• Title/Summary/Keyword: high temperature state

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A Study on the Characteristic of Conversion Efficiency for Three-way Catalyst in Hydrogen-Natural Gas Blend Fueled Engine (수소-천연가스 혼합연료 엔진의 삼원촉매 전환효율 특성 연구)

  • Park, Cheol-Woong;Yi, Ui-Hyung;Kim, Chang-Gi;Lee, Janghee
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.23-30
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    • 2016
  • The conventional natural gas engine realized lean combustion for the improved efficiency. However, in order to cope with exhaust gas regulations enforced gradually, the interest has shifted at the stoichiometric mixture combustion system. The stoichiometric mixture combustion method has the advantage of a three-way catalyst utilization whose purification efficiency is high, but the problem of thermal durability and the fuel economy remains as a challenge. Hydrogen-natural gas blend fuel (HCNG) can increase the rate of exhaust gas recirculation (EGR) because the hydrogen increases burning speed and lean flammability limit. The increase in the EGR rate can have a positive impact on heat resistance of the engine due to the decreased combustion temperature, and further can increase the compression ratio for efficient combustion. In this study, to minimize the exhaust emission developed HCNG engine with stoichiometric combustion method, developed three-way catalyst was applied to evaluate the conversion characteristics. The tests were carried out during the steady state and transient operating conditions, and the results were compared for both the conventional and proto-three-way catalyst of HCNG engine for city buses.

Fabrication and Characteristics of Infrared Photodiode Using Insb Wafer with p-i-n Structure (p-i-n 구조의 InSb 웨이퍼를 이용한 적외선 광다이오드의 제조 및 그 특성)

  • Cho, Jun-Young;Kim, Jong-Seok;Son, Seung-Hyun;Lee, Jong-Hyun;Choi, Sie-Young
    • Journal of Sensor Science and Technology
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    • v.8 no.3
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    • pp.239-246
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    • 1999
  • A highly sensitive photovoltaic infrared photodiode was fabricated for detecting infrared light in $3{\sim}5\;{\mu}m$ wavelength range on InSb wafer with p-i-n structure grown by MOCVD. Silicon dioxide($SiO_2$) insulating films for the junction interface and surface of photodiode were prepared using RPCVD because InSb has low melting point and evaporation temperature. After formation of In ohmic contacts by thermal evaporation, the electrical properties of the photodiode were characterized in dark state at 77K. A product of zero-bias resistance and area($R_0A$) showed $1.56{\times}10^6\;{\Omega}{\cdot}cm^2$ that satisfied BLIP(background limited infrared photodetector) condition. When the photodiode was tested under infrared light, the normalized detectivity of about $10^{11}\;cm{\cdot}Hz^{1/2}{\cdot}W^{-1}$ was obtained. we successfully fabricated a unit cell with InSb IR array with good quantum efficiency and high detectivity.

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Cyanobacterial Blooms and Water Quality of Major Recreational Park Ponds in the Capital Region (수도권 주요 공원 연못의 수질 특성과 남조류 대발생)

  • Park, Myung-Hwan;Suh, Mi-Yeon;Hwang, Soon-Jin;Kim, Yong-Jae;Han, Myung-Soo;Kim, Baik-Ho
    • Korean Journal of Ecology and Environment
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    • v.41 no.1
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    • pp.54-65
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    • 2008
  • The seasonal dynamics of phytoplankton and water quality were evaluated bimonthly at 7 park ponds in the capital region from October 2004 to August 2005. With out the change of water temperature $(0.4\sim26.0^{\circ}C)$, cyanobacteria dominated in park ponds such as Gyungbokgung Gyunghyaeru and Seokchon reservoir. The standing crops of phytoplankton was significant related with cell densities of cyanobacteria (r=0.993), while they did not significant correlation with environmental factors. Almost of all park ponds in the capital region were classified as eutrophic state with high TP concentrations and TN/TP ratios less than 10. Major dominant cyanobacteria were as followed; Anabaena sp., Aphanocapsa elachista, Lyngbya contorta, Merismopedia elegans, Microcystis aeruginosa, M. wesenbergii, Microcystis sp., Oscillatoria sp., Phormidium tenue, and Plectonema sp. To date, although the concentration of chlorophyll-${\alpha}$ and cyanobacterial densities in the capital region was below the 'danger' level of WHO guidelines value, the monitoring of cyanobacterial densities and its toxin (microcystin) in recreational/bath water should be continued.

The Study on the Environmental Factors of Atopic Dermatitis in Oriental-Western Medicine (아토피 피부염의 환경적 요인에 대한 동서의학적 고찰)

  • Park, Sung-gu;Noh, Hyeon-Min;Kweon, So-Hyoun;Jo, Eun-Hee;Jang, Hyun-Chul;Kim, Ho-kyoung;Park, Hi-Joon;Kim, Won-Jeong;Park, Min-Cheol
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.31 no.1
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    • pp.52-70
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    • 2018
  • Objectives : Atopic dermatitis(AD) and environmental factors are closely related, but there is lack of oriental medical examination. So we compared the relationship between AD and various environmental factors in Oriental medicine and Western medicine. Methods : We described the relationship between AD and environmental factors through the latest papers and a review of the oriental medicine literature. Results : The regional diversity of AD incidence implies a close relationship between climate factors and AD, and high altitude and low pH springs also have an effect on AD. Air pollutants from industrialization and urbanization aggravate AD. The increase in indoor residence time and the increase in room temperature and humidity have also increased the sensitization to allergens such as house dust mite. In oriental medicine, wind(風) is one of the environmental factors and is an inflammatory state due to external irritation. Wind-Humidity(風濕) refers to erythematous wetting dermatitis with itching and exudation, Wind-Fever(風熱) refers to acute inflammatory reaction with erythematous papules and plague, and Blood-Weakness(血虛) refers to aggravation and chronicization of inflammation due to persistence of skin barrier impairment. Conclusions : We examined the relationship between AD and various environmental factors. We also described the oriental medical viewpoints of the environmental factors in the occurrence of AD and skin barrier impairment.

Bias Characteristics Analysis of Himawari-8/AHI Clear Sky Radiance Using KMA NWP Global Model (기상청 전구 수치예보모델을 활용한 Himawari-8/AHI 청천복사휘도 편차 특성 분석)

  • Kim, Boram;Shin, Inchul;Chung, Chu-Yong;Cheong, Seonghoon
    • Korean Journal of Remote Sensing
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    • v.34 no.6_1
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    • pp.1101-1117
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    • 2018
  • The clear sky radiance (CSR) is one of the baseline products of the Himawari-8 which was launched on October, 2014. The CSR contributes to numerical weather prediction (NWP) accuracy through the data assimilation; especially water vapor channel CSR has good impact on the forecast in high level atmosphere. The focus of this study is the quality analysis of the CSR of the Himawari-8 geostationary satellite. We used the operational CSR (or clear sky brightness temperature) products in JMA (Japan Meteorological Agency) as observation data; for a background field, we employed the CSR simulated using the Radiative Transfer for TOVS (RTTOV) with the atmospheric state from the global model of KMA (Korea Meteorological Administration). We investigated data characteristics and analyzed observation minus background statistics of each channel with respect to regional and seasonal variability. Overall results for the analysis period showed that the water vapor channels (6.2, 6.9, and $7.3{\mu}m$) had a positive mean bias where as the window channels(10.4, 11.2, and $12.4{\mu}m$) had a negative mean bias. The magnitude of biases and Uncertainty result varied with the regional and the seasonal conditions, thus these should be taken into account when using CSR data. This study is helpful for the pre-processing of Himawari-8/Advanced Himawari Imager (AHI) CSR data assimilation. Furthermore, this study also can contribute to preparing for the utilization of products from the Geo-Kompsat-2A (GK-2A), which will be launched in 2018 by the National Meteorological Satellite Center (NMSC) of KMA.

Nickel Catalysts Supported on Ash-Free Coal for Steam Reforming of Toluene (무회분탄에 분산된 니켈 촉매의 톨루엔 수증기 개질)

  • PRISCILLA, LIA;KIM, SOOHYUN;YOO, JIHO;CHOI, HOKYUNG;RHIM, YOUNGJOON;LIM, JEONGHWAN;KIM, SANGDO;CHUN, DONGHYUK;LEE, SIHYUN
    • Journal of Hydrogen and New Energy
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    • v.29 no.6
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    • pp.559-569
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    • 2018
  • Catalytic supports made of carbon have many advantages, such as high coking resistance, tailorable pore and surface structures, and ease of recycling of waste catalysts. Moreover, they do not require pre-reduction. In this study, ash-free coal (AFC) was obtained by the thermal extraction of carbonaceous components from raw coal and its performance as a carbon catalytic support was compared with that of well-known activated carbon (AC). Nickel was dispersed on the carbon supports and the resulting catalysts were applied to the steam reforming of toluene (SRT), a model compound of biomass tar. Interestingly, nickel catalysts dispersed on AFC, which has a very small surface area (${\sim}0.13m^2/g$), showed higher activity than those dispersed on AC, which has a large surface area ($1,173A/cm^2$). X-ray diffraction (XRD) analysis showed that the particle size of nickel deposited on AFC was smaller than that deposited on AC, with the average values on AFC ${\approx}11nm$ and on AC ${\approx}23nm$. This proved that heteroatomic functional groups in AFC, such as carboxyls, can provide ion-exchange or adsorption sites for the nano-scale dispersion of nickel. In addition, the pore structure, surface morphology, chemical composition, and chemical state of the prepared catalysts were analyzed using Brunauer-Emmett-Taylor (BET) analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and temperature-programmed reduction (TPR).

Effect of 2-HEA and EGPA Composition on the Electro-optical Properties of Polymer Dispersed Liquid Crystal (아크릴계 단량체 2-HEA와 EGPA의 조성에 따른 고분자 분산형 액정(PDLC)의 전기광학적 특성 평가)

  • Choi, Jongseon;Kim, Young Dae;Kim, So Yeon
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.205-211
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    • 2019
  • Over the past several decades, the polymer dispersed liquid crystal (PDLC) has received particular attention as a material for developing smart window due to their electro-optical switchable properties. In this study, PDLC cells were fabricated using acrylate monomers, namely 2-hydroxyethyl acrylate (2-HEA) and ethylene glycol phenyl ether acrylate (EGPA), and the effect of the monomer composition on their electro-optical properties was investigated. The monomer mixture with a low viscosity (~10 cps) was easily filled between indium tin oxide (ITO) glasses by capillary action at room temperature. PDLC cells prepared using the mixture ratio of 1 : 9 (2-HEA : EGPA) did not show a complete opaque state at a 0 V condition but exhibited unstable electro-optical properties under an electric field. As the LC composition increased in the reaction mixture for PDLC cell preparation, the $V_{th}$ (threshold voltage) and $V_{sat}$ (saturation voltage) values as well as contrast ratio (CR) increased. $V_{th}$ and $V_{sat}$ values also increased with the cell gap thickness. PDLC cells with a $20{\mu}m$ cell gap thickness exhibited higher CR than those with 10 and $40{\mu}m$ cell gap thicknesses. Particularly, PDLC cells prepared using the mixture ratio of 7 : 3 (2-HEA : EGPA) showed excellent electro-optical properties such as a low driving voltage and high contrast ratio.

Proposal of Agricultural Drought Re-evaluation Method using Long-term Groundwater Level Monitoring Data (장기 지하수위 관측자료를 활용한 농업가뭄 재평가 방안 제언)

  • Jeong, ChanDuck;Lee, ByungSun;Lee, GyuSang;Kim, JunKyum
    • Journal of Soil and Groundwater Environment
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    • v.26 no.4
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    • pp.27-43
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    • 2021
  • Since climate factors, such as precipitation, temperature, etc., show repeated patterns every year, it can be said that future changes can be predicted by analyzing past climate data. As with groundwater, seasonal variations predominate. Therefore, when a drought occurs, the groundwater level is also lowered. Thus, a change in the groundwater level can represent a drought. Like precipitation, groundwater level changes also have a high correlation with drought, so many researchers use Standard Groundwater Level Index (SGI) to which the Standard Precipitation Index (SPI) method is applied to evaluate the severity of droughts and predict drought trends. However, due to the strong interferences caused by the recent increase in groundwater use, it is difficult to represent the droughts of regions or entire watersheds by only using groundwater level change data using the SPI or SGI methods, which analyze data from one representative observation station. Therefore, if the long-term groundwater level changes of all the provinces of a watershed are analyzed, the overall trend can be shown even if there is use interference. Thus, future groundwater level changes and droughts can be more accurately predicted. Therefore, in this study, it was confirmed that the groundwater level changes in the last 5 years compared with the monthly average groundwater level changes of the monitoring wells installed before 2015 appeared similar to the drought occurrence pattern. As a result of analyzing the correlation with the water storage yields of 3,423 agricultural reservoirs that do not immediately open their sluice gates in the cases of droughts or floods, it was confirmed that the correlation was higher than 56% in the natural state. Therefore, it was concluded that it is possible to re-evaluate agricultural droughts through long-term groundwater level change analyses.

Dietary supplementation with L-glutamine enhances immunity and reduces heat stress in Hanwoo steers under heat stress conditions

  • Yves, Kamali;Yong Ho, Jo;Won Seob, Kim;Jalil Ghassemi, Nejad;Jae-Sung, Lee;Hong Gu, Lee
    • Journal of Animal Science and Technology
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    • v.64 no.6
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    • pp.1046-1062
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    • 2022
  • This study investigated the effects of L-glutamine (Gln) supplementation on growth performance, physiological traits, heat shock proteins (HSPs), and gene expression related to muscle and adipose tissue development in Hanwoo steers under heat stress (HS) conditions. Eight Hanwoo steers (initial body weight [BW] 570.7 ± 43.6 kg, months of age 22.3 ± 0.88) were randomly separated into two groups, control and treatment, and supplied with the concentration (1.5% of BW kg/day/head) and rice straw (1.5 kg/day/head). The treatment group were fed the Gln supplementation (0.5% of concentration, as-fed basis) once a day at 08:00 h. Blood samples for the assessment of haematological and biochemical parameters and the separation of peripheral blood mononuclear cells (PBMCs) were collected four times, at 0, 3, 6, and 10 weeks of the experiment. Feed intake was measured daily. BW to analyze growth performance and hair follicle collection to analyze the expression of HSPs were executed four times at 0, 3, 6, and 10 weeks. To analyze gene expression, longissimus dorsi muscle samples were collected by biopsy at the end of the study. As a result, growing performance, including final BW, average daily gain, and gain-to-feed ratio, were not different between the two groups. Leukocytes including lymphocytes and granulocytes, tended to increase in the Gln supplementation group (p = 0.058). There were also no differences in biochemical parameters shown between the two groups, except total protein and albumin, both of which were lower in the Gln supplementation group (p < 0.05). Gene expressions related to muscle and adipose tissue development were not different between the two groups. As temperature-humidity index (THI) increased, HSP70 and HSP90 expression in the hair follicle showed a high correlation. HSP90 in the hair follicle was decreased in the treatment group compared with the control group at 10 weeks (p < 0.05). Collectively, dietary Gln supplementation (0.5% of concentration, as-fed basis) may not be influential enough to affect growth performance and gene expression related to muscle and adipose tissue development in steers. However, Gln supplementation increased the number of immune cells and decreased HSP90 in the hair follicle implying HS reduction in the corresponding group.

Consolidation and magnetic properties of ferromagnetic Fe-MgO powders prepared by ball milling process (볼밀링법으로 제조된 강자성 Fe-MgO 분말의 벌크화 및 자기적 특성)

  • Chung-Hyo Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.4
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    • pp.125-130
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    • 2024
  • Preparation of ferromagnetic powders for the mixture of hematite and pure Mg powders by ball milling has been investigated. Also, consolidation of the ball-milled powders was performed in a spark plasma sintering machine at 800-1,000℃. It is found that a ferromagnetic Fe-MgO composite powders are obtained by ball milling of hematite and pure Mg powders before 1 hour. The magnetization and coercivity of ball-milled samples change at the results of the solid state reaction of hematite by pure Mg during ball milling. The saturation magnetization of ball-milled samples increases with increasing ball milling time and reaches to a maximum value of 93.4 emu/g after 5 hours of ball milling. Shrinkage change after sintering of ball-milled sample for 5 hours was significant above 300℃ and gradually increased with increasing temperature up to 800℃. X-ray diffraction result shows that the average grain size of Fe in Fe-MgO bulk sample sintered at 900℃ is 50 nm. It can be also seen that the coercivity of bulk sample sintered at 900℃ is still high value of 90 Oe, indicating that the grain growth of magnetic Fe phase during sintering process tend to be suppressed.