separator together with a common sulfur cathode. We find that a considerable amount of Li2S is consumed amidst the first charge, and most of Li2S disappears at the end of the second charge. During the charge process, additional sulfur material is formed and contributes to a significant enhancement of the discharge capacity (~1400 mAh/g), compared with a control cell (~1260 mAh/g) without Li2S. Moreover, the Li2S containing cell exhibits much higher cycling stability (a 31% increase from ~840 to ~1100 mAh/g in the 100th cycle) and rate capability (a 30% increase from ~580 to ~750 mAh/g at 2 C) than the control cell. Our results indicate that adopting Li2S-containing separator is highly effective to improving the electrochemical performances of Li-S cells.

BaCeO3-BaZrO3 Solid Solution (BCZY) as a High Performance Electrolyte of Protonic Ceramic Fuel Cells (PCFCs) (BaCeO3-BaZrO3 고용체(BCZY) 기반 프로톤 세라믹 연료전지(PCFC)용 고성능 전해질 개발)

  • An, Hyegsoon;Shin, Dongwook;Choi, Sung Min;Lee, Jong-Ho;Son, Ji-Won;Kim, Byung-Kook;Je, Hae June;Lee, Hae-Weon;Yoon, Kyung Joong
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.271-277
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    • 2014
  • To overcome the limitations of the solid oxide fuel cells (SOFCs) due to the high temperature operation, there has been increasing interest in proton conducting fuel cells (PCFCs) for reduction of the operating temperature to the intermediate temperature range. In present work, the perovskite $BaCe_{0.85-x}Zr_xY_{0.15}O_{3-\delta}$ (BCZY, x = 0.1, 0.3, 0.5, and 0.7) were synthesized via solid state reaction (SSR) and adopted as an electrolyte materials for PCFCs. Powder characteristics were examined using X-ray diffraction (XRD), thermogravimetric analysis (TGA) and Brunauer, Emmett and Teller (BET) surface area analysis. Single phase BCZY were obtained in all compositions, and chemical stability was improved with increasing Zr content. Anode-supported cell with $Ni-BaCe_{0.55}Z_{0.3}Y_{0.15}O_{3-\delta}$ (BCZY3) anode, BCZY3 electrolyte and BCZY3-$Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-\delta}$ (BSCF) composite cathode was fabricated and electrochemically characterized. Open-circuit voltage (OCV) was 1.05 V, and peak power density of 370 ($mW/cm^2$) was achieved at $650^{\circ}C$.

Supplementation of protease and different nutrient density diets in growing-finishing pigs

  • Sehyun Park;Jihwan Lee;Won Yun;Seokman Hong;Hanjin Oh;Dongcheol Song;Seyeon Chang;Jaewoo An;Hyunah Cho;Kyeongho Jeon;Jinho Cho
    • Journal of Animal Science and Technology
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    • v.66 no.2
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    • pp.326-339
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    • 2024
  • This study was conducted to investigate the effects of protease supplementation and different nutrient density of diets in growing-finishing pigs. A total of one hundred-eight crossbred growing pigs ([Landrace × Yorkshire] × Duroc) with an initial body weight (BW; 18.74 ± 3.46 kg) were used for 15 weeks. Pigs were randomly assigned to six dietary treatments with 6 replicates of 3 pigs per pen in a 3 × 2 factorial through the following arrangement: Three groups of protease (1, Basal diets; 2, Protease A: 125 mg/kg protease derived from Streptomyces sps; 3, Protease B: 100 mg/kg protease derived from Bacillus licheniformis) at two different nutrient density diets (1, Basal requirement; 2, 0.94%-0.98% higher than requirement in dietary protein and 50 kcal/kg in energy). High nutrient (HN) diets showed higher average daily gain (ADG) (p < 0.05) and apparent total tract digestibility (ATTD) of crude protein (CP) (p < .0001) compared to basal nutrient (BN) diets during growing periods. Supplementation of protease showed higher BW (p < 0.05) and ADG (p < 0.05) compared to non-supplementation of protease during growing periods. Also, supplementation of protease showed higher ATTD of CP (p < 0.01), ATTD of gross energy (p < 0.05) and decreased blood urea nitrogen (BUN) level (p = 0.001) compared to non-supplementation of protease during finishing periods. Pigs which fed the protease showed decreased ammonia (NH3) emissions (p < 0.05) during experiment periods and decreased hydrogen sulfide (H2S) emissions (p < 0.01) during finishing periods. Interactions between nutrient density and protease were observed, which decreased the feed conversion ratio (p < 0.05) in HN diets without protease compared to BN diets without protease during weeks 4 to 6. Also, interaction between nutrient density and protease was observed, which resulted in improved ATTD of CP (p < 0.01) in response to PTA supplementation with HN diets during the finishing period. In conclusion, supplementation of protease reduces NH3 in feces and BUN in whole blood by increasing the digestibility of CP and improves growth performance. Also, diets with high nutrient density improved growth performance and nutrient digestibility in growing periods.

Influence of Lighting Schedule and Nutrient Density in Broiler Chickens: Effect on Growth Performance, Carcass Traits and Meat Quality

  • Li, Wen-Bin;Guo, Yan-Li;Chen, Ji-Lan;Wang, Rong;He, Yao;Su, Dong-Ge
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.11
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    • pp.1510-1518
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    • 2010
  • The study was conducted to evaluate the effect of lighting schedule and nutrient density on growth performance, carcass traits and meat quality of broiler chickens. A total of 576 day old Arbor Acre male chickens was used with a $4{\times}2$ factorial arrangement. The four lighting schedules were continuous (23 L:1 D, CL), 20 L:4 D (12 L:2 D:8 L:2 D), 16 L:8 D (12 L:3 D:2 L:3 D: 2 L:2 D) and 12 L:12 D (9 L:3 D:1 L:3 D:1 L:3 D:1 L:3 D) and provided by incandescent bulbs. The two nutrient densities were high (H, starter diet: 13.39 MJ/kg apparent metabolisable energy (AME), 23.00% crude protein (CP); finisher diet: 13.39 MJ AME/kg, 19.70% CP) and low energy and protein level (L, starter diet: 12.03 MJ AME/kg, 20.80% CP; finisher diet: 12.14 MJ AME/kg, 18.30% CP). Houses with dark curtains and solid sidewalls were used. Chickens were randomly allocated to the 8 treatments with each treatment comprising 6 replicates of 12 chickens. Feed and water were available ad libitum. Lighting schedules showed no difference (p>0.05) in growth performance at the end of the experiment. 12 L:12 D significantly reduced (p<0.05) the concentration of malondialdehyde (MDA) compared to 23 L:1 D treatment. Intermittent lighting (IL) schedules produced higher protein content (p<0.001) in breast meat. Birds on high density diets had higher body weight (BW), feed intake (FI) (p<0.001), and feed conversion ratio (FCR) (p<0.001) throughout the experiment with the exception of 36 to 42 d. High nutrient density increased (p<0.05) abdominal fat, decreased (p<0.05) the moisture loss of meat, and reduced percentage of wings and legs. There was a significant lighting schedule${\times}$diet interaction (p<0.001) on FCR for days 8 to 14 and 15 to 21. Results indicated that IL can give similar growth performance in comparison with CL, meanwhile with positive effects on meat quality by increasing protein content and decreasing the concentration of MDA. High nutrient density resulted in greater growth performance.

Directed Energy Weapon System and Analysis on Effectiveness HPM Weapon (지향성 에너지 무기체계와 고출력 마이크로파 무기 효과도 분석)

  • Kim, Ilkyu;Kim, Moonsup
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.10
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    • pp.935-940
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    • 2016
  • Directed energy weapon enables to radiate the concentrated energy so as to result in distraction and overload of the target electronics. Analysis on effectiveness of weapon system can be important consideration in order to determine performance and design weapon system. In this paper, air defense weapon system, which is one of directed energy weapon system is studied. In order to analyze the effectiveness, the reflector antenna with high power circularly polarized horn antenna is designed, and power density in axial effective area is simulated and calculated using Friis formula. Through the study, the validity of antenna system is verified, and the effectiveness of directed energy weapon system on the target is evaluated.

Fabrication of Fe-TiC Composite by High-Energy Milling and Spark-Plasma Sintering

  • Tuan, N.Q.;Khoa, H.X.;Vieta, N.H.;Lee, Y.H.;Lee, B.H.;Kim, J.S.
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.338-344
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    • 2013
  • Fe-TiC composite was fabricated from Fe and TiC powders by high-energy milling and subsequent spark-plasma sintering. The microstructure, particle size and phase of Fe-TiC composite powders were investigated by field emission scanning electron microscopy and X-ray diffraction to evaluate the effect of milling conditions on the size and distribution of TiC particles in Fe matrix. TiC particle size decreased with milling time. The average TiC particle size of 38 nm was obtained after 60 minutes of milling at 1000 rpm. Prepared Fe-TiC powder mixture was densified by spark-plasma sintering. Sintered Fe-TiC compacts showed a relative density of 91.7~96.2%. The average TiC particle size of 150 nm was observed from the FE-SEM image. The microstructure, densification behavior, Vickers hardness, and fracture toughness of Fe-TiC sintered compact were investigated.

Shape-dependent Adhesion and Friction on Au Nanoparticles Probed with Atomic Force Microscopy

  • Yuk, Youngji;Hong, Jong Wook;Han, Sang Woo;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.141-141
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    • 2013
  • Shape control of metal nanocrystals has broad applications, including catalysis, plasmonics, and sensing. It was found that controlling the atomic arrangement on metal nanocrystal surfaces affects many properties, including the electronic dipole or work function. Tuning the surface structure of exposed facets of metal nanocrystals was enabled by shape control. We investigated the effect of shape on nanomechanical properties, including friction and adhesion forces. Two nanoparticles systems, high-index {321} and low-index {100}, were used as model nanoparticle surfaces. Scanning force microscopy was used to probe nanoscale friction and adhesion. Because of the abundant presence of high-density atomic steps and kinks, high-index faceted nanoparticles have a higher surface energy than low-index faceted cubic nanoparticles. Due to this high surface energy, high-index faceted particles have shown stronger adhesion and higher friction than low-index nanoparticles. We discuss the results in light of the differences in surface energy as well as the effect of capping layers in the measurement.

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