• Title/Summary/Keyword: high temperature reactors

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Multiscale Modeling and Simulation of Water Gas Shift Reactor (Water Gas Shift Reactor의 Multiscale 모델링 및 모사)

  • Lee, Ukjune;Kim, Kihyun;Oh, Min
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.582-590
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    • 2007
  • In view of the analysis of the phenomena and the prediction of the performance, mathematical modelling and simulation of a high temperature pilot reactor for water gas shift reaction (WGSR) has been carried out. Multiscale simulation incorporated computational fluid dynamics (CFD) technique, which has the capability to deal with the reactor shape, fluid and energy transport with extensive degree of accuracy, and process modeling technique, which, in turn is responsible for reaction kinetics and mass transport. This research employed multiscale simulation and the results were compared with those from process simulation. From multiscale simulation, the maximum conversion of was predicted approximately 0.85 and the maximum temperature at the reactor was calculated 720 K, resulting from the heat of reaction. Dynamic simulation was also performed for the time transient profile of temperature, conversion, etc. Considering the results, it is concluded that multiscale simulation is a safe and accurate technique to predict reactor behaviors, and consequently will be available for the design of commercial size chemical reactors as well as other commercial unit operations.

Comparison of Salinity and Composting Efficiency by Washing before and after Aerobic Composting of Food Wastes (음식물쓰레기의 호기성 퇴비화 전과 후의 세척에 따른 염분도와 퇴비화효율 비교)

  • Park Seok Hwan
    • Journal of Environmental Health Sciences
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    • v.31 no.2 s.83
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    • pp.160-164
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    • 2005
  • This study was performed to evaluate the effects of washing food wastes before aerobic composting on temperature, pH and salinity, and the effects of washing after composting on salinity of sample mixtures. Weight ratios of food wastes to water in washing were 1:0(Control), 1:1(W-1), 1:2(W-2), 1:3(W-3) and 1:0(N-4), respectively. Ratios of food wastes to wood chips in reactor of Control, W-1, W-2, W-3 and N-1 were $5\;kg:0\iota,\;5\;kg:5\iota,\;5\;kg:5\iota,\;5\;kg:5\iota\;and\;5\;kg:5\iota$, respectively. Reactors were operated for 24 days with 1 hour stirring by 1 rpm and 2 hours of forced aeration per day. The increase in the ratio of water to food wastes resulted in the increase of the maximum reaction temperature and the shortening of the high temperature reaction period. The increase in the ratio of water to food wastes also resulted in faster reaching to the lowest pH and then to the steady state of pH 9.0. The final salinities of Control, N-1, W-1, W-2 and W-3 were $1.04\%,\;0.92\%,\;0.78\%,\;0.64\%\;and\;0.53\%$, respectively. The salinities of the N-l samples which were washed by the weight ratios (water:N-l) of 1:1, 2:1 and 3:1 after composting were $0.72\%,\;0.61\%\;and\;0.51\%$, respectively. Therefore, washing food wastes before aerobic composting is more efficient method than that after aerobic composting.

Assessment of Material Degradation of High-Temperature Components for Process Plant by Grain Boundary Etching Method (입계부식법에 의한 공정설비 고온요소의 재질열화 평가)

  • Han Sang In;Yoon Kee Bong;Kim Ji Yoon;Chung Se Hi
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.74-82
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    • 1998
  • The grain boundary etching method as a technique for assessing degradation of structural materials used at elevated temperature has received much attention since it is simple, inexpensive and easy to apply to real plant components. In this study, the technique is applied to some aged petroleum and chemical plant components such as reactors and drums. As a degradation parameter, intersection number ratio ($N_i/N_o$), is employed. The intersection number ratio ($N_i/N_o$) is defined as the ratio of intersection number ($N_i$) obtained from 5-minute picric acid etched surface to the number ($N_o$) obtained from Nital etched surface. In order to study degradation level, several relationships were measured such as the correlation between shift in ductile brittle transition temperature, $({\Delta}DBTT)_{sp}$ and intersection number ratio, ($N_i/N_o$) and the correlation between the measured ($N_i/N_o$) values and Larson-Miller Parameter values.

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Proposal of an Improved Concept Design for the Deep Geological Disposal System of Spent Nuclear Fuel in Korea

  • Lee, Jongyoul;Kim, Inyoung;Ju, HeeJae;Choi, Heuijoo;Cho, Dongkeun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.spc
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    • pp.1-19
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    • 2020
  • Based on the current high-level radioactive waste management basic plan and the analysis results of spent nuclear fuel characteristics, such as dimensions and decay heat, an improved geological disposal concept for spent nuclear fuel from domestic nuclear power plants was proposed in this study. To this end, disposal container concepts for spent nuclear fuel from two types of reactors, pressurized water reactor (PWR) and Canada deuterium uranium (CANDU), considering the dimensions and interim storage method, were derived. In addition, considering the cooling time of the spent nuclear fuel at the time of disposal, according to the current basic plan-based scenarios, the amount of decay heat capacity for a disposal container was determined. Furthermore, improved disposal concepts for each disposal container were proposed, and analyses were conducted to determine whether the design requirements for the temperature limit were satisfied. Then, the disposal efficiencies of these disposal concepts were compared with those of the existing disposal concepts. The results indicated that the disposal area was reduced by approximately 20%, and the disposal density was increased by more than 20%.

An Experimental Study on the Transient Interaction Between High Temperature Thermite Melt and Concrete

  • Nho, Ki-Man;Kim, Jong-Hwan;Kim, Sang-Baik;Shin, Ki-Yeol;Mo Chung
    • Nuclear Engineering and Technology
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    • v.29 no.4
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    • pp.336-347
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    • 1997
  • During postulated severe accidents in Light water Reactors, molten corium which was ejected from the reactor vessel bottom, may erode the concrete basemat of the containment and there by threaten the containment integrity. This study experimentally examines the molten core-concrete interaction (MCC) using 20kg of thermite melt (Fe + $Al_2$O$_3$) and the concrete, used in Yonggwang Nuclear Power Plant Units 3 and 4 (YGN 3 & 4) in Korea. The measured data are the downward heat fluxes, concrete erosion rate, gases and particle generation rates during MCCI. Transient results ore compared with those of TURCIT experiment conducted by SNL in USA. The peak downward heat flux to the concrete was measured to be about 2.1㎿/$m^2$. The initial concrete erosion rate was 175cm per hour, decreasing to 30cm per hour. It was shown from the post-test that the erosion was progressed downward up to 18mm in the concrete slug.

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Conceptual Design of Passive Containment Cooling System for Concrete Containment

  • Lee, Seong-Wook;Baek, Won-Pil;Chang, Soon-Heung
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.10a
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    • pp.358-363
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    • 1995
  • A study on passive cooling systems for concrete containment of advanced pressurized water reactors has been performed. The proposed passive containment cooling system (PCCS) consist of (1) condenser units located inside containment, (2) a steam condensing pool outside containment at higher elevation, and (3) downcommer/riser piping systems which provide coolant flow paths. During an accident causing high containment pressure and temperature, the steam/air mixture in containment is condensed on the outer surface of condenser tubes transferring the heat to coolant flowing inside tubes. The coolant transfers the heat to the steam condensing pool via natural circulation due to density difference. This PCCS has the following characteristic: (1) applicable to concrete containment system, (2) no limitation in plant capacity expansion, (3) efficient steam condensing mechanism (dropwise or film condensation at the surface of condenser tube), and (4) utilization of a fully passive mechanism. A preliminary conceptual design work has been done based on steady-state assumptions to determine important design parameter including the elevation of components and required heat transfer area of the condenser tube. Assuming a decay power level of 2%, the required heat transfer area for 1,000MWe plant is assessed to be about 2,000 ㎡ (equivalent to 1,600 of 10 m-long, 4-cm-OD tubes) with the relative elevation difference of 38 m between the condenser and steam condensing pool and the riser diameter of 0.62 m.

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A Study on the Composting of the Brewery and Nightsoil Mixed Sludge I - Influence of mixing ratio and agitation period in composting (맥주 및 분뇨슬러지 혼합물의 퇴비화에 관한 연구 I -혼합 및 교반주기가 퇴비화에 미치는 영향-)

  • 박종혁;김동수
    • Resources Recycling
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    • v.8 no.4
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    • pp.39-44
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    • 1999
  • Nightsoil and brewery sludges usually contain a high concentration of organic matters. A composting study using reactors was carried out for the recycle of brewery wastewater sludge and nightsoil treatment sludge, which have been landfilled. A good composting process was obtained with a sludge mixing ratio of 1:1 and injual pH had no effect on temperature increase related to microbial activity. The injtial C/N ratio at approximarely 15 decreased to 13 without the increase in pH.. It was found that agitation of one time a week provided the most effective composting process.

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Numerical Study on Operating Parameters and Shapes of a Steam Reformer for Hydrogen Production from Methane (천연가스로부터 수소를 생산하기 위한 수증기 개질기의 작동조건과 형상에 대한 수치해석 연구)

  • Park, Joong-Uen;Lee, Shin-Ku;Lim, Sung-Kwang;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.1
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    • pp.60-68
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    • 2009
  • The steam reformer for hydrogen production from methane is studied by a numerical method. Langmuir- Hinshelwood model is incorporated for catalytic surface reactions, and the pseudo-homogeneous model is used to take into account local equilibrium phenomena between a catalyst and bulk gas. Dominant chemical reactions are Steam Reforming (SR) reaction, Water-Gas Shift (WGS) reaction, and Direct Steam Reforming (DSR) reaction. The numerical results are validated with experimental results at the same operating conditions. Using the validated code, parametric study has been numerically performed in view of the steam reformer performance. As increasing a wall temperature, the fuel conversion increases due to the high heat transfer rate. When Steam to Carbon Ratio (SCR) increases, the concentration of carbon monoxide decreases since WGS reaction becomes more active. When increasing Gas Hourly Space Velocity (GHSV), the fuel conversion decreases due to the heat transfer limitation and the low residence time. The reactor shape effects are also investigated. The length and radius of cylindrical reactors are changed at the same catalyst volume. The longer steam reformer is, the better steam reformer performs. However, system energy efficiency decreases due to the large pressure drop.

REVIEW OF SUPERCRITICAL CO2 POWER CYCLE TECHNOLOGY AND CURRENT STATUS OF RESEARCH AND DEVELOPMENT

  • AHN, YOONHAN;BAE, SEONG JUN;KIM, MINSEOK;CHO, SEONG KUK;BAIK, SEUNGJOON;LEE, JEONG IK;CHA, JAE EUN
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.647-661
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    • 2015
  • The supercritical $CO_2$ (S-$CO_2$) Brayton cycle has recently been gaining a lot of attention for application to next generation nuclear reactors. The advantages of the S-$CO_2$ cycle are high efficiency in the mild turbine inlet temperature region and a small physical footprint with a simple layout, compact turbomachinery, and heat exchangers. Several heat sources including nuclear, fossil fuel, waste heat, and renewable heat sources such as solar thermal or fuel cells are potential application areas of the S-$CO_2$ cycle. In this paper, the current development progress of the S-$CO_2$ cycle is introduced. Moreover, a quick comparison of various S-$CO_2$ layouts is presented in terms of cycle performance.

Effect of Kinetic Parameters on Simultaneous Ramp Reactivity Insertion Plus Beam Tube Flooding Accident in a Typical Low Enriched U3Si2-Al Fuel-Based Material Testing Reactor-Type Research Reactor

  • Nasir, Rubina;Mirza, Sikander M.;Mirza, Nasir M.
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.700-709
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    • 2017
  • This work looks at the effect of changes in kinetic parameters on simultaneous reactivity insertions and beam tube flooding in a typical material testing reactor-type research reactor with low enriched high density ($U_3Si_2-Al$) fuel. Using a modified PARET code, various ramp reactivity insertions (from $0.1/0.5 s to $1.3/0.5 s) plus beam tube flooding ($0.5/0.25 s) accidents under uncontrolled conditions were analyzed to find their effects on peak power, net reactivity, and temperature. Then, the effects of changes in kinetic parameters including the Doppler coefficient, prompt neutron lifetime, and delayed neutron fractions on simultaneous reactivity insertion and beam tube flooding accidents were analyzed. Results show that the power peak values are significantly sensitive to the Doppler coefficient of the system in coupled accidents. The material testing reactor-type system under such a coupled accident is not very sensitive to changes in the prompt neutron life time; the core under such a coupled transient is not very sensitive to changes in the effective delayed neutron fraction.